Research Article  Open Access
Hamit Yurtseven, Koray Kaymazlar, "Temperature Dependence of the Bragg PeakIntensity Close to the Incommensurate Transition in Quartz", Journal of Solid State Physics, vol. 2014, Article ID 538540, 5 pages, 2014. https://doi.org/10.1155/2014/538540
Temperature Dependence of the Bragg PeakIntensity Close to the Incommensurate Transition in Quartz
Abstract
Quartz as a mineral has a stable crystalline phase at room temperature and atmospheric pressure; at low temperatures it is in the phase and when it is heated up, it transforms into the phase through the intermediate (incommensurate) phase within the temperature interval of nearly 1.3 K at around 847 K. The order parameter occurs due to a tilting of SiO_{4} tetrahedra around the threefold axis, which can be related to variation of the peakintensity with the temperature in quartz. In this study, we analyze the temperature dependence of the Bragg peakintensity measured through the  transition in quartz, as obtained from the literature according to a powerlaw formula. From our analysis, we deduce the values of the critical exponent for the order parameter (Bragg peakintensity) for the incommensurate (IC) transition. Our values indicate that the IC phase transition is of a second order and that the IC phase transition is of a weak first order, as also reported in the literature.
1. Introduction
Quartz (SiO_{2}) is a mineral in crystalline form or amorphous [1] with various phases. At low temperatures in the phase with symmetry , it transforms into the phase with the symmetry [2] as the temperature increases. The transition temperature between the and phases is about 847 K. This crystalline structure was discovered by Le Chatelier in 1889 [3]. Since then, a great deal of work has been devoted to quartz. A review paper [4] and some studies on the  transition in quartz have been reported in the literature [5–9].
Measurements of the heat capacity [7–9] correlated with the thermal expansion have revealed the existence of an intermediate phase (incommensurate phase) in a small temperature interval of ~1.3 K between the and phases. We have analyzed the specific heat [10, 11] and we have examined the Pippard relations for the  transition in quartz [11] using the experimental data [8].
Spectroscopic studies on the  transition in quartz have also been reported in the literature. Some earlier Raman studies [12, 13] have investigated experimentally the soft mode behaviour of the 147 cm^{−1} and 207 cm^{−1} lattice modes close to the  transition in quartz. Neutron diffraction measurements [6, 7, 14, 15] have shown that the incommensurate phase is modulated.
Change in the symmetry from the phase (low symmetry) to the phase (high symmetry) causes the order parameter in the phase to become zero in the phase. Ordering in the phase is due to a tilting of SiO_{4} tetrahedra around the threefold axis. It has been pointed out [16] that the symmetry change gives rise to the excitation of many lowfrequency highamplitude modes of vibration which is associated with the phase transition in quartz. This can be the reason for the orientational disorder of the SiO_{4} tetrahedra and the order parameter for the displacive phase transition in quartz is then defined as the angle that each SiO_{4} tetrahedron rotates about the hexagonal or trigonal 100 directions [16]. In fact, it has been observed [17] that the infraredactive phonons near 795 cm^{−1 }and 695 cm^{−1} and the Raman active mode near 355 cm^{−1} are associated with the symmetrybreaking order parameter of the  phase transition in quartz. This displacive transition in quartz is not a classical orderdisorder transition since an orientational disorder still exists below in the phase, which grows in the phase as the temperature increases [16]. It has been argued [16] that the dynamic disorder at the phase transition is not due to the fluctuations of the order parameter as in critical fluctuations, but it is due to the excitation of new lowenergy vibrations, as stated above. It has also been argued [16] that the existence of the soft mode is not because of some degree of an orderdisorder nature of the phase transition in quartz, but because of the excitation of lowenergy vibrations which couple through anharmonic interactions with the soft mode. This soft mode which drives the phase transition in quartz propagates as a phonon that moves the SiO_{4} tetrahedra as rigid units [18]. A soft mode associated with a SiO_{4} rotation, which softens in the phase, vanishes in the incommensurate phase and it hardens in the phase as the temperature increases. This has been the subject of a number of studies in quartz [6, 12, 19–22]. We have also studied the soft modes by calculating the Raman frequencies and the linewidths for the  transition in quartz [23, 24] and in SiO_{2} moganite [25].
In regard to the temperature dependence of the order parameter , in the phase at low temperatures, variation of the order parameter related to the atomic displacements can be described by the variation of the peakintensity with the temperature. The peakintensity has been measured by neutron diffraction experiments [15] at various temperatures for the  transition in quartz.
In this study, we analyze the temperature dependence of the peakintensity using the experimental data [15] by a powerlaw formula for the  transition in quartz. Below, we present our calculations and results in Section 2. In Section 3, we discuss our results and in Section 4 conclusions are given.
