Table of Contents
Journal of Fuels
Volume 2014, Article ID 914856, 12 pages
http://dx.doi.org/10.1155/2014/914856
Research Article

Evaluation of Thermal Evolution Profiles and Estimation of Kinetic Parameters for Pyrolysis of Coal/Corn Stover Blends Using Thermogravimetric Analysis

1Consortium for Fossil Fuel Science, Department of Chemical and Materials Engineering, University of Kentucky, Lexington, KY 40508, USA
2Department of Mining Engineering, University of Kentucky, Lexington, KY 40508, USA

Received 17 October 2013; Revised 31 December 2013; Accepted 11 February 2014; Published 19 March 2014

Academic Editor: Despina Vamvuka

Copyright © 2014 Abhijit Bhagavatula et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. P. Basu, Biomass Gasification and Pyrolysis: Practical Design and Theory, Elsevier, New York, NY, USA, 2010.
  2. R. C. Brown, Biorenewable Resources: Engineering New Products from Agriculture, Blackwell Publishing, Southampton, UK, 1st edition, 2003.
  3. R. Fernando, Fuels for Biomass Co-Firing, IEA Coal Research, London, UK, 2005.
  4. C. D. Di Blasi, G. Signorelli, and G. Portoricco, “Countercurrent fixed-bed gasification of biomass at laboratory scale,” Industrial and Engineering Chemistry Research, vol. 38, no. 7, pp. 2571–2581, 1999. View at Google Scholar · View at Scopus
  5. G. Gordillo, K. Annamalai, and N. Carlin, “Adiabatic fixed-bed gasification of coal, dairy biomass, and feedlot biomass using an air-steam mixture as an oxidizing agent,” Renewable Energy, vol. 34, no. 12, pp. 2789–2797, 2009. View at Publisher · View at Google Scholar · View at Scopus
  6. D. L. Klass, Biomass for Renewable Energy, Fuels, and Chemicals, Academic Press, San Diego, Calif, USA, 1998.
  7. America's Energy Future Panel on Alternative Transportation Fuels, Liquid Transportation Fuels from Coal and Biomass: Technological Status, Costs, and Environmental Impacts, The National Academic Press, Washington, DC, USA, 2009.
  8. M. J. Prins, K. J. Ptasinski, and F. J. J. G. Janssen, “From coal to biomass gasification: comparison of thermodynamic efficiency,” Energy, vol. 32, no. 7, pp. 1248–1259, 2007. View at Publisher · View at Google Scholar · View at Scopus
  9. R. Fernando, “Co-gasification and indirect co-firing of coal and biomass,” in Profiles, pp. 9–14, IEA Clean Coal Centre, 2009. View at Google Scholar
  10. A. K. Sadhukhan, P. Gupta, T. Goyal, and R. K. Saha, “Modelling of pyrolysis of coal-biomass blends using thermogravimetric analysis,” Bioresource Technology, vol. 99, no. 17, pp. 8022–8026, 2008. View at Publisher · View at Google Scholar · View at Scopus
  11. J. Bu, Kinetic Analysis of Coal and Biomass Co-Gasification with Carbon Dioxide, West Virginia University, 2009.
  12. C. Higman and M. van der Burgt, Gasification, Elsevier, New York, NY, USA, 2008.
  13. K. Liu, C. Song, and V. Subramani, Hydrogen and Syngas Production and Purification Technologies, John Wiley & Sons, New York, NY, USA, 2010.
  14. S. Dutta, C. Y. Wen, and R. J. Belt, “Reactivity of coal and char. 1. In carbon dioxide atmosphere,” Industrial and Engineering Chemistry Process Design and Development, vol. 16, no. 1, pp. 20–30, 1977. View at Google Scholar · View at Scopus
  15. E. Sima-Ella, G. Yuan, and T. Mays, “A simple kinetic analysis to determine the intrinsic reactivity of coal chars,” Fuel, vol. 84, no. 14-15, pp. 1920–1925, 2005. View at Publisher · View at Google Scholar · View at Scopus
