Synthesis, Characterization, and X-Ray Crystal Structure of Bis(O-amyl dithiocarbonato-κ²S,S′)bis(4-cyanopyridine-κN)nickel(II)

Table 1

Crystallographic data for the title compound.

CCDC number	893165
Empirical formula	C24H30N4O2S4Ni
Formula weight	593.47
Temperature (K)	293(2)
Shape	Block shaped
Color	Dark green
Crystal system	Orthorhombic
Space group	P b c a
Unit cell dimensions (Å, °)
𝑎	11.455(5)
𝑏	9.602(4)
𝑐	26.374(1)
𝛼	90.00
𝛽	90.00
𝛾	90.00
Volume (Å^3), Z	2900.8(2), 4
Dimension (mm^3)	0.30×0.20×0.20
𝐷𝑐 (gcm^−3)	1.359
𝜇 (mm^−1)	0.984
𝐹 (000)	1240
2𝜃 range for data collection (°)	3.56–26.00
Limiting indices	−14<ℎ<14
	−11<𝑘<11
	−32<𝑙<32
Reflection collected	18668
Independent reflection	2850
Goodness-of-fit on 𝐹^2	1.104
Data/restraint/parameter	2850/6/179
Final 𝑅 indices [𝐼>2𝜎(𝐼)]	0.0499
𝑅 indices (all data)	0.0781
Largest difference peak and hole (e nm^−3)	358 and −263