Table of Contents
Journal of Polymers
Volume 2014, Article ID 906780, 9 pages
http://dx.doi.org/10.1155/2014/906780
Research Article

Role of Hard-Acid/Hard-Base Interaction on Structural and Dielectric Behavior of Solid Polymer Electrolytes Based on Chitosan-XCF3SO3 (X = Li+, Na+, Ag+)

1Department of Physics, Faculty of Science and Science Education, University of Sulaimani, Sulaimani City, Kurdistan Regional Government, Iraq
2Centre for Ionics University of Malaya (CIUM), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur, Malaysia

Received 6 August 2013; Accepted 17 December 2013; Published 16 January 2014

Academic Editor: Jean-Marc Saiter

Copyright © 2014 Shujahadeen B. Aziz and Zul Hazrin Z. Abidin. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. G. Rajasudha, L. M. Jayan, D. Durga Lakshmi et al., “Polyindole-CuO composite polymer electrolyte containing LiClO4 for lithium ion polymer batteries,” Polymer Bulletin, vol. 68, no. 1, pp. 181–196, 2012. View at Publisher · View at Google Scholar · View at Scopus
  2. A. M. Stephan, “Review on gel polymer electrolytes for lithium batteries,” European Polymer Journal, vol. 42, no. 1, pp. 21–42, 2006. View at Publisher · View at Google Scholar · View at Scopus
  3. S. Zhou and S. Fang, “High ionic conductivity of all-solid polymer electrolytes based on polyorganophosphazenes,” European Polymer Journal, vol. 43, no. 8, pp. 3695–3700, 2007. View at Publisher · View at Google Scholar · View at Scopus
  4. A. Bhide and K. Hariharan, “Ionic transport studies on (PEO)6:NaPO3 polymer electrolyte plasticized with PEG400,” European Polymer Journal, vol. 43, no. 10, pp. 4253–4270, 2007. View at Publisher · View at Google Scholar · View at Scopus
  5. W. Li, M. Yuan, and M. Yang, “Dual-phase polymer electrolyte with enhanced phase compatibility based on Poly(MMA-g-PVC)/PMMA,” European Polymer Journal, vol. 42, no. 6, pp. 1396–1402, 2006. View at Publisher · View at Google Scholar · View at Scopus
  6. H. Mitsuda, T. Uno, M. Kubo, and T. Itoh, “Solid polymer electrolytes based on poly(1,3-diacetyl-4-imidazolin-2-one),” Polymer Bulletin, vol. 57, no. 3, pp. 313–319, 2006. View at Publisher · View at Google Scholar · View at Scopus
  7. P.-L. Kuo, W.-J. Liang, and T.-Y. Chen, “Solid polymer electrolytes V: microstructure and ionic conductivity of epoxide-crosslinked polyether networks doped with LiClO4,” Polymer, vol. 44, no. 10, pp. 2957–2964, 2003. View at Publisher · View at Google Scholar · View at Scopus
  8. C. Tan, W. He, H. Meng, and X. Huang, “A novel titration method based on fiber-optic refractive index sensing for the determination of deacetylation degree of chitosans,” Polymer Bulletin, vol. 69, pp. 189–197, 2012. View at Publisher · View at Google Scholar · View at Scopus
  9. P. Agrawal, G. J. Strijkers, and K. Nicolay, “Chitosan-based systems for molecular imaging,” Advanced Drug Delivery Reviews, vol. 62, no. 1, pp. 42–58, 2010. View at Publisher · View at Google Scholar · View at Scopus
  10. P. Bai, F. Cao, X. Lan, F. Zhao, Y. Ma, and C. Zhao, “Chitosan gel beads immobilized Cu (II) for selective adsorption of amino acids,” Journal of Biochemical and Biophysical Methods, vol. 70, no. 6, pp. 903–908, 2008. View at Publisher · View at Google Scholar · View at Scopus
