Table of Contents
Journal of Thermodynamics
Volume 2014 (2014), Article ID 231296, 5 pages
http://dx.doi.org/10.1155/2014/231296
Research Article

Thermodynamic Properties of Vapors from Speed of Sound

Faculty of Technology, University of Tuzla, 75000 Tuzla, Bosnia and Herzegovina

Received 5 May 2014; Accepted 9 July 2014; Published 21 July 2014

Academic Editor: Angelo Lucia

Copyright © 2014 Muhamed Bijedić and Sabina Begić. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

A numerical procedure for deriving the thermodynamic properties , , and of the vapor phase in the subcritical temperature range from the speed of sound is presented. The set of differential equations connecting these properties with the speed of sound is solved as the initial-value problem in domain . The initial values of and are specified along the isotherm with the highest temperature, at a several values of [0.1, 1.0]. The values of are generated by the reference equation of state, while the values of are derived from the speed of sound, by solving another set of differential equations in domain in the transcritical temperature range. This set of equations is solved as the initial-boundary-value problem. The initial values of and are specified along the isochore in the limit of the ideal gas, at several isotherms distributed according to the Chebyshev points of the second kind. The boundary values of are specified along the same isotherm and along another isotherm with a higher temperature, at several values of . The procedure is tested on Ar, N2, CH4, and CO2, with the mean AADs for , , and at 0.0003%, 0.0046%, and 0.0061%, respectively (0.0007%, 0.0130%, and 0.0189% along the saturation line).