Journal of Soft Matter / 2014 / Article / Tab 2

Research Article

Kinetic Treatment of the Reaction of Fructose and N-Bromosuccinimide in Cationic/Anionic/Nonionic Micelles

Table 2

Effect of substrate, oxidant, solvent, and H2SO4 on .

102, fructose mol dm−3104, NBS Mol dm−3104, H2SO4 Mol dm−3%, acetic acid (v/v)104,  s−1
AqueousaCTABbSDSc

1.02.00.5300.802.00.62
2.51.113.500.86
5.01.555.401.23
10.02.08.01.63
20.02.6412.102.46
2.51.00.5301.133.540.88
2.01.113.500.86
3.01.113.500.85
4.01.103.500.84
5.01.103.490.84
2.52.00.50301.113.500.86
1.00.922.600.70
2.500.651.750.53
5.00.491.320.39
10.00.361.00.31
2.52.00.5202.095.251.0
251.824.600.95
301.113.500.86
400.662.300.77
500.481.780.65

Reaction conditions: [Hg(OAc)2] = 5.0 10−4 mol dm−3.
bReaction conditions:Hg(OAc)2 = 5.0 10−4 mol dm−3, CTAB = 1.2 10−3 mol dm−3.
cReaction conditions: Hg(OAc)2 = 5.0 10−4 mol dm−3, SDS = 1.0 10−2 mol dm−3.