Table of Contents
Journal of Coatings
Volume 2014, Article ID 526369, 7 pages
Research Article

Dependence of Adhesion Property of Epoxidized Natural Rubber (ENR 25)/Ethylene-Propylene-Diene Rubber Blend Adhesives Crosslinked by Benzoyl Peroxide

School of Industrial Technology, Universiti Sains Malaysia, 11800 Penang, Malaysia

Received 20 February 2014; Revised 2 May 2014; Accepted 11 May 2014; Published 29 May 2014

Academic Editor: Fahmina Zafar

Copyright © 2014 B. T. Poh and Y. Y. Teh. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


The loop tack, peel strength, and shear strength of crosslinked epoxidized natural rubber (ENR 25)/ethylene-propylene-diene rubber (EPDM) blend adhesives were investigated. Coumarone-indene resin, toluene, and benzoyl peroxide were used as the tackifier, solvent, and crosslinking agent, respectively, throughout the experiment. The adhesive was coated on a polyethylene terephthalate (PET) substrate using a SHEEN hand coater at 60 μm and 120 μm coating thickness. It was cured at 80°C for 30 minutes before testing on a Lloyd adhesion tester operating at testing rates from 10 to 60 cm min−1. Results show that loop tack and peel strength of the ENR 25/EPDM adhesive pass through a maximum value at 2 parts per hundred parts of rubber (phr) of benzoyl peroxide content. This observation is attributed to the increase in crosslinking which enhances the cohesive strength of the adhesive. Further addition of the crosslinking agent decreases the tack and peel strength due to the decrease in wettability of the over-crosslinked adhesive. Shear strength, however, increases steadily with benzoyl peroxide content, an observation which is associated with the steady increase in the cohesive strength. The adhesion properties increase with increasing coating thickness and testing rate.