Table of Contents
Laser Chemistry
Volume 10, Issue 5-6, Pages 319-332
http://dx.doi.org/10.1155/1990/71064

Doppler Measurement of Differential Cross Sections in Crossed Beam Experiments: Dependence of the Detection Sensitivity With the Product Velocity

Laboratoire de Spectroscopie Hertzienne de I’E.N.S. 24, rue Lhomond, Paris Cédex 05 75231, France

Received 15 November 1989; Accepted 15 December 1989

Copyright © 1990 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

Differential cross sections can be measured as a function of the internal state of a reaction product thanks to the analysis of the Doppler profile of the laser induced fluorescence detection line. This analysis is complicated by two effects: first, the LIF signal intensity depends on the interaction time of the molecule with the laser, and this time depends on the scattering angle, second, the angular and velocity distributions of the beams have non negligible widths. We present here a treatment of these effects in the case of the F+I2 reaction for which we have measured the differential cross section by this technique. The same formalism is also applied to the deduction of the rovibrational distribution of the products from the relative intensities of the LIF lines.