Table of Contents
Organic Chemistry International
Volume 2012, Article ID 819190, 6 pages
http://dx.doi.org/10.1155/2012/819190
Research Article

Oxidative Carbonylation of 2-Propyn-1-ol and 2-Methyl-3-butyn-2-ol in an Oscillatory Mode

Department of Basic Organic Synthesis, Lomonosov Moscow State University of Fine Chemical Technologies (MITHT), Vernadsky Avenue 86, 119571 Moscow, Russia

Received 31 October 2011; Accepted 18 January 2012

Academic Editor: Dipakranjan Mal

Copyright © 2012 Sergey Nikolaevich Gorodsky. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The oscillatory modes of oxidative carbonylation reaction of two new substrates—2-methyl-3-butyn-2-ol and 2-propyn-1-ol in homogeneous system PdI2-KI-CO-O2-CH3OH are found. Borders of oscillatory areas are drawn, the basic products of reaction are identified, and probable processes routes are offered.