Research Article

Magmatism in the Asunción-Sapucai-Villarrica Graben (Eastern Paraguay) Revisited: Petrological, Geophysical, Geochemical, and Geodynamic Inferences

Table 5

Average chemical analyses (recalculated to 100 wt% on anhydrous basis; in parentheses, standard deviation) of mantle xenoliths (LK and HK suites, K2O <0.15 wt%, and >0.2 wt%, resp.from ASV [53, 54, 56]. The age is the average of ages of Table 4. The bleb is a representative glassy drop in an H-K harzburgite [54, 56].

Whol-rock L-K L-K H-K H-KH-K
lherzoliteharzburgitelherzoliteharzburgitebleb

No. of samples (5) (6) (3) (2) (1)
Wt%
 SiO244.02 (1.15)43.95 (0.35)44.65 (0.11)44.63 (0.20)46.15
 TiO20.03 (0.02)0.01 (0.00)0.07 (0.03)0.02 (0.00)0.70
 Al2O31.76 (0.86)1.14 (0.50)2.37 (0.04)1.36 (0.03)10.10
 FeOtot7.97 (0.13)7.85 (0.22)7.92 (0.24)7.52 (0.01)6.74
 MnO0.12 (0.01)0.11 (0.00)0.11 (0.01)0.11 (0.00)0.14
 MgO44.17 (1.87)45.58 (1.60)41.55 (0.46)44.76 (0.21)23.67
 CaO1.75 (0.86)1.18 (0.69)2.64 (0.23)1.12 (0.02)6.56
 Na2O 0.12 (0.01)0.10 (0.05)0.28 (0.01)0.16 (0.01)2.00
 K2O 0.09 (0.04)0.06 (0.04)0.39 (0.10)0.32 (0.00)3.10
 P2O50.21 (0.10)0.01 (0.01)0.01 (0.00)0.02 (0.00)0.83
ppm
 La1.69 (0.12)2.87 (0.51)2.66 (0.52)6.71 (0.69)77.39
 Ce1.53 (0.09)4.09 (0.75)3.35 (0.67)8.45 (0.81)106.25
 Nd0.20 (0.01)0.28 (0.16)0.96 (0.55)2.42 (0.25)27.74
 Sm0.012 (0.004)0.038 (0.015)0.260 (0.014)0.51 (0.20)4.16
 Eu0.001 (0.001)0.006 (0.002)0.010 (0.01)0.020 (0.006)1.00
 Gd0.07 (0.008)0.04 (0.01)0.37 (0.02) 0.74 (0.03)2.92
 Dy0.10 (0.01)0.05 (0.01)0.43 (0.02)0.91 (0.04)2.61
 Er0.07 (0.001)0.05 (0.01)0.30 (0.01)0.65 (0.06)1.68
 Yb0.07 (0.001)0.08 (0.01)0.29 (0.01)0.63 (0.03)1.23
 Lu
 Cr2601 (350)2421 (357)2360 (88)2635 (30)38114
 Ni2307 (160)2309 (102)2120 (4)2307 (73)1124
 Rb3.33 (9.51)2.67 (1.63)7.50 (2.12)6.00 (1.41)120
 Sr22.41 (10.47)11.15 (4.58)28.89 (10.29)64.67 (7.62)1414
 Ba20.0 (10.0)4.67 (1.18)40 (8)34.5 (14.8)1781
 Th
 U
 Ta
 Nb5.91 (0.58)1.78 (0.20)6.39 (1.77)6.98 (1.01)155
 Zr5.95 (0.41)6.08 (0.45)6.90 (0.13)7.86 (0.93)189
 Y0.51 (0.10)0.72 (0.09)2.62 (0.09)5.70 (1.08)14.70
Measured
  (87Sr/86Sr)0.70426 (0.00005)0.70421 (0.00038)0.70416 (0.00006)0.70395 (0.00002)
  (143Nd/144Nd) 0.51264 (0.00007)0.51275 (0.00039)0.51299 (0.00033)0.51288 (0.00005)
 Age
Initial ratio
 (87Sr/86Sr)i0.703980.703760.703670.70377
  (143Nd/144Nd)i0.512630.512720.512940.51285
427448446453
Sr
Nd1.062.927.085.16