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Journal of Coatings
Volume 2013 (2013), Article ID 180740, 6 pages
Hot-Dip Aluminizing of Low Carbon Steel Using Al-7Si-2Cu Alloy Baths
1Department of Metallurgical and Materials Engineering, National Institute of Technology Karnataka, Surathkal, Mangalore 575025, India
2Department of Mechanical Engineering, Srinivasa School of Engineering, Mukka, Surathkal, Mangalore 575021, India
Received 17 May 2013; Accepted 14 August 2013
Academic Editor: Masahiro Fukumoto
Copyright © 2013 Prashanth Huilgol et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Hot-dip aluminizing of low carbon steel was done in molten Al-7Si-2Cu bath at 690°C for dipping time ranging from 300 to 2400 seconds. Characterization of the intermetallics layer was done by using scanning electron microscope with energy dispersive spectroscopy. Four intermetallic phases, -Al7Fe2Si, -FeAl3, -Fe2Al5, and -Al2Fe3Si3, were identified in the reaction layer. - Al7Fe2Si phase was observed adjacent to aluminum-silicon topcoat, -FeAl3 between and -Fe2Al5, -Fe2Al5 adjacent to base material, and -Al2Fe3Si3 precipitates within Fe2Al5 layer. The average thickness of Fe2Al5 layer increased linearly with square root of dipping time, while for the rest of the layers such relationship was not observed. The tongue-like morphology of Fe2Al5 layer was more pronounced at higher dipping time. Overall intermetallic layer thickness was following parabolic relationship with dipping time.
Hot-dip aluminizing is an effective and inexpensive coating process to protect steels from oxidation [1, 2]. The quality of coating depends on the properties of the intermetallics layer forming at the interface. A brittle intermetallic layer may peel off from surface during forming operations , which generally follows aluminizing treatment. Therefore it becomes necessary to study the formation of intermetallics layer under different conditions. Gebhardt and Obrowski  observed that when steel comes in contact with the molten aluminum, the major intermetallic layer formed is Fe2Al5. Bouché et al.  reported the formation of two intermetallic layers, namely, Fe2Al5 and FeAl3, when solid iron is dipped in liquid aluminum over the temperature range 700°C to 900°C. They reported that the growth behaviour is initially nonparabolic which is followed by parabolic. Kinetic studies done by Bouayad et al.  for medium dipping times (<45 min) showed that the growth of Fe2Al5 layer is diffusion controlled and FeAl3 layer growth is linear with time. Many researchers tried to explain the observed tongue-like morphology of the intermetallic layers [5–7] and are of the opinion that the anisotropic diffusion is responsible for this growth. Springer et al.  investigated interdiffusion between low carbon steel and pure Al (99.99%) and Al alloy (Al-5%Si) between temperatures 600°C and 675°C and showed that growth rate of -layer (Fe2Al5) is diffusion controlled and it governs overall intermetallic layer growth. Cheng and Wang  observed that as the silicon content in the molten bath increases, the thickness of intermetallic layer decreases as well as the interface between intermetallic layer and steel substrate becomes flat. Cheng and Wang  investigated the effect of nickel preplating on the formation of intermetallic layer when the mild steel is dipped in pure Al. Li et al.  investigated the phase constituents within the intermetallic layer formed during hot-dip aluminizing. Bhat et al.  discussed the effect of ZnCl2 + NH4Cl flux on the microstructural formation during dip aluminizing of steel with aluminum.
It is also reported that Si and Cu are the alloying elements in the aluminizing bath which are effective in restraining the growth of intermetallic layer [4, 13]. Addition of Cu has an additional effect that promotes formation of cubic variant for Al7Fe2Si . Cubic variants are better than hexagonal variants because of improved ductility . Also, Al-Si-Cu alloy is one of the filler metals used during dissimilar TIG welding of aluminum alloys to stainless steels [15, 16]. To the best of our knowledge there is no reported investigations on the combined effect of Si and Cu on the intermetallic layer formation during hot-dip aluminizing. In the present work an attempt has been made to study the kinetics of various intermetallic phases formed as a function of time during hot-dip aluminizing of steel with Al-7%Si-2%Cu bath at a dipping temperature of 690°C.