  16. C. Di Blasi, “Modeling chemical and physical processes of wood and biomass pyrolysis,” Progress in Energy and Combustion Science, vol. 34, no. 1, pp. 47–90, 2008. View at Publisher · View at Google Scholar · View at Scopus
  17. A. K. Sadhukhan, P. Gupta, and R. K. Saha, “Modelling and experimental studies on pyrolysis of biomass particles,” Journal of Analytical and Applied Pyrolysis, vol. 81, no. 2, pp. 183–192, 2008. View at Publisher · View at Google Scholar · View at Scopus
  18. J. Cai, Y. Wang, L. Zhou, and Q. Huang, “Thermogravimetric analysis and kinetics of coal/plastic blends during co-pyrolysis in nitrogen atmosphere,” Fuel Processing Technology, vol. 89, no. 1, pp. 21–27, 2008. View at Publisher · View at Google Scholar · View at Scopus
  19. P. Ahuja, S. Kumar, and P. C. Singh, “A model for primary and heterogeneous secondary reactions of wood pyrolysis,” Chemical Engineering and Technology, vol. 19, no. 3, pp. 272–282, 1996. View at Google Scholar · View at Scopus
  20. A. W. Coats and J. P. Redfern, “Kinetic parameters from thermogravimetric data,” Nature, vol. 201, no. 4914, pp. 68–69, 1964. View at Publisher · View at Google Scholar · View at Scopus
  21. W. de Jong, G. Di Nola, B. C. H. Venneker, H. Spliethoff, and M. A. Wójtowicz, “TG-FTIR pyrolysis of coal and secondary biomass fuels: determination of pyrolysis kinetic parameters for main species and NOx precursors,” Fuel, vol. 86, no. 15, pp. 2367–2376, 2007. View at Publisher · View at Google Scholar · View at Scopus
  22. C. A. Koufopanos, N. Papayannakos, G. Maschio, and A. Lucchesi, “Modelling of the pyrolysis of biomass particles. Studies on kinetics, thermal and heat transfer effects,” Canadian Journal of Chemical Engineering, vol. 69, no. 4, pp. 907–915, 1991. View at Google Scholar · View at Scopus
  23. L. Zhou, Y. Wang, Q. Huang, and J. Cai, “Thermogravimetric characteristics and kinetic of plastic and biomass blends co-pyrolysis,” Fuel Processing Technology, vol. 87, no. 11, pp. 963–969, 2006. View at Publisher · View at Google Scholar · View at Scopus
  24. T. Hatakeyama and F. X. Quinn, Thermal Analysis—Fundamentals and Applications to Polymer Science, John Wiley & Sons, Chichester, UK, 1999.
  25. H. E. Kissinger, “Reaction kinetics in differential thermal analysis,” Analytical Chemistry, vol. 29, no. 11, pp. 1702–1706, 1957. View at Google Scholar · View at Scopus
  26. E. S. Freeman and B. Carroll, “The application of thermoanalytical techniques to reaction kinetics. The thermogravimetric evaluation of the kinetics of the decomposition of calcium oxalate monohydrate,” Journal of Physical Chemistry, vol. 62, no. 4, pp. 394–397, 1958. View at Google Scholar · View at Scopus
  27. A. Jerez, “A modification to the Freeman and Carroll method for the analysis of the kinetics of non-isothermal processes,” Journal of Thermal Analysis, vol. 26, no. 2, pp. 315–318, 1983. View at Publisher · View at Google Scholar · View at Scopus
  28. J. Fermoso, B. Arias, M. V. Gil et al., “Co-gasification of different rank coals with biomass and petroleum coke in a high-pressure reactor for H2-rich gas production,” Bioresource Technology, vol. 101, no. 9, pp. 3230–3235, 2010. View at Publisher · View at Google Scholar · View at Scopus
  29. S. Gopalakrishnan and R. Sujatha, “Comparative thermoanalytical studies of polyurethanes using Coats-Redfern, Broido and Horowitz-Metzger methods,” Der Chemica Sinica, vol. 2, no. 5, pp. 103–117, 2011. View at Google Scholar
