Laser Chemistry

Laser Chemistry / 1995 / Article
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Molecular Energy Transfer and Reaction Dynamics in Japan: Part 1

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Volume 15 |Article ID 075278 | https://doi.org/10.1155/1995/75278

Takumi Kono, Masao Takayanagi, Ichiro Hanazaki, "The C=O Stretching Frequency in the S1 (π* - n) State of Acetaldehyde and its Deuterated Derivatives Determined With the Photofragment Excitation Spectroscopy", Laser Chemistry, vol. 15, Article ID 075278, 11 pages, 1995. https://doi.org/10.1155/1995/75278

The C=O Stretching Frequency in the S1 (π* - n) State of Acetaldehyde and its Deuterated Derivatives Determined With the Photofragment Excitation Spectroscopy

Received15 Apr 1994

Abstract

The vibrational structure was recorded for the S1 (π* - n) state of acetaldehyde (CH3CHO) and its deuterated derivatives (CH3CDO, CD3CHO and CD3CDO up to ∼3500 cm-1above the 0-0 bands with the LIF (laser induced fluorescence) and PHOFEX (photofragment excitation) techniques. In the PHOFEX spectroscopy, the yield of the formyl radical, HCO(X ˜) or DCO(X ˜), produced in the photodissociation of acetaldehyde is measured against the excitation frequency. The yield was determined by monitoring one of the rotational lines in the B˜X˜ transition of the formyl radical by the LIF technique. This is the first measurement of the vibronic structure of acetaldehydes in supersonic jets above the dissociation threshold where they are non-fluorescent. The results have made it possible to locate v4 (the C=O stretching) and 2v4 bands unequivocally; the v4 fundamentals at 1217, 1189, 1210 and 1178 cm-1 above the 0-0 band for CH3CHO, CH3CDO, CD3CHO and CD3CDO, respectively. The corresponding overtone (2v4) bands are observed, respectively, at 2414, 2350, 2399 and 2334cm-1. All the vibronic bands newly observed in the PHOFEX spectra are found to be interpreted as the combinations of v4 and 2v4 with the modes appearing in the lower frequency (< 1200 cm-1) region, which consist of v10 (the C—C—O in-plane bending), v14 (the C=O out-of-plane wagging) and v15 (the methyl torsion).

Copyright © 1995 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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