Table of Contents
Physics Research International
Volume 2012 (2012), Article ID 576547, 14 pages
http://dx.doi.org/10.1155/2012/576547
Review Article

Second-Order Nonlinear Optical Microscopy of a H–Si(111)1 × 1 Surface in Ultra-High Vacuum Conditions

1School of Materials Science, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Nomi, Ishikawa 923-1292, Japan
2Core Research for Evolutional Science and Technology, Japan Science and Technology Corporation, 5-3 Yonbancho, Chiyoda-ku, Tokyo 102-8666, Japan

Received 2 December 2011; Accepted 10 February 2012

Academic Editor: Vladimir I. Gavrilenko

Copyright © 2012 Yoshihiro Miyauchi. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. J. A. Del Alamo, “Nanometre-scale electronics with III-V compound semiconductors,” Nature, vol. 479, no. 7373, pp. 317–323, 2011. View at Publisher · View at Google Scholar
  2. A. H. Mahan, Y. Xu, D. L. Williamson et al., “Structural properties of hot wire a-Si:H films deposited at rates in excess of 100 Å/s,” Journal of Applied Physics, vol. 90, no. 10, pp. 5038–5047, 2001. View at Publisher · View at Google Scholar · View at Scopus
  3. B. G. Koehler, C. H. Mak, D. A. Arthur, P. A. Coon, and S. M. George, “Desorption kinetics of hydrogen and deuterium from Si(111)7×7 studied using laser-induced thermal desorption,” The Journal of Chemical Physics, vol. 89, no. 3, pp. 1709–1718, 1988. View at Google Scholar · View at Scopus
  4. G. S. Higashi, Y. J. Chabal, G. W. Trucks, and K. Raghavachari, “Ideal hydrogen termination of the Si (111) surface,” Applied Physics Letters, vol. 56, no. 7, pp. 656–658, 1990. View at Publisher · View at Google Scholar · View at Scopus
  5. J. J. Boland, “Nature of the hydride species on the hydrogenated Si(111)-(7×7) surface,” Journal of Physical Chemistry, vol. 95, no. 4, pp. 1521–1524, 1991. View at Google Scholar · View at Scopus
  6. D. Lin and R. Chen, “Hydrogen-desorption kinetic measurement on the Si(100)-2×1:H surface by directly counting desorption sites,” Physical Review B, vol. 60, no. 12, pp. R8461–R8464, 1999. View at Google Scholar
  7. V. De Renzi, R. Biagi, and U. Del Pennino, “Study of the transition from the ideal Si(111)-H(1×1) surface to the (7×7) reconstruction by HREELS, UPS and LEED,” Surface Science, vol. 497, no. 1–3, pp. 247–253, 2002. View at Publisher · View at Google Scholar · View at Scopus
  8. P. Bratu and U. Höfer, “Phonon-assisted sticking of molecular hydrogen on Si(111)- (7×7),” Physical Review Letters, vol. 74, no. 9, pp. 1625–1628, 1995. View at Publisher · View at Google Scholar · View at Scopus
  9. M. Y. Mao, P. B. Miranda, D. S. Kim, and Y. R. Shen, “Characterization of hydrogen-terminated Si(111) surfaces by sum-frequency surface vibrational spectroscopy,” Applied Physics Letters, vol. 75, no. 21, pp. 3357–3359, 1999. View at Google Scholar · View at Scopus
  10. S. Ye, T. Saito, S. Nihonyanagi et al., “Stability of the Si-H bond on the hydrogen-terminated Si(1 1 1) surface studied by sum frequency generation,” Surface Science, vol. 476, no. 1-2, pp. 121–128, 2001. View at Publisher · View at Google Scholar · View at Scopus
  11. A. Kawasuso, M. Yoshikawa, K. Kojima, S. Okada, and A. Ichimiya, “Rocking curves of reflection high-energy positron diffraction from hydrogen-terminated Si(111) surfaces,” Physical Review B, vol. 61, no. 3, pp. 2102–2106, 2000. View at Google Scholar · View at Scopus
  12. M. Tsuji, K. Kobarai, S. Yamaguchi, H. Obase, and Y. Nishimura, “Dissociative excitation of SiH4 by collisions with krypton active species,” Chemical Physics Letters, vol. 166, no. 5-6, pp. 485–490, 1990. View at Google Scholar · View at Scopus
  13. K. Ishikawa, K. Ueda, and M. Yoshimura, “New development of scanning-type microscope for two-dimensional hydrogen distribution using electron-stimulated desorption method,” Surface Science, vol. 433, pp. 244–248, 1999. View at Publisher · View at Google Scholar · View at Scopus
