Kinetic Treatment of the Reaction of Fructose and N-Bromosuccinimide in Cationic/Anionic/Nonionic Micelles

Table 2

Effect of substrate, oxidant, solvent, and H₂SO₄ on .

10^2, fructose mol dm^−3	10^4, NBS Mol dm^−3	10^4, H2SO4 Mol dm^−3	%, acetic acid (v/v)	10^4,  s^−1
				Aqueous^a	CTAB^b	SDS^c
1.0	2.0	0.5	30	0.80	2.0	0.62
2.5				1.11	3.50	0.86
5.0				1.55	5.40	1.23
10.0				2.0	8.0	1.63
20.0				2.64	12.10	2.46
2.5	1.0	0.5	30	1.13	3.54	0.88
	2.0			1.11	3.50	0.86
	3.0			1.11	3.50	0.85
	4.0			1.10	3.50	0.84
	5.0			1.10	3.49	0.84
2.5	2.0	0.50	30	1.11	3.50	0.86
		1.0		0.92	2.60	0.70
		2.50		0.65	1.75	0.53
		5.0		0.49	1.32	0.39
		10.0		0.36	1.0	0.31
2.5	2.0	0.5	20	2.09	5.25	1.0
			25	1.82	4.60	0.95
			30	1.11	3.50	0.86
			40	0.66	2.30	0.77
			50	0.48	1.78	0.65

Reaction conditions: [Hg(OAc)₂] = 5.0 10⁻⁴ mol dm⁻³.
^bReaction conditions:Hg(OAc)₂ = 5.0 10⁻⁴ mol dm⁻³, CTAB = 1.2 10⁻³ mol dm⁻³.
^cReaction conditions: Hg(OAc)₂ = 5.0 10⁻⁴ mol dm⁻³, SDS = 1.0 10⁻² mol dm⁻³.