Table of Contents
Laser Chemistry
Volume 14, Issue 4, Pages 217-224
http://dx.doi.org/10.1155/1994/36860

A Bottleneck Effect in Perfluoropropene

Instituto de Óptica "Daza de Valdés". C.S.I.C., Serrano 121, Madrid 28006, Spain

Received 28 January 1993

Copyright © 1994 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

By investigating the infrared dissociation yield of perfluoropropene under a convenient range of experimental conditions on pressure, laser fluence and number of irradiation shots, we have seen that i) besides the already known final products, C2F4 and C2F6, the dissociation of this molecule also produces polytetrafluoroethylene, and ii) contrary to what one should expect from its rather large molecular size, perfluoropropene opposes a strong bottleneck effect against absorption of resonant infrared radiation, at least for irradiation fluences smaller than ≈ 1.8 Jcm-2