Table of Contents
Laser Chemistry
Volume 19, Issue 1-4, Pages 329-333
http://dx.doi.org/10.1155/1999/63925

Two Distinct Solvated Structures of Para-Nitroaniline in Acetonitrile and Their Dissociation and Reassociation Dynamics

1Kanagawa Academy of Science and Technology, KSP East 301, 3-2-1 Sakado, Takatsu, Kawasaki, 213, Japan
2Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro, Tokyo 153, Japan
3Department of Chemistry, School of Science, The University of Tokyo, Hongo 113, Bunkyo, Japan

Received 12 May 1997

Copyright © 1999 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

We have measured the femtosecond time-resolved absorption spectra of para-nitroaniline in acetonitrile just after the photoexcitation to the lowest excited singlet state. The Singular Value Decomposition (SVD) analysis shows that two temporal evolutions follow the photoexcitation. The fast component (0.7 ps time constant) describes the dissociation of the 1:2 associated form to generate the 1:0 form followed by its reassociation with AN molecules. A slower temporal evolution of 10 ps is most likely to represent the cooling down process of the whole system.