Table of Contents
Research Letters in Organic Chemistry
Volume 2009, Article ID 792967, 4 pages
http://dx.doi.org/10.1155/2009/792967
Research Letter

Catalytic Oxidative Cleavage of C=N Bond in the Presence of Zeolite H-NaX Supported C u ( N O 3 ) 2 , as a Green Reagent

1Department of Chemistry, Periyar University, Salem 636 011, India
2School of Chemistry, Madurai Kamaraj University, Madurai 625 021, India

Received 28 April 2009; Accepted 20 June 2009

Academic Editor: Pierre Esteves

Copyright © 2009 A. Lalitha et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. P. Lazslo, Preparative Chemistry Using Supported Reagents, Academic Press, San Diego, Calif, USA, 1987.
  2. J. H. Clark, A. P. Kybett, and D. J. Macquarrie, Supported Reagents: Preparation, Analysis and Applications, VCH, New York, NY, USA, 1992.
  3. N. D. Cheronis and J. B. Entrikin, Identification of Organic Compounds, Interscience, New York, NY, USA, 1963.
  4. M. M. Heravi, L. Ranjbar, F. Derikvand, H. A. Oskooie, and F. F. Bamoharram, “Catalytic oxidative cleavage of C=N bond in the presence of mixed-addenda vanadomolybdophosphate, H6PMo9V3O40 as a green and reusable catalyst,” Journal of Molecular Catalysis A, vol. 265, no. 1-2, pp. 186–188, 2007. View at Publisher · View at Google Scholar
  5. S. B. Shim, K. Kim, and Y. H. Kim, “Direct conversion of oximes and hydrazones into their ketones with dinitrogen tetroxide,” Tetrahedron Letters, vol. 28, no. 6, pp. 645–648, 1987. View at Publisher · View at Google Scholar
  6. B. P. Bandgar, L. B. Kunde, and J. L. Thote, “Deoximation with N-haloamides,” Synthetic Communications, vol. 27, no. 7, pp. 1149–1152, 1997. View at Publisher · View at Google Scholar
  7. M. Giurg and J. Młochowski, “Regeneration of carbonyl compounds from azines with cerium(IV) ammonium nitrate,” Synthetic Communications, vol. 29, no. 24, pp. 4307–4313, 1999. View at Publisher · View at Google Scholar
  8. M. M. Heravi, D. Ajami, M. Tajbakhsh, and M. Ghassemzadeh, “Clay supported bis-(trimethylsilyl)-chromate: an efficient reagent for oxidative deoximation,” Monatshefte für Chemie, vol. 131, no. 10, pp. 1109–1113, 2000. View at Publisher · View at Google Scholar
  9. M. M. Heravi, D. Ajami, and M. M. Mojtahedi, “Regeneration of carbonyl compounds from oximes on clayfen under conventional heating and microwave irradiation,” Journal of Chemical Research, vol. 2000, no. 3, pp. 126–127, 2000. View at Google Scholar
  10. C. C. Addison, N. Logan, S. C. Wallwork, and C. D. Garner, “Structural aspects of co-ordinated nitrate groups,” Quarterly Reviews, Chemical Society, vol. 25, no. 2, pp. 289–322, 1971. View at Publisher · View at Google Scholar
  11. C. C. Addison, “The relation between chemical reactivity of ligands and the nature of the metal-ligand bond: nitrato-complexes,” Coordination Chemistry Reviews, vol. 1, no. 1-2, pp. 58–65, 1966. View at Publisher · View at Google Scholar
  12. A. Cornelis and P. Laszlo, “Clay-supported copper(II) and iron(III) nitrates: novel multi-purpose reagents for organic synthesis,” Synthesis, vol. 10, p. 909, 1985. View at Publisher · View at Google Scholar
  13. E. C. Taylor, C.-S. Chiang, A. McKillop, and J. F. White, “Oxidative rearrangements via oxythallation with thallium(III) nitrate supported on clay,” Journal of the American Chemical Society, vol. 98, no. 21, pp. 6750–6752, 1976. View at Publisher · View at Google Scholar
  14. D. Savoia, C. Trombini, and A. Umani-Ronchi, “Synthesis of 2-(6-carboxyhexyl)cyclopent-2-en-1-one, an intermediate in prostaglandin synthesis,” Journal of Organic Chemistry, vol. 47, no. 3, pp. 564–566, 1982. View at Publisher · View at Google Scholar
  15. J. H. Clark, A. P. Kybett, P. Landon, D. J. Macquarrie, and K. Martin, “Catalytic Oxidation of Organic Substrates using Alumina Supported Chromium and Manganese,” Journal of Chemical Society., Chemical Communication, p. 1355, 1989. View at Google Scholar
  16. G. W. Kabalka and M. Richard, “Organic reactions on alumina,” Tetrahedron, vol. 53, pp. 7999–8065, 1997. View at Google Scholar
  17. A. Lalitha and K. Sivakumar, “Zeolite H-Y-supported copper(II) nitrate: a simple and effective solid-supported reagent for nitration of phenols and their derivatives,” Synthetic Communications, vol. 38, no. 11, pp. 1745–1752, 2008. View at Publisher · View at Google Scholar