Table of Contents
Laser Chemistry
Volume 19, Issue 1-4, Pages 83-90
http://dx.doi.org/10.1155/1999/61425

Femtosecond Mid-Infrared Spectroscopy of Hydrogen-Bonded Liquids

FOM-Institute for Atomic and Molecular Physics, Kruislaan 407, Amsterdam 1098 SJ, The Netherlands

Received 29 April 1997

Copyright © 1999 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

We perform femtosecond mid-infrared pump-probe spectroscopy on hydrogen-bonded ethanol dissolved in CCl4. We find that upon excitation of the OH-stretching vibration the hydrogen bonds are predissociated on a femtosecond time scale, and that the predissociation time constant depends strongly on the hydrogen-bond strength.