Research Article

Synthesis, Characterization, and X-Ray Structure of Bis(O-butyldithiocarbonato)bis(3-ethyl pyridine)nickel(II)

Table 4

Bond lengths ( ), bond angles, and torsion angles (°).

Bond distances ( )

Ni1 N62.112(3) Ni1 S22.4436(11)
Ni1 S12.4551(10)S2 C11.677(5)
S1 C11.684(4) C12 C131.466(8)
C8 C121.507(6)O2 C11.340(5)
O2 C2B1.426(9)O2 C2A1.432(8)

Bond angles (°)

N6–Ni1–S290.31(9)N6–Ni1–S189.26(9)
S2–Ni1–S1106.63(4)C1–S2–Ni183.03(14)
C1–S1–Ni182.53(16)C13–C12–C8115.2(5)
O2–C1–S2117.5(3)O2–C1–S1121.5(3)

Torsion angles (°)

C9–C8–C12–C13−66.2(8)N6–Ni1–S2–C1−88.76(16)
C7–C8–C12–C13113.5(6)S2–Ni1–N6–C7−55.4(3)
C10–C9–C8–C12−179.2(5)C9–C8–C12–C13−66.2(8)