  14. Y. R. Shen, The Principles of Nonlinear Optics, Wiley, New York, NY, USA, 1984.
  15. T. F. Heinz, M. M. T. Loy, and W. A. Thompson, “Study of Si(111) surfaces by optical second-harmonic generation: reconstruction and surface phase transformation,” Physical Review Letters, vol. 54, no. 1, pp. 63–66, 1985. View at Publisher · View at Google Scholar · View at Scopus
  16. U. Höfer, “Nonlinear optical investigations of the dynamics of hydrogen interaction with silicon surfaces,” Applied Physics A, vol. 63, no. 6, pp. 533–547, 1996. View at Google Scholar
  17. T. Suzuki, “Surface-state transitions of Si(111)-7×7 probed using nonlinear optical spectroscopy,” Physical Review B, vol. 61, no. 8, pp. R5117–R5120, 2000. View at Google Scholar · View at Scopus
  18. G. A. Reider, U. Höfer, and T. F. Heinz, “Surface diffusion of hydrogen on Si(111)7×7,” Physical Review Letters, vol. 66, no. 15, pp. 1994–1997, 1991. View at Google Scholar · View at Scopus
  19. J. Price, Y. Q. An, P. S. Lysaght, G. Bersuker, and M. C. Downer, “Resonant photoionization of defects in Si/SiO2/HfO2 film stacks observed by second-harmonic generation,” Applied Physics Letters, vol. 95, no. 5, Article ID 052906, 2009. View at Publisher · View at Google Scholar · View at Scopus
  20. A. Wirth, J. Wei, J. J. H. Gielis et al., “Second-harmonic spectroscopy of Si nanocrystals embedded in silica,” Physica Status Solidi C, vol. 5, no. 8, pp. 2662–2666, 2008. View at Publisher · View at Google Scholar · View at Scopus
  21. Y. Q. An, R. Carriles, and M. C. Downer, “Absolute phase and amplitude of second-order nonlinear optical susceptibility components at Si(001) interfaces,” Physical Review B, vol. 75, no. 24, Article ID 241307, 2007. View at Publisher · View at Google Scholar · View at Scopus
  22. Y. Sonoda, G. Mizutani, H. Sano, S. Ushioda, T. Sekiya, and S. Kurita, “Ultra-high vacuum optical second harmonic microscope,” Japanese Journal of Applied Physics Part 2, vol. 39, no. 3, pp. L253–L255, 2000. View at Google Scholar · View at Scopus
  23. Y. Miyauchi, H. Sano, and G. Mizutani, “Optical second harmonic intensity images of hydrogen deficiency on H-Si(111) surfaces,” e-Journal of Surface Science and Nanotechnology, vol. 4, pp. 105–109, 2006. View at Publisher · View at Google Scholar · View at Scopus
  24. Y. Miyauchi, H. Sano, and G. Mizutani, “Numerical analysis of second harmonic intensity images of a H-Si(111) surface after UV light pulse irradiation,” Applied Surface Science, vol. 255, no. 5, pp. 3442–3446, 2008. View at Publisher · View at Google Scholar · View at Scopus