2. Analysis and Results
The temperature dependence of the intensity can be analyzed using a powerlaw formula close to the phase transitions. The divergence behaviour of the intensity at the transition point can be related to the order of parameter as where represents the temperature dependence of the order parameter below the transition temperature . By describing this temperature dependence using a powerlaw formula where is the critical exponent for the order parameter, the temperature dependence of the intensity can be expressed as In (3), is the amplitude. By taking the logarithm of both sides, we obtain Thus, by knowing the temperature dependence of the intensity the values of and can be determined. Value of the critical exponent characterizes the phase transition of the system studied.
In this study, we analyzed the temperature dependence of the Bragg peakintensity measured for the  transition in quartz [15] according to a powerlaw formula (3). This analysis was performed in the vicinity of the incommensurate phase (~1.3 K) between and phases for K ( phase) and K ( phase), where K as the incommensurate transition temperature of quartz.
From our analysis, we obtained the values of and for the , and incommensurate phases as given in Table 1. Figures 1 and 2 give in the heating process lnln plots of Bragg intensity as a function of temperature in the incommensurate phase. For the phase, we also plot in the lnln scale the Bragg intensity at various temperatures for the heating and cooling processes, respectively, in Figures 3 and 4. For the cooling process, Figure 5 gives our plot of versus in the incommensurate phase of quartz. For this process, we plot versus for phase in Figure 6. Finally, for the cooling process in the phase versus is plotted in Figure 7.

3. Discussion
The Bragg peakintensity was analyzed here using the experimental data [15] according to a powerlaw formula (see (3)). Values of the critical exponent for the order parameter (Bragg peakintensity) were determined for the incommensurate phase transition in quartz (Table 1). For the heating and cooling runs, values of and as given within the temperature intervals for the incommensurate transitions vary from to . This large variety of the critical exponent () characterizes first order and second order transitions occurring in quartz.
As noted previously [15], a second order transition occurs from the phase to the incommensurate phase at K. The negative values from to −0.07 (Table 1) below in the incommensurate phase should characterize a second order transition between the phase and incommensurate phase. This is due to the fact that the (022) Bragg peakintensity diverges as as the critical scattering intensity since this mode is overdamped and unstable which exhibits the soft mode behaviour. Similar soft mode behaviour has been observed [15] for the temperature dependence of the integrated scattering intensity for the (1, 0, 3) reflection in the  quartz phase transition by inelastic neutron scattering as the Curie law divergence in ferroelectrics. This transition changes its character from a second order ( to INC phases) to the first order (INC to the phases) at K. In the cooling process, the first order transition can be recognized by the values of the critical exponent which vary from to 0.31 (Table 1). Although the large value of the critical exponent () indicates a first order transition, the value of 0.31 is close to the values of , , and 0.33 as predicted from the Ising (), Heisenberg (, ), and models [26], respectively, which describe the second order transition. This then indicates that, in the cooling process, transition from the incommensurate to the phase at K can be considered as a weak first order or close to the second order in quartz. This is not in disagreement with the earlier conclusion that the to the incommensurate transition at is found to be continuous, but the incommensurate to the transition at is of first order [27]. The fact that the second order transition ( to incommensurate phase at ) changes to a weak first order transition (incommensurate to the phase at ) may be due to a coupling of the order parameter (Bragg peakintensity) with other degrees of freedom [28] such as acoustic phonons in the incommensurate phase where the soft phonon condensates inside the Brillouin zone, as also pointed out previously [27].
Different from the second order transition for the cooling process when the phase undergoes the incommensurate (INC) phase at K, it has been observed that the two phases coexist indicating a first order transition [14, 29]. By the intense light scattering [30], the existence of heterogeneous structure has been observed experimentally [31] from the to the phase at and from the incommensurate to the phase at in quartz. Incommensurate phase that occurs between and phases in quartz similar to NaNO_{2} [32] can be investigated in some detail using various physical properties which can be obtained both experimentally and theoretically.
4. Conclusions
Temperature variation of the (022) Bragg peakintensity was analyzed using the experimental data by a powerlaw formula for the incommensurate transition in quartz. Values of the critical exponent for the Bragg peakintensity associated with the order parameter indicate that the to incommensurate transition () is of the second order whereas incommensurate to the transition () is a weak first order (or close to the second order) type in quartz. Scattered Bragg peakintensity in the incommensurate phase (~1.3 K) can be attributed to the divergence of the fluctuation of the order parameter, which can be regarded as the critical opalescence of the soft mode in this phase of quartz.
Conflict of Interests
The authors declare that there is no conflict of interests regarding the publication of this paper.
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Copyright © 2014 Hamit Yurtseven and Koray Kaymazlar. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.