Table of Contents
Journal of Thermodynamics
Volume 2013, Article ID 413878, 8 pages
http://dx.doi.org/10.1155/2013/413878
Research Article

Studies on Excess Volume, Viscosity, and Speed of Sound of Binary Mixtures of Methyl Benzoate in Ethers at and  K

1Physical Chemistry Research Laboratory, B.N. Bandodkar College of Science, Thane 400601, India
2Department of Chemistry, Dr. P.R.Ghogrey Science College, Deopur, Dhule 424005, India

Received 24 April 2013; Revised 19 July 2013; Accepted 19 July 2013

Academic Editor: Felix Sharipov

Copyright © 2013 M. V. Rathnam et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Densities, viscosities, and speed of sound have been determined at T = (303.15, 308.15, and 313.15) K for the binary mixtures of methyl benzoate with tetrahydrofuran, 1,4-dioxane, anisole, and butyl vinyl ether over the entire range of composition. Using these measured values, excess volume , deviation in viscosities , excess Gibb’s free energy of activation for viscous flow , and deviation in isentropic compressibility have been calculated. These calculated binary data have been fitted to Redlich-Kister equation to determine the appropriate coefficients. The values of excess volume and deviation in viscosities are negative over the entire range of composition for all the binary systems at the studied temperatures. The behavior of these parameters with composition of the mixture has been discussed in terms of molecular interactions between the components of liquids.