Review Article

Polymeric Gas-Separation Membranes for Petroleum Refining

Table 10

Current technologies for dehydration of natural gas [141, 150].

TechnologyAdvantagesDisadvantages

Glycol absorption(i) Continuous process.
(ii) Lower pressure drop compared to solid desiccants.
(iii) Better chemical stability.
(i) Difficult to achieve water dew point below −32°C.
(ii) Harmful VOCs are formed during the regeneration of solvent.

Alumina desiccant(i) Ability to adsorb heavy hydrocarbons.
(ii) Performance is nearly independent of the feed operating condition.
(i) High pressure drop.
(ii) Regeneration is needed.

Zeolite molecular sieving(i) Ability to achieve dew point of −101 to 149°C.
(ii) Stable under sour gas.
(i) More energy is needed for regeneration.

Polymeric membranes(i) Ability to separate hydrogen sulfide, carbon dioxide, and heavy hydrocarbons (C3+) in one step.
(ii) Long life (7 years).
(iii) No need for regeneration.
(i) Pretreatment may be required.
(ii) Energy requirement for compressors.
(iii) Not suitable for large volume.