  30. S. Syed, R. Qudaih, I. Talab, and I. Janajreh, “Kinetics of pyrolysis and combustion of oil shale sample from thermogravimetric data,” Fuel, vol. 90, no. 4, pp. 1631–1637, 2011. View at Publisher · View at Google Scholar · View at Scopus
  31. “Introduction Department of Energy Coal Sample Bank & Database,” http://www.energy.psu.edu/copl/doesb.html.
  32. ASTM Standard D7582-12, Standard Test Methods for Proximate Analysis of Coal and Coke by Macro Thermogravimetric Analysis, ASTM International, West Conshohocken, Pa, USA, 2013.
  33. ASTM Standard D5373-08, Standard Test Methods for Determination of Carbon, Hydrogen and Nitrogen in Analysis Samples of Coal and Carbon in Analysis Samples of Coal and Coke, ASTM International, West Conshohocken, Pa, USA, 2013.
  34. ASTM Standard D4239-12, Standard Test Method for Sulfur in the Analysis Sample of Coal and Coke Using High-Temperature Tube Furnace Combustion, ASTM International, West Conshohocken, Pa, USA, 2013.
  35. S. S. Idris, N. A. Rahman, K. Ismail, A. B. Alias, Z. A. Rashid, and M. J. Aris, “Investigation on thermochemical behaviour of low rank Malaysian coal, oil palm biomass and their blends during pyrolysis via thermogravimetric analysis (TGA),” Bioresource Technology, vol. 101, no. 12, pp. 4584–4592, 2010. View at Publisher · View at Google Scholar · View at Scopus
  36. Y. Sun, A. Mukherjee, O. Kuznetsov, R. Thaner, L. B. Alemany, and W. E. Billups, “Functionalization by reductive alkylation and mapping of a subbituminous coal by energy dispersive X-ray spectroscopy,” Energy and Fuels, vol. 25, no. 4, pp. 1571–1577, 2011. View at Publisher · View at Google Scholar · View at Scopus
  37. M. Jeguirim and G. Trouvé, “Pyrolysis characteristics and kinetics of Arundo donax using thermogravimetric analysis,” Bioresource Technology, vol. 100, no. 17, pp. 4026–4031, 2009. View at Publisher · View at Google Scholar · View at Scopus
  38. H. B. Vuthaluru, “Investigations into the pyrolytic behaviour of coal/biomass blends using thermogravimetric analysis,” Bioresource Technology, vol. 92, no. 2, pp. 187–195, 2004. View at Publisher · View at Google Scholar · View at Scopus
  39. A. O. Aboyade, J. F. Görgens, M. Carrier, E. L. Meyer, and J. H. Knoetze, “Thermogravimetric study of the pyrolysis characteristics and kinetics of coal blends with corn and sugarcane residues,” Fuel Processing Technology, vol. 106, pp. 310–320, 2013. View at Publisher · View at Google Scholar
  40. E. Biagini, F. Lippi, L. Petarca, and L. Tognotti, “Devolatilization rate of biomasses and coal-biomass blends: an experimental investigation,” Fuel, vol. 81, no. 8, pp. 1041–1050, 2002. View at Publisher · View at Google Scholar · View at Scopus
  41. S. Yaman and H. Haykiri-Acma, “Synergy in devolatilization characteristics of lignite and hazelnut shell during co-pyrolysis,” Fuel, vol. 86, no. 3, pp. 373–380, 2007. View at Publisher · View at Google Scholar · View at Scopus
  42. S. Yaman and H. Haykiri-Acma, “Interaction between biomass and different rank coals during co-pyrolysis,” Renewable Energy, vol. 35, no. 1, pp. 288–292, 2010. View at Publisher · View at Google Scholar · View at Scopus
  43. C. Meesri and B. Moghtaderi, “Lack of synergetic effects in the pyrolytic characteristics of woody biomass/coal blends under low and high heating rate regimes,” Biomass and Bioenergy, vol. 23, no. 1, pp. 55–66, 2002. View at Publisher · View at Google Scholar · View at Scopus