Table of Contents
Laser Chemistry
Volume 5, Issue 3, Pages 107-117
http://dx.doi.org/10.1155/LC.5.107

Measurements of the Relaxation Kinetics of Photo-Excited Enol Form of Dibenzoylmethane

1Faculty of Physics, Sofia University, Sofia BG-1126, Bulgaria
2Department of Organic Chemistry, University of Sofia, BG-1126, Bulgaria

Received 29 March 1984; Accepted 6 June 1984

Copyright © 1985 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The decay rate of the excited state of the enol form of dibenzoylmethane (DBM) in different solvents is measured directly using nanosecond light pulses. The observed relaxation kinetics is explained by the formation of three intermediate forms of the excited cis-enol form of DBM. The decay rates of the intermediates and their absorption cross sections for λ = 266 nm are reported too.