Table of Contents
Journal of Quantum Chemistry
Volume 2014, Article ID 149380, 8 pages
http://dx.doi.org/10.1155/2014/149380
Research Article

Quantum Chemical Study of Mixed-Ligand Monometallic Ruthenium(II) Complex of Composition [(bpy)2Ru(H3Imbzim)](ClO4)2·2H2O

School of Chemical Sciences, Central University of Gujarat, Sector 30, Gandhinagar, Gujarat 382030, India

Received 29 November 2013; Revised 24 February 2014; Accepted 11 March 2014; Published 19 May 2014

Academic Editor: Yinghong Sheng

Copyright © 2014 Mohsin Yousuf Lone and Prakash Chandra Jha. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. L. Sessler, P. A. Gale, and W. S. Cho, Anion Receptor Chemistry, Royal Society of Chemistry, Cambridge, UK, 2006.
  2. R. Martinez-Manez and F. Sancenon, “Fluorogenic and chromogenic chemosensors and reagents for anions,” Chemical Reviews, vol. 103, pp. 4419–4476, 2003. View at Publisher · View at Google Scholar
  3. A. Bianchi, K. Bowman-James, and E. Garcia-Espana, Supramolecular Chemistry of Anions, Wiley-VCH, New York, NY, USA, 1997.
  4. J. M. Lehn, Supramolecular Chemistry Concepts and Perspective, Wiley-VCH, Weinheim, Germany, 1995.
  5. V. Amendola, D. Esteban-Gómez, L. Fabbrizzi, and M. Licchelli, “What anions do to N-H-containing receptors,” Accounts of Chemical Research, vol. 39, no. 5, pp. 343–353, 2006. View at Publisher · View at Google Scholar · View at Scopus
  6. C. Suksai and T. Tuntulani, “Chromogenic anion sensors,” Topics in Current Chemistry, vol. 255, pp. 163–198, 2005. View at Publisher · View at Google Scholar · View at Scopus
  7. J. Pérez and L. Riera, “Stable metal-organic complexes as anion hosts,” Chemical Society Reviews, vol. 37, no. 12, pp. 2658–2667, 2008. View at Publisher · View at Google Scholar · View at Scopus
  8. S.-T. Lam, N. Zhu, and V. W.-W. Yam, “Synthesis and characterization of luminescent rhenium(l) tricarbonyl diimine complexes with a triarylboron moiety and the study of their fluoride ion-binding properties,” Inorganic Chemistry, vol. 48, no. 20, pp. 9664–9670, 2009. View at Publisher · View at Google Scholar · View at Scopus
  9. K. L. Kirk, Biochemistry of the Halogens and Inorganic Halides, Plenum Press, New York, NY, USA, 1991.
  10. R. L. P. Adams, J. T. Knowler, and D. P. Leader, The Biochemistry of the Nucleic Acids, Chapman & Hall, New York, NY, USA, 10th edition, 1986.
  11. N. Kartner, J. W. Hanrahan, T. J. Jensen et al., “Expression of the cystic fibrosis gene in non-epithelial invertebrate cells produces a regulated anion conductance,” Cell, vol. 64, no. 4, pp. 681–691, 1991. View at Google Scholar · View at Scopus
  12. K. Renkawek and G. J. C. G. M. Bosman, “Anion exchange proteins are a component of corpora amylacea in Alzheimer disease brain,” NeuroReport, vol. 6, no. 6, pp. 929–932, 1995. View at Google Scholar · View at Scopus
  13. B. Moss, “A land awash with nutrients—the problem of eutrophication,” Chemistry and Industry, pp. 407–411, 1996. View at Google Scholar
  14. C. Glidewell, “Nitrate/nitrite controversy,” Chemistry in Britain, vol. 26, no. 2, pp. 137–140, 1990. View at Google Scholar · View at Scopus
  15. S. Ayoob and A. K. Gupta, “Fluoride in drinking water: a review on the status and stress effects,” Critical Reviews in Environmental Science and Technology, vol. 36, no. 6, pp. 433–487, 2006. View at Publisher · View at Google Scholar · View at Scopus
