Molecular Structure of 1,2-Dibenzoyl-1′,2′,3′,4′,5′-pentamethylruthenocene Dioxime Hydrochloride

Table 3

Hydrogen bonds (Å and °) and selected bond lengths (Å) and torsion angles (°).

D–H⋯A	𝑑 (D–H)	𝑑 (H⋯A)	𝑑 (D⋯A)	<(DHA)
O1–H(1O)⋯Cl1	0.812(18)	2.21(2)	2.999(3)	165(4)
O2–H(2O)⋯Cl1	0.821(18)	2.16(2)	2.965(4)	167(4)
O3–H(3O)⋯Cl2	0.827(18)	2.21(2)	3.021(3)	165(4)
O4–H(4O)⋯Cl2	0.823(19)	2.14(2)	2.952(3)	170(4)
N2–H(2N)⋯N1	0.902(18)	1.69(2)	2.574(4)	164(4)
N4–H(4N)⋯N3	0.904(19)	1.71(2)	2.586(4)	163(4)

Selected bond lengths: O1–N1 1.390(4), O2–N2 1.374(4), O3–N3 1.392(3), O4–N4 1.374(3), N1–C11 1.283(4), N2–C18 1.289(4), N3–C35 1.286(4), N4–C42 1.290(4), C6–C18 1.461(4), C10–C11 1.478(4), C30–C42 1.464(4), C34–C35 1.469(4) and Cp-rings: C6–C10 1.458(4), C6–C7 1.437(4), C7–C8 1.412(4), C8–C9 1.416(5), C9–C10 1.427(4), C30–C34 1.472(4), C30–C31 1.439(4), C31–C32 1.409(4), C32–C33 1.410(5), and C33–C34 1.435(4).
Selected torsion angles: C6–C10–C11–N1 20.4(5), C10–C6–C18–N2 −14.3(5), C30–C34–C35–N3 −20.4(5), and C34–C30–C42–N4 17.2(5).