Table of Contents
Laser Chemistry
Volume 19, Issue 1-4, Pages 385-387
http://dx.doi.org/10.1155/1999/41464

Vibrational Mode Coupling to Reverse Electron Transfer in (CN)5FeCNRu(NH3)5 in Solution

Department of Chemistry, University of Pittsburgh, Pittsburgh 15260, PA, USA

Received 7 April 1997

Copyright © 1999 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

We present charge transfer absorption, resonance Raman and time-resolved infrared spectral data for (CN)5FeCNRu(NH3)5 in various solvents. The transient infrared spectra and anisotropies reveal both non-equilibrium vibrational populations of high frequency modes and local solvent heating.