  11. G. Lu, L. Kong, B. Sheng, G. Wang, Y. Gong, and X. Zhang, “Degradation of covalently cross-linked carboxymethyl chitosan and its potential application for peripheral nerve regeneration,” European Polymer Journal, vol. 43, no. 9, pp. 3807–3818, 2007. View at Publisher · View at Google Scholar · View at Scopus
  12. S. L. Agrawal, M. Singh, M. Tripathi, M. M. Dwivedi, and K. Pandey, “Dielectric relaxation studies on [PEO-SiO2]:NH4SCN nanocomposite polymer electrolyte films,” Journal of Materials Science, vol. 44, no. 22, pp. 6060–6068, 2009. View at Publisher · View at Google Scholar · View at Scopus
  13. S. B. Aziz and Z. H. Z. Abidin, “Electrical conduction mechanism in solid polymer electrolytes: new concepts to arrhenius equation,” Journal of Soft Matter, vol. 2013, Article ID 323868, 8 pages, 2013. View at Publisher · View at Google Scholar
  14. F. Yuan, Z. Peng, and J.-M. Liu, “Dielectric behaviors of relaxor ferroelectric Pb(Mg1/2Nb1/2)O3−35% PbTiO3: temperature and frequency dependences,” Materials Science and Engineering B, vol. 117, no. 3, pp. 265–270, 2005. View at Publisher · View at Google Scholar · View at Scopus
  15. S. B. Aziz, “Li+ ion conduction mechanism in poly (ε-caprolactone)-based polymer electrolyte,” Iranian Polymer Journal, vol. 22, pp. 877–883, 2013. View at Publisher · View at Google Scholar
  16. S. B. Aziz, Z. H. Z. Abidin, and A. K. Arof, “Effect of silver nanoparticles on the DC conductivity in chitosansilver triflate polymer electrolyte,” Physica B, vol. 405, no. 21, pp. 4429–4433, 2010. View at Publisher · View at Google Scholar · View at Scopus
  17. J. Malathi, M. Kumaravadivel, G. M. Brahmanandhan, M. Hema, R. Baskaran, and S. Selvasekarapandian, “Structural, thermal and electrical properties of PVA-LiCF3SO3 polymer electrolyte,” Journal of Non-Crystalline Solids, vol. 356, pp. 2277–2281, 2010. View at Publisher · View at Google Scholar · View at Scopus
  18. K. C. Khulbe, T. Matsuura, G. Lamarche, and A.-M. Lamarche, “X-ray diffraction analysis of dense PPO membranes,” Journal of Membrane Science, vol. 170, no. 1, pp. 81–89, 2000. View at Publisher · View at Google Scholar · View at Scopus
  19. R. P. Suvarna, K. R. Rao, and K. Subbarangaiah, “A simple technique for a.c. conductivity measurements,” Bulletin of Materials Science, vol. 25, no. 7, pp. 647–651, 2002. View at Google Scholar · View at Scopus
  20. A. S. A. Khiar, R. Puteh, and A. K. Arof, “Conductivity studies of a chitosan-based polymer electrolyte,” Physica B, vol. 373, no. 1, pp. 23–27, 2006. View at Publisher · View at Google Scholar · View at Scopus
  21. K. P. Padmasree and D. K. Kanchan, “Modulus studies of CdI2-Ag2O-V2O5-B2O3 system,” Materials Science and Engineering B, vol. 122, no. 1, pp. 24–28, 2005. View at Publisher · View at Google Scholar · View at Scopus
  22. S. Rajendran, R. S. Babu, and P. Sivakumar, “Investigations on PVC/PAN composite polymer electrolytes,” Journal of Membrane Science, vol. 315, no. 1-2, pp. 67–73, 2008. View at Publisher · View at Google Scholar · View at Scopus
  23. F. Göktepe, S. Ü. Çelik, and A. Bozkurt, “Preparation and the proton conductivity of chitosan/poly(vinyl phosphonic acid) complex polymer electrolytes,” Journal of Non-Crystalline Solids, vol. 354, no. 30, pp. 3637–3642, 2008. View at Publisher · View at Google Scholar · View at Scopus
