Optics of Chromites and Charge-Transfer Transitions

Table 1

Many-electron CT transitions generated by one-electron 𝑡_2𝑢,𝑡_1𝑢(𝜋),𝑡_1𝑢(𝜎)→3d𝑒_𝑔 CT transitions.

𝛾	𝜎	RME	𝛾	𝜎	RME
𝑇2	2	√5/2⟨𝑒𝑔‖𝐝‖̂𝑡2𝑢⟩	𝑇1	2	−√5/2⟨𝑒𝑔‖𝐝‖̂𝑡1𝑢⟩
𝑇2	1	−√3/2⟨𝑒𝑔‖𝐝‖̂𝑡2𝑢⟩	𝑇1	1	√3/2⟨𝑒𝑔‖𝐝‖̂𝑡1𝑢⟩