2. Materials and Methods
The substrate used in this experiment is a low carbon steel having the following composition (all are in wt%): C-0.24%, Si-0.29%, and Mn-0.54%. The substrate was in the form of a cold rolled strip. Coupons of dimensions 3 mm × 8 mm × 50 mm were cut, metallographically polished, and used for aluminizing. Before aluminizing samples were precleaned using 10% hydrochloric acid, followed by washing with distilled water and drying.
Samples were dipped in a melt of Aluminum-7Si-2Cu (all are in wt%). The aluminizing was conducted at 690°C temperature (±5°C) for different dipping times (300 s, 600 s, 900 s, 1500 s, and 2400 s). After dipping for predetermined time, the sample was removed and cooled rapidly in air. During melting and aluminizing, the Al melt was covered with a flux made using an eutectic mixture of zinc chloride and ammonium chloride (ratio being 3 : 1 by weight). The specimens were cut across the cross-section, metallographically polished, and etched using 3% nital solution. Microstructures were studied using scanning electron microscope (SEM) and the chemical composition was measured using EDS (Energy Dispersive Spectroscopy). The intermetallic layer thickness was measured over a large number of locations (>40) spread on 4 surfaces.
Figure 1(a) shows a typical cross-sectional micrograph of the interface between the base material and Al-Si topcoat. Besides topcoat and base material, it has a continuous intermetallic layer (IML). The thickness of the intermetallic layer was varying across the length of the interface. Figure 1(b) shows a magnified image from Figure 1(a). It indicates that the IML consists of a number of intermetallic phases. Chemical compositions at various locations (A to D) in the IML was estimated, and they are given in Table 1. Using morphological information shown in Figure 1(b) and chemical composition shown in Table 1, we identify four intermetallic phases in the IML. They are at A: -Al7Fe2Si, at B: -FeAl3, at C: -Fe2Al5, and at D: -Al2Fe3Si3.
Figures 2(a) and 2(b) show IML formation at 690°C for dipping times of 300 s and 2400 s, respectively. At the initial dipping time of 300 s the thickness of total IML is in the range of 8–24.6 μm with an average value of 17.5 μm. Within the IML, () layer formed the largest fraction. Since the thickness of -FeAl3 layer is very small, the thickness of -FeAl3 and -Al7Fe2Si was measured together. With increase in dipping time, the thickness of -Fe2Al5 layer increased rapidly, while increase in () layer was relatively gradual. At dipping time of 2400 s the average thickness of -Fe2Al5 was more than that of () layer.
4.1. Microstructural Features
From Figures 1(a), 1(b), 2(a), and 2(b) we see that the intermetallic layer consists of four phases, namely, -Al7Fe2Si (with Cu), -FeAl3, -Fe2Al5, and -Al2Fe3Si3. This is true for all time scales investigated. As expected near Al-Si topcoat we have which is richer in Al compared to (which is near steel side). Presence of -Al7Fe2Si, -FeAl3, -Fe2Al5, and -Al2Fe3Si3 is reported for the case of Al-5Si and Al-10Si bath . Other phases in the Fe-Al system like Fe3Al, FeAl which were observed by Li et al.  in the case of Fe-Al system were not observed. is the only layer which had Cu in it, which could be detected by SEM-EDS. All other phases were devoid of Cu. Song et al.  and Lin et al.  have reported partial substitution of Al by Cu in -FeAl3.
Although the phase -Al2Fe3Si3 is discontinuous and embedded in -Fe2Al5, we can say that the diffusion path from iron side is BCC Fe-Fe2Al5, , , and . It is to be noted that when Si content in Fe2Al5 layer increases more than 4.7 at %, is getting precipitated in Fe2Al5 layer . is present very close to Al-Si-Cu topcoat. Its thickness is continuously varying. In the literature  Cheng and Wang have reported two variants for , that is, (cubic) and (hexagonal). Hexagonal variant has a chemical formula corresponding to Al7Fe2Si, and cubic variant has a chemical formula corresponding to Al7(Fe, M)2Si, where M can be copper, cobalt, or manganese. From mechanical property point of view cubic variant is desirable than hexagonal variant .
