Research Letter

Synthesis of a New Calix[4]Arene and Its Application in Construction of a Highly Selective Silver Ion-Selective Membrane Electrode

Table 1

Optimization of membrane ingredients.

Membrane no.Composition (%)Slope (mV per decade)
PVCPlasticizerIonophoreNaTPB

130BA, 664 1 7 . 5 ± 0 . 5
230BA, 655 2 1 . 2 ± 0 . 4
330BA, 646 2 0 . 3 ± 0 . 3
430BA, 637 1 9 . 2 ± 0 . 6
530BA, 6352 4 8 . 4 ± 0 . 3
630BA, 6253 5 2 . 5 ± 0 . 3
730BA, 6154 5 6 . 7 ± 0 . 5
830BA, 6055 5 6 . 4 ± 0 . 5
930DBP, 6154 5 9 . 7 ± 0 . 4
1030NB, 6154 2 0 . 8 ± 0 . 5
1130DBP, 664 7 . 8 ± 0 . 5