Table of Contents
Journal of Crystallography
Volume 2015 (2015), Article ID 312963, 4 pages
http://dx.doi.org/10.1155/2015/312963
Research Article

Solid State Structure of Bis[(bromo)(dicyclopentadienyl)vanadium(μ2-fluoro)][(bromo)(cyclopentadienyl)vanadium][tetrafluoroborate]

Department of Chemistry, University of Utah, 315 S. 1400 E., Room 2020, Salt Lake City, UT 84112-0850, USA

Received 14 October 2015; Accepted 12 November 2015

Academic Editor: Mehmet Akkurt

Copyright © 2015 Lisa M. Chan et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. G. Wilkinson and J. M. Birmingham, “Bis-cyclopentadienyl compounds of Ti, Zr, V, Nb and Ta,” Journal of the American Chemical Society, vol. 76, no. 17, pp. 4281–4284, 1954. View at Publisher · View at Google Scholar · View at Scopus
  2. S. P. Mishra, S. N. Singh, J. C. Evans, and C. C. Rowlands, “Isolation and EPR studies in dibromobis(η-cyclopentadienyl)vanadum,” Journal of Molecular Structure, vol. 112, no. 1-2, pp. 59–64, 1984. View at Publisher · View at Google Scholar
  3. M. Morán, “Synthesis and characterization of cyclopentadienyl transition metal halides, part I, vanadium halides,” Transition Metal Chemistry, vol. 6, no. 1, pp. 42–44, 1981. View at Publisher · View at Google Scholar · View at Scopus
  4. I. Klepalová, J. Honzíček, J. Vinklárek, Z. Padělková, L. Šebestová, and M. Řezáčová, “Vanadocene and niobocene dihalides containing electron-withdrawing substituents in the cyclopentadienyl rings: synthesis, characterization and cytotoxicity,” Inorganica Chimica Acta, vol. 402, pp. 109–115, 2013. View at Publisher · View at Google Scholar
  5. N. Tzavellas, N. Kloluras, and C. P. Raptopoulou, “New 1,1′-ring-substituted vanadocene dichlorides. Crystal structures of [V(η5-C5H4SiMe3)2Cl2] and [V(η5-C5H5)2Cl2],” Zeitschrift für Anorganische und Allgemeine Chemie, vol. 622, no. 5, pp. 898–902, 1996. View at Publisher · View at Google Scholar
  6. J. Honzíček, J. Vinklárek, I. Císařová, and M. Erben, “Synthesis and structural investigation of vanadocene(IV) complexes of non-linear pseudohalides,” Inorganica Chimica Acta, vol. 362, no. 1, pp. 83–88, 2009. View at Publisher · View at Google Scholar
  7. J. L. Petersen and L. F. Dahl, “Synthesis and structural characterization by x-ray diffraction and EPR single-crystal techniques of (dichloro)bis(η5-methylcyclopentadienyl)vanadium and (dichloro)bis(η5-methylcyclopentadienyl)titanium. Spatial distribution of the unpaired electron in a V(η5-C5H5)2L2-type complex,” Journal of the American Chemical Society, vol. 97, no. 22, pp. 6422–6433, 1975. View at Publisher · View at Google Scholar
  8. J. A. Belot, R. D. McCullough, A. L. Rheingold, and G. P. A. Yap, “A facile and efficient method for preparing ring-alkylated vanadocenes (RCp)2V and mono- and dichlorides of ring-alkylated vanadocenes (RCp)2VCl and (RCp)2VCl2,” Organometallics, vol. 15, no. 23, pp. 5062–5065, 1996. View at Publisher · View at Google Scholar
  9. P. Gowik, T. Klapötke, and U. Thewalt, “Metallocen-chemie hochfluorierter ligand-systeme XI. Synthese und charakterisierung von Cp2Ti(SbF6)2 und Cp2Ti(Sb2F11)2; struktur von Cp2Ti(SbF6)2 und Cp2V(SbF6)2,” Journal of Organometallic Chemistry, vol. 385, no. 3, pp. 345–350, 1990. View at Publisher · View at Google Scholar