  24. Y. Wan, K. A. M. Creber, B. Peppley, and V. Tam Bui, “Chitosan-based solid electrolyte composite membranes—I. Preparation and characterization,” Journal of Membrane Science, vol. 280, no. 1-2, pp. 666–674, 2006. View at Publisher · View at Google Scholar · View at Scopus
  25. B. Smitha, S. Sridhar, and A. A. Khan, “Chitosan-sodium alginate polyion complexes as fuel cell membranes,” European Polymer Journal, vol. 41, no. 8, pp. 1859–1866, 2005. View at Publisher · View at Google Scholar · View at Scopus
  26. S. A. Hashmi and S. Chandra, “Experimental investigations on a sodium-ion-conducting polymer electrolyte based on poly(ethylene oxide) complexed with NaPF6,” Materials Science and Engineering B, vol. 34, no. 1, pp. 18–26, 1995. View at Google Scholar · View at Scopus
  27. R. A. Sanders, A. G. Snow, R. Frech, and D. T. Glatzhofer, “A spectroscopic and conductivity comparison study of linear poly(N-methylethylenimine) with lithium triflate and sodium triflate,” Electrochimica Acta, vol. 48, no. 14–16, pp. 2247–2253, 2003. View at Publisher · View at Google Scholar · View at Scopus
  28. M. Hema, S. Selvasekarapandian, D. Arunkumar, A. Sakunthala, and H. Nithya, “FTIR, XRD and ac impedance spectroscopic study on PVA based polymer electrolyte doped with NH4X(X = Cl, Br, I),” Journal of Non-Crystalline Solids, vol. 355, no. 2, pp. 84–90, 2009. View at Publisher · View at Google Scholar · View at Scopus
  29. P. B. Bhargav, V. M. Mohan, A. K. Sharma, and V. V. R. N. Rao, “Investigations on electrical properties of (PVA:NaF) polymer electrolytes for electrochemical cell applications,” Current Applied Physics, vol. 9, no. 1, pp. 165–171, 2009. View at Publisher · View at Google Scholar · View at Scopus
  30. S. Sunderrajan, B. D. Freeman, C. K. Hall, and I. Pinnau, “Propane and propylene sorption in solid polymer electrolytes based on poly(ethylene oxide) and silver salts,” Journal of Membrane Science, vol. 182, no. 1-2, pp. 1–12, 2001. View at Publisher · View at Google Scholar · View at Scopus
  31. I. Pinnau and L. G. Toy, “Solid polymer electrolyte composite membranes for olefin/paraffin separation,” Journal of Membrane Science, vol. 184, no. 1, pp. 39–48, 2001. View at Publisher · View at Google Scholar · View at Scopus
  32. R. J. Sengwa and S. Sankhla, “Characterization of ionic conduction and electrode polarization relaxation processes in ethylene glycol oligomers,” Polymer Bulletin, vol. 60, no. 5, pp. 689–700, 2008. View at Publisher · View at Google Scholar · View at Scopus
  33. D. K. Pradhan, R. N. P. Choudhary, and B. K. Samantaray, “Studies of structural, thermal and electrical behavior of polymer nanocomposite electrolytes,” Express Polymer Letters, vol. 2, no. 9, pp. 630–638, 2008. View at Publisher · View at Google Scholar · View at Scopus
  34. A. Bakker, S. Gejji, J. Lindgren, K. Hermansson, and M. M. Probst, “Contact ion pair formation and ether oxygen coordination in the polymer electrolytes M[N(CF3SO2)2]2PEOn for M = Mg, Ca, Sr and Ba,” Polymer, vol. 36, no. 23, pp. 4371–4378, 1995. View at Google Scholar · View at Scopus
  35. S. W. Kang, J. H. Kim, K. S. Oh et al., “Highly stabilized silver polymer electrolytes and their application to facilitated olefin transport membranes,” Journal of Membrane Science, vol. 236, no. 1-2, pp. 163–169, 2004. View at Publisher · View at Google Scholar · View at Scopus
