Synthesis and Crystal Structure of Alkynylplatinum(IV) Complex Containing the Terpyridine Ligand

Table 2

Geometrical parameters.

(a) Selected bond lengths and angles (Å, °)

Pt1–Br1	2.4498(12)	C1–C2	1.059(17)
Pt1–Br2	2.4644(12)	N1–Pt1–N2	80.8(4)
Pt1–N1	2.041(10)	N2–Pt1–N3	80.2(4)
Pt1–N2	1.976(9)	Pt1–C1–C2	175.3(12)
Pt1–N3	2.030(11)	C1–C2–C3	174.4(14)
Pt1–C1	2.054(10)	Br1–Pt1–Br2	178.46(5)

(b) Interatomic distances (Å) for intermolecular - interactions

C2⋯C22^i	3.299(15)
C3⋯C21^i	3.373(15)
C3⋯C22^i	3.302(15)
C4⋯C23^ii	3.366(17)
C5⋯C20^i	3.290(17)
C5⋯C22^ii	3.362(17)
C5⋯C23^ii	3.256(16)
C8⋯C21^i	3.374(18)

Symmetry operators: ⁱ, , ; ⁱⁱ, , .

(c) Hydrogen-bond geometry (Å, °)

D–H⋯A	D–H	H⋯A	D⋯A	D–H⋯A
C4–H1⋯Br1^i	0.95	2.84	3.688(14)	149
C11–H8⋯Br1^ii	0.95	2.86	3.761(13)	160
C22–H15⋯Br1^i	0.95	3.34	3.836(14)	115
C23–H16⋯Br1^i	0.95	2.80	3.576(13)	140
C4–H1⋯Br2^iii	0.95	3.49	4.072(13)	122
C5–H2⋯Br2^iii	0.95	3.17	3.922(14)	137
C16–H11⋯Br2^iv	0.95	2.87	3.702(14)	147
C10–H7⋯Br2^v	0.95	2.94	3.733(13)	142
C8–H5⋯Br3^ii	0.95	3.12	3.758(13)	126
C9–H6⋯Br3^ii	0.95	3.14	3.738(11)	122
C22–H15⋯Br3^vi	0.95	3.20	3.872(12)	129
C10–H7⋯Br3^ii	0.95	3.12	3.718(13)	122
C12–H9⋯Br3	0.95	3.19	3.945(13)	138
C15–H10⋯Br3	0.95	2.89	3.597(13)	132
C6–H3⋯Br3^vii	0.95	3.32	3.943(13)	125
C17–H12⋯Br3^viii	0.95	2.89	3.819(15)	166
C21–H14⋯Br3^vi	0.95	3.28	3.909(13)	126

Symmetry operators: ⁱ, , ; ⁱⁱ, , ; ⁱⁱⁱ, , ; ^iv, , ; ^v, , ; ^vi, , ; ^vii, , ; ^viii, , .