Table of Contents
Journal of Nanoparticles
Volume 2014, Article ID 125360, 12 pages
Research Article

Preparation of Cerium Orthophosphate Nanosphere by Coprecipitation Route and Its Structural, Thermal, Optical, and Electrical Characterization

Crystal Growth and Material Research Laboratory, Department of Physics & Electronics, University of Jammu, Jammu 180006, India

Received 28 May 2014; Revised 8 August 2014; Accepted 22 August 2014; Published 16 September 2014

Academic Editor: Frank Hubenthal

Copyright © 2014 Seema Verma and K. K. Bamzai. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Cerium orthophosphate (CePO4) nanoparticles were synthesized via wet chemical coprecipitation technique using cerium nitrate hexahydrate for Ce3+ ion and ammonium dihydrogen phosphate for ion source. X-ray diffraction (XRD) analysis suggests that the material belongs to monoclinic crystal system with crystallite size of 49.3 nm. Scanning electron microscope (SEM) and transmission electron microscope (TEM) reveal the surface morphology of the prepared nanoparticles as nanospheres having grain size in the range of 30–50 nm. The energy dispersive X-ray analysis (EDAX) gives elemental composition present in the grown nanomaterial. Thermogravimetric analysis suggests that the structural phase transition is above 800°C. The optical properties include UV-VIS-NIR absorption and the photoluminescence spectrum shows the absorption and emission peaks in the ultraviolet region. The dielectric constant and ac conductivity properties were investigated with regard to change in temperature (40 to 500°C) and frequency (5 kHz to 1 MHz). The dielectric measurement indicates that the transition is diffused and the activation energy values decrease suggesting that the conduction mechanism is due to hopping of the charge carriers from one site to another.