  10. P. Gowik, T. Klapötke, K. Siems, and U. Thewalt, “Organo-übergangsmetall-chemie hochfluorierter ligand-systeme: vanadocenhexafluoroarsenat-komplexe: struktur von Cp2V(AsF6)2 und 51V-NMR von [Cp2VCl2]+[AsF6],” Journal of Organometallic Chemistry, vol. 431, no. 1, pp. 47–53, 1992. View at Publisher · View at Google Scholar
  11. R. Sustmann and G. Kopp, “Reactions of vanadocene with aliphatic halides,” Journal of Organometallic Chemistry, vol. 347, no. 3, pp. 325–332, 1988. View at Publisher · View at Google Scholar · View at Scopus
  12. S. Scholz, M. Scheibitz, F. Schödel, M. Bolte, M. Wagner, and H.-W. Lerner, “Difference in reactivity of triel halides EX3 towards ferrocene,” Inorganica Chimica Acta, vol. 360, no. 10, pp. 3323–3329, 2007. View at Publisher · View at Google Scholar · View at Scopus
  13. A. Altomare, M. C. Burla, M. Camalli et al., “SIR97: a new tool for crystal structure determination and refinement,” Journal of Applied Crystallography, vol. 32, no. 1, pp. 115–119, 1999. View at Publisher · View at Google Scholar · View at Scopus
  14. G. M. Sheldrick, SHELXL97, Programs for Crystal Structure Analysis, University of Göttingen, Göttingen, Germany, 1997.
  15. International Tables for Crystallography, vol. C, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1992.
  16. B. F. Fieselmann and G. D. Stucky, “The crystal structure of dicyclopentadienylvanadium monochloride and its implications for the structures of other d2 dicyclopentadienyl compounds,” Journal of Organometallic Chemistry, vol. 137, no. 1, pp. 43–54, 1977. View at Publisher · View at Google Scholar · View at Scopus
  17. C. E. Johnson, E. A. Kysor, M. Findlater et al., “The synthesis and characterization of [IMesH]+[(η3-C5H5)V(N)Cl2]: an anionic vanadium(v) complex with a terminal nitrido ligand,” Dalton Transactions, vol. 39, no. 14, pp. 3482–3488, 2010. View at Publisher · View at Google Scholar · View at Scopus
  18. D. B. Morse, T. B. Rauchfuss, and S. R. Wilson, “Highly oxidizing organometallics: the preparation of magnetic charge transfer salts derived from (MeCp)VCl3,” Journal of the American Chemical Society, vol. 110, no. 8, pp. 2646–2648, 1988. View at Publisher · View at Google Scholar · View at Scopus
  19. D. B. Morse, D. N. Hendrickson, T. B. Rauchfuss, and S. R. Wilson, “Highly oxidizing organometallics: physicochemical characterization of (methylcyclopentadienyl)vanadium(IV) trichloride and related vanadium(III) and titanium(III) derivatives,” Organometallics, vol. 7, no. 2, pp. 496–502, 1988. View at Publisher · View at Google Scholar · View at Scopus
  20. M. S. Hammer and L. Messerle, “Solution and solid-state structures of the monomeric, piano-stool mono(peralkylcyclopentadienyl)vanadium(IV) trihalides,” Inorganic Chemistry, vol. 29, no. 9, pp. 1780–1782, 1990. View at Publisher · View at Google Scholar · View at Scopus
  21. D. B. Morse, T. B. Rauchfuss, and S. R. Wilson, “Studies on organometallic oxidants: structure, redox properties, and magnetism of tribromo- and triodo(cyclopentadienyl)vanadium,” Inorganic Chemistry, vol. 30, no. 4, pp. 775–778, 1991. View at Publisher · View at Google Scholar
  22. R. Basta, A. M. Arif, and R. D. Ernst, “Higher valent metal pentadienyl chemistry: syntheses, structures, and reactions of Zr(6,6-dmch)2X2 complexes (dmch = dimethylcyclohexadienyl; X = Cl, Br, I) and related species,” Organometallics, vol. 24, pp. 3974–3981, 2005. View at Publisher · View at Google Scholar