Table of Contents
Journal of Nanoparticles
Volume 2013 (2013), Article ID 132180, 10 pages
Research Article

Selective Hydrogenation of p-Chloronitrobenzene on Nanosized PdNiB Catalysts

Department of Chemical Engineering, National Central University, Chung-Li 320, Taiwan

Received 10 January 2013; Accepted 1 February 2013

Academic Editor: Mohammad H. Maneshian

Copyright © 2013 Yu-Wen Chen and Der-Shing Lee. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


A series of PdNiB bimetallic nanoalloy catalysts with various Pd contents was prepared. Pd was well dispersed in NiB. Even adding a small amount of Pd in NiB had a significant effect on activity and selectivity in hydrogenation of p-chloronitrobenzene (p-CNB) to p-chloroaniline (p-CAN). High activity and selectivity on PdNiB could be attributed to both ensemble effect and electronic effect. The particle size in PdNiB decreased with an increase in Pd content. Electron-enriched Ni could activate the polar-NO2 groups of p-CNB and depress the dehalogenation of p-CAN.