Research Article
Synthesis, Crystal Structures, and Magnetic Properties of Ternary M(II)-Dicyanamide-hydroxypyridine Complexes
Table 1
Crystal and structure refinement for compounds 1–3.
| | Compound | 1 | 2 | 3 |
| | Formula | C16H14CoN8O2 | C10H7CuN7O | C11H9MnN7O | | Formula mass | 409.28 | 304.77 | 310.19 | | Cryst. syst. | Monoclinic | Triclinic | Monoclinic | | Space group | C2/c | P-1 | P21/c | | (Å) | 18.5091 (19) | 7.4025 (10) | 12.828 (3) | | (Å) | 7.8876 (8) | 7.5004 (9) | 8.0561 (18) | | (Å) | 14.0965 (15) | 11.4982 (15) | 12.982 (3) | | (°) | 90.00 | 78.557 (2) | 90.00 | | (°) | 118.124 (2) | 89.574 (2) | 103.162 (5) | | (°) | 90.00 | 72.701 (2) | 90.00 | | (Å3) | 1815.0 (3) | 596.50 (13) | 1306.4 (5) | | 4 | 2 | 4 | | (K) | 293 (2) | 293 (2) | 293 (2) | | (000) | 836 | 306 | 628 | | Dc (g cm−3) | 1.498 | 1.697 | 1.577 | | (mm−1) | 0.975 | 1.834 | 1.017 | | Final indexes [] | 0.0319, 0.0832 | 0.0391, 0.0926 | 0.0488, 0.1032 | | Final R indexes [all data] | 0.0345, 0.0847 | 0.0449, 0.0963 | 0.0955, 0.1219 |
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