Crystal Structure, Spectral Studies, and Hirshfeld Surfaces Analysis of 5-Methyl-5H-dibenzo[b,f]azepine and 5-(4-Methylbenzyl)-5H-dibenzo[b,f]azepine

Table 2

Intermolecular interactions geometry [Å, °].

D–H⋯A	D–H (Å)	H–A (Å)	D–A (Å)	D–H⋯A(°)
1
C12–H12⋯Cg(1)^iii	2.895	0.9300	3.775 (12)	166.41
2
C3–H3⋯Cg(1)^i	2.990	0.7613	3.7513 (15)	141
C7–H7⋯Cg(2)^ii	2.880	0.8726	3.7526 (14)	156
C8–H8⋯Cg(1)^ii	2.620	0.8787	3.4987 (14)	159

ⁱ𝑥−1/2, 𝑦−1/2, and 𝑧; ⁱⁱ𝑥−1, 𝑦+1/2, and 𝑧−1/2; ⁱⁱⁱ−𝑥, 𝑦−2, and 𝑧−1/2.