  16. M. Kleerekoper, “The role of fluoride in the prevention of osteoporosis,” Endocrinology and Metabolism Clinics of North America, vol. 27, no. 2, pp. 441–452, 1998. View at Publisher · View at Google Scholar · View at Scopus
  17. P. Anzebacher, D. S. Tyson, K. Jurslkova, and F. N. Castellano, “Luminescence lifetime-based sensor for cyanide and related anions,” Journal of the American Chemical Society, vol. 124, pp. 6232–6233, 2002. View at Publisher · View at Google Scholar
  18. T. Mizuno, W.-H. Wei, L. R. Eller, and J. L. Sessler, “Phenanthroline complexes bearing fused dipyrrolylquinoxaline anion recognition sites: efficient fluoride anion receptors,” Journal of the American Chemical Society, vol. 124, no. 7, pp. 1134–1135, 2002. View at Publisher · View at Google Scholar · View at Scopus
  19. P. D. Beer, F. Szemes, V. Balzani et al., “Anion selective recognition and sensing by novel macrocyclic transition metal receptor systems. 1H NMR, electrochemical, and photophysical investigations,” Journal of the American Chemical Society, vol. 119, pp. 11864–11875, 1997. View at Publisher · View at Google Scholar
  20. Y. Cui, H.-J. Mo, J.-C. Chen et al., “Anion-selective interaction and colorimeter by an optical metalloreceptor based on ruthenium(II) 2,2′-biimidazole: hydrogen bonding and proton transfer,” Inorganic Chemistry, vol. 46, no. 16, pp. 6427–6436, 2007. View at Publisher · View at Google Scholar · View at Scopus
  21. S. Debasish, D. Shyamal, B. Chanchal, D. Supriya, and B. Sujoy, “Monometallic and bimetallic ruthenium(II) complexes derived from 4,5-Bis(benzimidazol-2-yl)imidazole (H3Imbzim) and 2,2′-bipyridine as colorimetric sensors for anions: synthesis, characterization, and binding studies,” Inorganic Chemistry, vol. 49, pp. 2334–2348, 2010. View at Publisher · View at Google Scholar
  22. M. J. Frisch, G. W. Trucks, H. B. Schlegel et al., Gaussian 03 Revision B 05 Pople, Gaussian, Pittsburgh, Pa, USA, 2003.
  23. V. Barone and M. Cossi, “Quantum calculation of molecular energies and energy gradients in solution by a conductor solvent model,” Journal of Physical Chemistry A, vol. 102, no. 11, pp. 1995–2001, 1998. View at Google Scholar · View at Scopus
  24. P. J. Hay and W. R. Wadt, “Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi,” The Journal of Chemical Physics, vol. 82, no. 1, pp. 284–298, 1985. View at Google Scholar · View at Scopus
  25. C. Adamo and V. Barone, “Toward reliable density functional methods without adjustable parameters: the PBE0 model,” Journal of Chemical Physics, vol. 110, no. 13, pp. 6158–6170, 1999. View at Google Scholar · View at Scopus
  26. C. Adamo and V. Barone, “Toward reliable adiabatic connection models free from adjustable parameters,” Chemical Physics Letters, vol. 274, pp. 242–250, 1997. View at Publisher · View at Google Scholar
  27. C. Adamo and V. Barone, “Exchange functionals with improved long-range behavior and adiabatic connection methods without adjustable parameters: the mPW and mPW1PW models,” Journal of Chemical Physics, vol. 108, no. 2, pp. 664–675, 1998. View at Google Scholar · View at Scopus
  28. C. Adamo and D. Jacquemin, “The calculations of excited-state properties with time-dependent density functional theory,” Chemical Society Reviews, vol. 42, pp. 845–856, 2013. View at Publisher · View at Google Scholar
  29. J. Tomasi, B. Mennucci, and R. Cammi, “Quantum mechanical continuum solvation models,” Chemical Reviews, vol. 105, no. 8, pp. 2999–3093, 2005. View at Publisher · View at Google Scholar · View at Scopus