Synthesis and Crystal Structure of Alkynylplatinum(IV) Complex Containing the Terpyridine Ligand

Table 1

Crystallographic details for trans(Br)-[PtBr₂(C≡CPh)(tpy)]Br.

Empirical formula	C23H16Br3N3Pt
Fw	769.20
Temperature (K)	173(2)
(Å)	0.71075
Crystal system	Triclinic
Space group	-1
(Å)	7.2090(4)
(Å)	12.9921(6)
(Å)	13.1231(6)
(deg)	67.0477(14)
(deg)	75.8967(15)
(deg)	78.1381(19)
(Å^3)	1089.25(9)
	2
(Mg/m^3)	2.345
(Mo K) (mm^−1)	11.950
Number of reflections	10839
Unique reflections	4955
GOF ()	1.095
	0.0902
1^a ()	0.0486
2^b (all data)	0.1210

. ^b.