Laser Chemistry

Laser Chemistry / 1999 / Article

Open Access

Volume 18 |Article ID 086213 | https://doi.org/10.1155/1999/86213

R. Teule, S. Stolte, W. Ubachs, "Collision-Induced E(0g+)D(0u+) State-to-State Energy Transfer in I2", Laser Chemistry, vol. 18, Article ID 086213, 18 pages, 1999. https://doi.org/10.1155/1999/86213

Collision-Induced E(0g+)D(0u+) State-to-State Energy Transfer in I2

Received19 Nov 1998

Abstract

Electronic energy transfer in the E(0g+)D(0u+) system of I2 is investigated in an experiment, where single rovibrational quantum states are prepared, single collision conditions prevail, and the final states have been determined from dispersed fluorescence. In I2(E)X(X=Ar,N2,O2) the collisional decay is found to be governed by minimum energy transfer. With (X=I2) an anomalous behaviour is found for the initially prepared E, ν=8, J=56 level, which is tentatively ascribed to vibrational excitation of the collision partner.

Copyright © 1999 Hindawi Publishing Corporation. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


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