  25. P. Guyot-Sionnest, “Coherent processes at surfaces: free-induction decay and photon echo of the Si-H stretching vibration for H/Si(111),” Physical Review Letters, vol. 66, no. 11, pp. 1489–1492, 1991. View at Publisher · View at Google Scholar · View at Scopus
  26. M. Flörsheimer, C. Brillert, and H. Fuchs, “Chemical imaging of interfaces by sum-frequency generation,” Materials Science and Engineering C, vol. 8-9, pp. 335–341, 1999. View at Google Scholar · View at Scopus
  27. K. Cimatu, H. J. Moore, T. R. Lee, and S. Baldelli, “Sum frequency generation imaging of microcontact-printed monolayers derived from aliphatic dithiocarboxylic acids: contrast based on terminal-group orientation,” Journal of Physical Chemistry C, vol. 111, no. 32, pp. 11751–11755, 2007. View at Publisher · View at Google Scholar · View at Scopus
  28. Y. Miyauchi, H. Sano, J. Okada, H. Yamashita, and G. Mizutani, “Simultaneous optical second harmonic and sum frequency intensity image observation of hydrogen deficiency on a H-Si(111) 1×1 surface after IR light pulse irradiation,” Surface Science, vol. 603, no. 19, pp. 2972–2977, 2009. View at Publisher · View at Google Scholar · View at Scopus
  29. K. T. T. Hien, Y. Miyauchi, and G. Mizutani, “Pump-probe time-resolved sum frequency spectroscopy of the H-Si(111)1×1 surface,” e-Journal of Surface Science and Nanotechnology, vol. 8, pp. 89–92, 2010. View at Publisher · View at Google Scholar
  30. G. Mizutani and Y. Miyauchi, “Development and application of optical sum frequency microscopy,” Surface and Interface Analysis, vol. 42, no. 10-11, pp. 1675–1679, 2010. View at Publisher · View at Google Scholar · View at Scopus
  31. Y. Miyauchi, H. Sano, J. Okada, H. Yamashita, and G. Mizutani, “Experimental and numerical analysis of sum frequency microscopic images of a H-Si(111)1×1 surface after IR light pulse irradiation,” Surface and Interface Analysis, vol. 42, no. 10-11, pp. 1667–1670, 2010. View at Publisher · View at Google Scholar · View at Scopus
  32. K. T. T. Hien, Y. Miyauchi, and G. Mizutani, “Construction of a pump-probe system for observing time-resolved sum frequency images,” Surface and Interface Analysis, vol. 42, no. 10-11, pp. 1671–1674, 2010. View at Publisher · View at Google Scholar · View at Scopus
  33. Y. R. Shen and V. Ostroverkhov, “Sum-frequency vibrational spectroscopy on water interfaces: polar orientation of water molecules at interfaces,” Chemical Reviews, vol. 106, no. 4, pp. 1140–1154, 2006. View at Publisher · View at Google Scholar · View at Scopus
  34. B. G. Koehler and S. M. George, “Laser-induced desorption of H2 from Si(111)7×7,” Surface Science, vol. 248, no. 1-2, pp. 158–172, 1991. View at Google Scholar · View at Scopus
