Structural Studies of [(py)₂CdFe(CO)₄]₃ and {(THF)₅[CdFe(CO)₄]₃}

Table 3

Selected bond lengths (Å) and angles (°) for {(THF)₅[CdFe(CO)₄]₃}.

Bond distances
Fe1–C1	1.788(3)	C1–O1	1.146(4)
Fe1–C2	1.776(3)	C2–O2	1.152(4)
Fe1–C3	1.781(3)	C3–O3	1.156(4)
Fe1–C4	1.786(3)	C4–O4	1.162(4)
Fe2–C5	1.781(3)	C5–O5	1.150(4)
Fe2–C6	1.789(3)	C6–O6	1.144(4)
Fe2–C7	1.787(3)	C7–O7	1.157(4)
Fe2–C8	1.793(3)	C8–O8	1.157(4)
Fe3–C9	1.783(3)	C9–O9	1.148(4)
Fe3–C10	1.781(3)	C10–O10	1.147(4)
Fe3–C11	1.785(3)	C11–O11	1.157(4)
Fe3–C12	1.782(3)	C12–O12	1.155(4)
Cd1–Fe2	2.5679(4)	Cd1–O13	2.475(2)
Cd1–Fe3	2.5803(4)	Cd2–O14	2.476(2)
Cd2–Fe1	2.6201(4)	Cd2–O15	2.415(2)
Cd2–Fe3	2.6350(4)	Cd3–O16	2.406(2)
Cd3–Fe1	2.6466(5)	Cd3–O17	2.372(2)
Cd3–Fe2	2.6501(5)
Bond angles
Fe1–Cd2–Fe3	143.34(2)	C1–Fe1–C2	93.94(14)
Fe1–Cd3–Fe2	139.03(2)	C3–Fe1–C4	139.09(15)
Fe2–Cd1–Fe3	157.27(2)	C5–Fe2–C6	98.22(14)
Cd1–Fe2–Cd3	87.13(1)	C7–Fe2–C8	146.31(14)
Cd1–Fe3–Cd2	84.41(1)	C9–Fe3–C10	98.94(14)
Cd2–Fe1–Cd3	99.79(1)	C11–Fe3–C12	147.61(14)
Cd1–Fe2–C6	84.22(10)	Cd2–Fe3–C9	86.73(10)
Cd1–Fe3–C10	98.93(10)	Cd3–Fe1–C1	88.22(11)
Cd2–Fe1–C2	78.15(9)	Cd3–Fe2–C5	90.41(11)
O14–Cd2–O15	87.35(8)	O16–Cd3–O17	83.27(8)
O13–Cd1–Fe2	99.80(6)	O13–Cd1–Fe3	102.83(6)