Synthesis, Characterization, and Crystal Structure of [Co₄(CH₃CO₂)₂L₄]₂[BPh₄]₄0.5H₂O, Where HL = 4-(Salicylaldiminato)antipyrine

Table 1

Crystal data and structure refinement details for the complex.

Empirical formula	C248H219B4Co8N24O24.50
Formula weight	4442.15
Temperature	295 K
Wavelength	0.71073 Å
Crystal system	Triclinic
Space group (number)	P-1 (2)
Unit cell parameters	= 19.4643(5) Å, = 98.095(2)°
	= 22.3372(5) Å, = 107.063(2)°
	= 29.1735(5) Å, = 109.257(2)°
Cell volume	11043.4(4) Å^3
	2
c	1.336 g cm^−3
μ	0.659 mm^−1
(000)	4614
Crystal size	0.48 × 0.25 × 0.18 mm^3
range for data collection	2.88–25.68°
Index ranges	−23 ≤ ≤ 23, −27 ≤ ≤ 26, −32 ≤ ≤ 35
Reflections collected	98826
Independent reflections	41906 (int) = 0.0725
Completeness	99.8%
Data/restraints/parameters	41906/96/2772
Goodness-of-fit on	1.023
indices	> 2() = 0.0816, = 0.1484
indices (all data)	= 0.1632, = 0.1826
Largest difference peak and hole	0.681 and −0.350 eÅ^−3