  35. E. D. Palik, Handbook of Optical Constants of Solids, Academic Press, Boston, Mass, USA, 1985.
  36. R. F. Wood, C. W. White, and R. T. Young, Semiconductors and Semimetals, Academic Press, Orlando, Fla, USA, 1984.
  37. R. Gunnella, M. Ali, M. Abbas, F. D'Amico, E. Principi, and A. Di Cicco, “Depth profiling of melting and metallization in Si(111) and Si(001) surfaces,” Physical Review Letters, vol. 107, no. 16, Article ID 166103, 2011. View at Publisher · View at Google Scholar
  38. G. A. Reider, U. Höfer, and T. F. Heinz, “Desorption kinetics of hydrogen from the Si(111)7×7 surface,” The Journal of Chemical Physics, vol. 94, no. 5, pp. 4080–4083, 1991. View at Google Scholar · View at Scopus
  39. H. Sano, G. Mizutani, W. Wolf, and R. Podloucky, “Ab initio study of linear and nonlinear optical responses of Si(111) surfaces,” Physical Review B, vol. 66, no. 19, Article ID 195338, 6 pages, 2002. View at Google Scholar · View at Scopus
  40. V. I. Gavrilenko and F. Rebentrost, “Nonlinear optical susceptibility of the (111) and (001) surfaces of silicon,” Applied Physics A, vol. 60, no. 2, pp. 143–146, 1995. View at Publisher · View at Google Scholar · View at Scopus
  41. P. Guyot-Sionnest, “Effect of substrate photoexcitation on the dynamics of the Si-H stretch for Si(111)/H,” Journal of Electron Spectroscopy and Related Phenomena, vol. 64-65, pp. 1–9, 1993. View at Google Scholar · View at Scopus
  42. M. Rasolt, A. M. Malvezzi, and H. Kurz, “Plasmon-phonon-assisted electron-hole recombination in silicon at high laser fluence,” Applied Physics Letters, vol. 51, no. 26, pp. 2208–2210, 1987. View at Publisher · View at Google Scholar · View at Scopus
  43. Y. D. Glinka, N. H. Tolk, X. Liu, Y. Sasaki, and J. K. Furdyna, “Hot-phonon-assisted absorption at semiconductor heterointerfaces monitored by pump-probe second-harmonic generation,” Physical Review B, vol. 77, no. 11, Article ID 113310, 2008. View at Publisher · View at Google Scholar · View at Scopus
  44. P. Dumas, Y. J. Chabal, and G. S. Higashi, “Coupling of an adsorbate vibration to a substrate surface phonon: H on Si(111),” Physical Review Letters, vol. 65, no. 9, pp. 1124–1127, 1990. View at Publisher · View at Google Scholar · View at Scopus
  45. M. W. Rowe, H. Liu, G. P. Williams, and R. T. Williams, “Picosecond photoelectron spectroscopy of excited states at Si(111)3×3R30°-B, Si(111)7×7, Si(100)2×1, and laser-annealed Si(111)1×1 surfaces,” Physical Review B, vol. 47, no. 4, pp. 2048–2064, 1993. View at Publisher · View at Google Scholar · View at Scopus
  46. A. Bandara, S. Katano, J. Kubota et al., “The effect of co-adsorption of on-top CO on the sum-frequency generation signal of bridge CO on the Ni(111) surface,” Chemical Physics Letters, vol. 290, no. 1–3, pp. 261–267, 1998. View at Google Scholar · View at Scopus
  47. P. Gupta, V. L. Colvin, and S. M. George, “Hydrogen desorption kinetics from monohydride and dihydride species on silicon surfaces,” Physical Review B, vol. 37, no. 14, pp. 8234–8243, 1988. View at Publisher · View at Google Scholar · View at Scopus
  48. M. L. Wise, B. G. Koehler, P. Gupta, P. A. Coon, and S. M. George, “Comparison of hydrogen desorption kinetics from Si(111)7×7 and Si(100)2×1,” Surface Science, vol. 258, no. 1–3, pp. 166–176, 1991. View at Google Scholar · View at Scopus
  49. V. De Renzi, R. Biagi, and U. Del Pennino, “Study of the transition from the ideal Si(111)-H(1×1) surface to the (7×7) reconstruction by HREELS, UPS and LEED,” Surface Science, vol. 497, no. 1–3, pp. 247–253, 2002. View at Publisher · View at Google Scholar · View at Scopus
  50. R. L. Lo, I. S. Hwang, M. S. Ho, and T. T. Tsong, “Diffusion of single hydrogen atoms on Si(111)-(7×7) surfaces,” Physical Review Letters, vol. 80, no. 25, pp. 5584–5587, 1998. View at Google Scholar · View at Scopus