Journal of Thermodynamics / 2014 / Article / Tab 5 / Research Article
Thermophysical Properties of Binary Mixtures of Dimethylsulfoxide with 1-Phenylethanone and 1,4-Dimethylbenzene at Various Temperatures Table 5 Derived parameters of Redlich-Kister equation (
12 ) and standard deviation (
13 ) for various functions of the binary mixtures at different temperatures (DMSO-
-xylene).
(cm3 ·mol−1 )313.15 −8.5850 −15.1234 −6.084 12.8652 0.15687 318.15 −8.2010 −15.9715 −5.4345 15.6022 0.17024 323.15 −7.7110 −16.483 −4.7908 17.7396 0.19337 328.15 −7.1898 −16.3123 −4.0863 18.0512 0.20482
(mPa·s)313.15 −0.9028 −0.7268 −0.2127 0.25 0.00553 318.15 −0.8069 −0.7852 −0.1061 0.5942 0.00475 323.15 −0.7589 −0.7364 0.093 0.6582 0.00619 328.15 −0.7126 −0.6943 0.2137 0.6476 0.0067
(TPa−1 )313.15 −119.0039 −64.4234 −74.9361 −36.2431 1.03835 318.15 −137.2976 −76.3846 −70.5856 −21.5844 0.97745 323.15 −148.0003 −81.8649 −67.7606 −17.6011 0.84832 328.15 −166.5237 −92.1709 −61.6439 −2.9525 0.87227
313.15 −3.25811 4.787247 −1.77213 −3.9986 0.226222 318.15 −3.20078 4.955419 −1.49922 −4.5735 0.239049 323.15 −3.14001 5.033874 −1.26969 −4.89488 0.245337 328.15 −3.0793 5.147192 −1.01287 −5.28097 0.254675 Δ
(J·mol−1 ) 313.15 −1022.2560 −1753.98 −140.348 1173.282 15.8755 318.15 −1013.8590 −2190.4 88.3584 2252.137 14.30563 323.15 −1011.6820 −2200.58 769.1765 2310.619 22.20041 328.15 −1113.8360 −2249.67 1294.863 2307.221 24.1139