4.2. Growth of Intermetallic Layers
Figures 1 and 2 indicate that the intermetallic layer is not smooth. This is also true for individual layers, namely, -Fe2Al5 and () layers. Hence thickness is measured over a relatively larger area, covering four sides of the sample. The reported thickness values are average of at least 40 readings. Figure 3(a) shows variation of -Fe2Al5 layer thickness as a function of dipping time. As dipping time increases, the -Fe2Al5 layer thickness increases and the relation is a parabolic one with a fitting coefficient . A plot of thickness of -Fe2Al5 layer against square root of the dipping time is drawn (Figure 3(b)), and the rate constant estimated is 0.57 μm/s1/2. We can write kinetics of growth of -Fe2Al5 as , where is thickness, is rate constant, and is dipping time. The value of rate constant is much less than in the case of a bath without silicon and copper . It is assumed that at this temperature, the dissolution of the substrate in the molten bath is negligible.
With increase in dipping time the growth rate of -Fe2Al5 layer is higher as compared to that of () layer. Therefore, at higher dipping times the tongue-like morphology or the waviness of the -Fe2Al5 layer is more pronounced. The literature  reports that this tongue-like morphology is a result of favourable path for aluminum atoms to diffuse along -axis of the Fe2Al5 orthorhombic structure.
Figure 4 shows variation of () layer with time, and an attempt to fit parabolic curve fitting shows very poor fitting. This may be due to various mechanisms involved in the formation of -Al7Fe2Si. Literature  reports that (i) can be formed by the interdiffusion of Al and Si towards steel and steel towards molten Al bath, (ii) can be formed as a product of eutectic reaction during cooling from diffusion temperature. The report also says that phase is a metastable phase which is forming only during fast solidification after aluminizing using high silicon baths. Also, it is reported that the -FeAl3 layer follows quasilinear growth behavior with time .
4.3. Comparative Growth of -Fe2Al5 with respect to ()
Figure 5 shows a comparison of relative growth of -Fe2Al5 with respect to (). We see that at lower dipping time () layer is more compared to -Fe2Al5 layer. In Fe-Al system, Gibbs free energy for formation of is smaller than that of . When Fe is dipped in molten Al, FeAl3 layer forms first by interfacial reaction. Later Al diffuses through FeAl3 layer to form Fe2Al5 layer. Dybkov  have reported that, for the formation of a second compound layer, a minimum thickness of first compound layer is essential. Bouché et al.  have reported that growth kinetics of -Fe2Al5 is always greater than that of -FeAl3, at 800°C. So at higher dipping time more of -Fe2Al5 compared to -FeAl3.
4.4. Overall Growth Behavior of Intermetallics
Figure 6 shows variation of total intermetallic layer (IML) thickness as a function of time. The IML thickness value is very low compared to IML formation in the case of steel-Al 8combination [5, 10, 11, 18, 19]. The values are still low compared to IML values reported by Hwang et al.  who has done aluminizing at 660°C using a bath of Al-9 wt% Si. It is reported  that the elements like Cu and Si can decrease the activity coefficient of Al in Fe so as to reduce the thickness of intermetallic layer forming at the interface. The Si in the Fe2Al5 occupies vacancies in the -axis of the crystal structure and reduces diffusion of Al towards Fe side. Comparing the experimental data with the reported data we can conclude that Cu and Si can be added in a view to control the thickness of the intermetallic layer. The critical limit for intermetallic layers in Al-Fe dissimilar joints with respect to their mechanical properties is about 10 μm [8, 21].
Low carbon steel is hot-dip aluminized using Al-7Si-2Cu bath at 690°C for time in the range of 300 s to 2400 s. The intermetallic layer consisted of four phases, namely, -Al7Fe2Si (with Cu), -FeAl3, -Fe2Al5, and -Al2Fe3Si3. The growth of Fe2Al5 layer is diffusion controlled with a parabolic rate constant of 0.57 μm/s1/2. The value is much less than that reported in the literature for Al-Si bath. The overall intermetallic growth is also parabolic in nature.
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