Table of Contents
Laser Chemistry
Volume 16, Issue 1, Pages 43-51

Measurements of Rate Constants for HO2 + NO and NH2 + NO Reactions by Time-Resolved Photoionization Mass Spectrometry

Atmospheric Environment Division, National Institute for Environmental Studies, 16-2 Onogawa, Tsukuba, Ibaraki 305, Japan

Received 1 September 1994

Copyright © 1995 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


Absolute rate constants for HO2 + NO and NH2 + NO reactions were measured by a photoionization mass spectrometry coupled with a laser flash photolysis. HO2 and NH2 radicals were photoionized by an Ar resonance lamp and were detected as their parent ions (HO2+ and NH2+). The rate constants were determined to be K(HO2+NO)=(6.5±2.0)1012cm3molecule1s1K(NH2+NO)=(1.9±0.3)1011cm3molecule1s1 Both rates are consistent with those previously reported.