  36. P. Y. Lim, R. S. Liu, P. L. She, C. F. Hung, and H. C. Shih, “Synthesis of Ag nanospheres particles in ethylene glycol by electrochemical-assisted polyol process,” Chemical Physics Letters, vol. 420, no. 4-6, pp. 304–308, 2006. View at Publisher · View at Google Scholar · View at Scopus
  37. J. H. Kim, B. R. Min, J. Won, and Y. S. Kang, “Anomalous temperature dependence of facilitated propylene transport in silver polymer electrolyte membranes,” Journal of Membrane Science, vol. 227, no. 1-2, pp. 197–206, 2003. View at Publisher · View at Google Scholar · View at Scopus
  38. J. H. Kim, C. K. Kim, J. Won, and Y. S. Kang, “Role of anions for the reduction behavior of silver ions in polymer/silver salt complex membranes,” Journal of Membrane Science, vol. 250, no. 1-2, pp. 207–214, 2005. View at Publisher · View at Google Scholar · View at Scopus
  39. S. H. Mun, S. W. Kang, J.-S. Cho, S.-K. Koh, and Y. S. Kang, “Enhanced olefin carrier activity of clean surface silver nanoparticles for facilitated transport membranes,” Journal of Membrane Science, vol. 332, no. 1-2, pp. 1–5, 2009. View at Publisher · View at Google Scholar · View at Scopus
  40. M. Selva Kumar and D. K. Bhat, “Polyvinyl alcohol-polystyrene sulphonic acid blend electrolyte for supercapacitor application,” Physica B, vol. 404, no. 8–11, pp. 1143–1147, 2009. View at Publisher · View at Google Scholar · View at Scopus
  41. D. K. Pradhan, R. N. P. Choudhary, and B. K. Samantaray, “Studies of dielectric relaxation and AC conductivity behavior of plasticized polymer nanocomposite electrolytes,” International Journal of Electrochemical Science, vol. 3, pp. 597–608, 2008. View at Google Scholar
  42. M. Okutan and E. Şentürk, “β Dielectric relaxation mode in side-chain liquid crystalline polymer film,” Journal of Non-Crystalline Solids, vol. 357, pp. 1526–1530, 2008. View at Publisher · View at Google Scholar
  43. K. M. Batoo, S. Kumar, C. G. Lee, and A. Alimuddin, “Study of dielectric and ac impedance properties of Ti doped Mn ferrites,” Current Applied Physics, vol. 9, no. 6, pp. 1397–1406, 2009. View at Publisher · View at Google Scholar · View at Scopus
  44. C. V. Subba Reddy, X. Han, Q.-Y. Zhu, L.-Q. Mai, and W. Chen, “Dielectric spectroscopy studies on (PVP + PVA) polyblend film,” Microelectronic Engineering, vol. 83, no. 2, pp. 281–285, 2006. View at Publisher · View at Google Scholar · View at Scopus
  45. M. S. Salem, Journal of Material Science, vol. 44, p. 5660, 2009.
  46. C. S. Ramya, S. Selvasekarapandian, G. Hirankumar, T. Savitha, and P. C. Angelo, “Investigation on dielectric relaxations of PVP-NH4SCN polymer electrolyte,” Journal of Non-Crystalline Solids, vol. 354, no. 14, pp. 1494–1502, 2008. View at Publisher · View at Google Scholar · View at Scopus
  47. K. C. Kwan, Dielectric Phenomena in Solids, Elsevier Academic Press, 2004.
  48. S. B. Aziz, Z. H. Z. Abidin, and A. K. Arof, “Influence of silver ion reduction on electrical modulus parameters of solid polymer electrolyte based on chitosan-silver triflate electrolyte membrane,” eXPRESS Polymer Letters, vol. 4, no. 5, pp. 300–310, 2010. View at Publisher · View at Google Scholar