Table of Contents
Journal of Inorganic Chemistry
Volume 2013, Article ID 902192, 8 pages
http://dx.doi.org/10.1155/2013/902192
Research Article

A Novel Approach to Prepare Well-Defined Silica-Supported Polyoxometalate Species by Reaction with a Chlorinated Support

Université Lyon 1, CPE Lyon, CNRS, UMR C2P2, LCOMS, Bâtiment CPE Curien, 43 Boulevard du 11 Novembre 1918, 69616 Villeurbanne, France

Received 25 June 2013; Accepted 19 July 2013

Academic Editor: Emmanuel Guillon

Copyright © 2013 Eva Grinenval et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. M. T. Pope, Heteropoly and Isopoly Oxometalates, Springer, Berlin, Germany, 1983.
  2. H. K. Yang, Y. X. Cheng, M. M. Su et al., “Polyoxometalate-biomolecule conjugates: a new approach to create hybrid drugs for cancer therapeutics,” Bioorganic & Medicinal Chemistry Letters, vol. 23, no. 5, pp. 1462–1466, 2013. View at Publisher · View at Google Scholar
  3. D. Liu, Y. Lu, H. Q. Tan et al., “Polyoxometalate-based purely inorganic porous frameworks with selective adsorption and oxidative catalysis functionalities,” Chemical Communications, vol. 49, no. 35, pp. 3673–3675, 2013. View at Publisher · View at Google Scholar
  4. N. Joo, S. Renaudineau, G. Delapierre et al., “Organosilyl/-germyl polyoxotungstate hybrids for covalent grafting onto silicon surfaces: towards molecular memories,” Chemistry, vol. 16, no. 17, pp. 5043–5051, 2010. View at Publisher · View at Google Scholar · View at Scopus
  5. A. Proust, B. Matt, R. Villanneau, G. Guillemot, P. Gouzerh, and G. Izzet, “Functionalization and post-functionalization: a step towards polyoxometalate-based materials,” Chemical Society Reviews, vol. 41, no. 22, pp. 7605–7622, 2012. View at Publisher · View at Google Scholar
  6. V. Dufaud and F. Lefebvre, “Inorganic hybrid materials with encapsulated polyoxometalates,” Materials, vol. 3, no. 1, pp. 682–703, 2010. View at Publisher · View at Google Scholar
  7. E. Grinenval, X. Rozanska, A. Baudouin et al., “Controlled interactions between anhydrous keggin-type heteropolyacids and silica support: preparation and characterization of well-defined silica-supported polyoxometalate species,” Journal of Physical Chemistry C, vol. 114, no. 44, pp. 19024–19034, 2010. View at Publisher · View at Google Scholar · View at Scopus
  8. A. Mazeaud, Y. Dromzee, and R. Thouvenot, “Organic—inorganic hybrids based on polyoxometalates. 6.1 Syntheses, structure, and reactivity of the Bis(tert-butylsilyl)decatungstophosphate [(γ-PW10O36)(t-BuSiOH)2]3−,” Inorganic Chemistry, vol. 39, no. 21, pp. 4735–4740, 2000. View at Publisher · View at Google Scholar · View at Scopus
  9. W. H. Knoth, “Derivatives of heteropolyanions. 1. Organic derivatives of W12SiO404-, W12PO403-, and MO12SiO404-,” Journal of the American Chemical Society, vol. 101, no. 3, pp. 759–760, 1979. View at Google Scholar · View at Scopus
  10. D. D. Perrin and W. L. F. Armarego, Purification of Laboratory Chemicals, Pergamon Press, New York, NY, USA, 3rd edition, 1988.
  11. A. Tézé and G. Hervé, “α-, β-, and γ-dodecatungstosilicic acids: isomers and related lacunary compounds,” Inorganic Syntheses, vol. 27, article 85, 1990. View at Publisher · View at Google Scholar
  12. J. Canny, A. Tézé, R. Thouvenot, and G. Hervé, “Disubstituted tungstosilicates. 1. Synthesis, stability, and structure of the lacunary precursor polyanion of a tungstosilicate .gamma.-SiW10O368-,” Inorganic Chemistry, vol. 25, pp. 2114–2119, 1986. View at Publisher · View at Google Scholar
  13. J. D. Le Grange, J. L. Markham, and C. R. Kurkjian, “Effects of surface hydration on the deposition of silane monolayers on silica,” Langmuir, vol. 9, no. 7, pp. 1749–1753, 1993. View at Google Scholar · View at Scopus
  14. C. G. Armistead, A. J. Tyler, F. H. Hambleton, S. A. Mitchell, and J. A. Hockey, “The surface hydroxylation of silica,” Journal of Physical Chemistry, vol. 73, no. 11, pp. 3947–3953, 1969. View at Google Scholar · View at Scopus
  15. M. L. Hair and W. Hertl, “Reactions of chlorosilanes with silica surfaces,” Journal of Physical Chemistry, vol. 73, no. 7, pp. 2372–2378, 1969. View at Google Scholar · View at Scopus
  16. M. L. Hair and C. P. Tripp, “Alkylchlorosilane reactions at the silica surface,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 105, no. 1, pp. 95–103, 1995. View at Google Scholar · View at Scopus
  17. C. P. Tripp, M. L. Hair, and R. P. N. Veregin, Application: US 1992-996390, Xerox Corp., Norwalk, Conn, USA, 1994.