Research Article
Crystallization and Structural Characterization of Dimeric and Trimeric Forms of (Neocuproine)CdFe(CO)4
Table 3
Selected bond lengths (
) and angles (°) for [(neocuproine)CdFe(CO)
4]
3.
| Bond distances | Cd1–Fe2 | 2.7258(3) | Cd1–Fe3 | 2.7307(3) | Cd2–Fe1 | 2.6969(3) | Cd2–Fe3 | 2.7287(3) | Cd3–Fe1 | 2.7307(3) | Cd3–Fe2 | 2.7251(3) | Fe1–C1 | 1.777(2) | C1–O1 | 1.149(3) | Fe1–C2 | 1.780(2) | C2–O2 | 1.152(3) | Fe1–C3 | 1.774(2) | C3–O3 | 1.162(3) | Fe1–C4 | 1.777(2) | C4–O4 | 1.159(3) | Fe2–C5 | 1.766(2) | C5–O5 | 1.155(3) | Fe2–C6 | 1.767(2) | C6–O6 | 1.156(3) | Fe2–C7 | 1.779(2) | C7–O7 | 1.160(3) | Fe2–C8 | 1.781(2) | C8–O8 | 1.159(3) | Fe3–C9 | 1.774(2) | C9–O9 | 1.154(3) | Fe3–C10 | 1.772(3) | C10–O10 | 1.151(3) | Fe3–C11 | 1.776(2) | C11–O11 | 1.153(3) | Fe3–C12 | 1.768(2) | C12–O12 | 1.165(3) | Cd1–N1 | 2.3814(16) | Cd1–N2 | 2.4616(17) | Cd2–N3 | 2.3901(19) | Cd2–N4 | 2.4395(18) | Cd3–N5 | 2.4967(17) | Cd3–N6 | 2.4301(17) |
| Bond angles | Fe1–Cd2–Fe3 | 133.732(10) | C1–Fe1–C2 | 94.54(11) | Fe1–Cd3–Fe2 | 137.829(10) | C1–Fe1–C3 | 102.61(11) | Fe2–Cd1–Fe3 | 138.272(10) | C1–Fe1–C4 | 100.21(11) | Cd1–Fe2–Cd3 | 95.439(10) | C2–Fe1–C3 | 104.13(10) | Cd1–Fe3–Cd2 | 99.481(10) | C2–Fe1–C4 | 101.90(10) | Cd2–Fe1–Cd3 | 101.855(10) | C3–Fe1–C4 | 143.59(10) | Fe1–C1–O1 | 176.1(2) | C5–Fe2–C6 | 98.01(10) | Fe1–C2–O2 | 175.9(2) | C5–Fe2–C7 | 104.93(11) | Fe1–C3–O3 | 174.7(2) | C5–Fe2–C8 | 97.20(11) | Fe1–C4–O4 | 172.6(2) | C6–Fe2–C7 | 95.15(10) | Fe2–C5–O5 | 175.0(2) | C6–Fe2–C8 | 97.19(10) | Fe2–C6–O6 | 177.4(2) | C7–Fe2–C8 | 152.84(10) | Fe2–C7–O7 | 170.1(2) | C9–Fe3–C10 | 95.00(11) | Fe2–C8–O8 | 169.4(2) | C9–Fe3–C11 | 101.71(12) | Fe3–C9–O9 | 175.6(2) | C9–Fe3–C12 | 102.79(10) | Fe3–C10–O10 | 175.8(2) | C10–Fe3–C11 | 98.78(13) | Fe3–C11–O11 | 172.2(2) | C10–Fe3–C12 | 106.88(11) | Fe3–C12–O12 | 173.8(2) | C11–Fe3–C12 | 142.47(10) | N1–Cd1–N2 | 70.10(6) | N3–Cd2–N4 | 70.51(7) | N5–Cd3–N6 | 68.54(6) | | |
|
|