Advances in Civil Engineering

Advances in Civil Engineering / 2019 / Article

Research Article | Open Access

Volume 2019 |Article ID 7530325 | https://doi.org/10.1155/2019/7530325

Rostislav Drochytka, Matej Ledl, Jiri Bydzovsky, Nikol Zizkova, Johannes Bester, "Use of Secondary Crystallization and Fly Ash in Waterproofing Materials to Increase Concrete Resistance to Aggressive Gases and Liquids", Advances in Civil Engineering, vol. 2019, Article ID 7530325, 12 pages, 2019. https://doi.org/10.1155/2019/7530325

Use of Secondary Crystallization and Fly Ash in Waterproofing Materials to Increase Concrete Resistance to Aggressive Gases and Liquids

Academic Editor: Emilio Bastidas-Arteaga
Received21 Jan 2019
Revised25 Mar 2019
Accepted15 Apr 2019
Published29 May 2019

Abstract

This paper describes the use of cement-based waterproofing screed and waterproofing coating, in which 10% of the original amount of cement was replaced by fly ash and 2% of the crystallization admixture was added by weight of cement, as a mean of protection of concrete against aggressive environments. The modified materials were applied to the underlying concrete and subjected to testing of physical and mechanical properties after exposure to effects of aggressive environments for up to 18 months. The results of the analysis have shown that after the application of waterproofing materials, there is a sufficient development of the crystals in the underlying concrete to enhance its durability. Thus, it is possible to use fly ash functionally and efficiently in polymer cement systems as a substitute for the cement together with the crystallization admixture.

1. Introduction

The concrete is probably the most commonly used construction material due to its versatility [1]. Unfortunately, durability is not an intrinsic property of concrete, and in certain instances, concrete needs protection from the aggressiveness of the environment. The aggressive environment may be due to chemical and physical attacks [2, 3]. Concrete is a multi-component composite containing cement sealant, in which there are significantly more pores and capillaries than in dense aggregates. For this reason, it is much more susceptible to physical and chemical degradation. A basic factor which is a major contributor to the degradation processes is water. It may be in liquid form, vapour, or any dissolved substances. It may, by means of diffusion, capillarity, and ion exchange, penetrate into the concrete through a system of open and interconnected capillary pores and interfere with the cement sealant. Mehta and Monteiro [4] and Kumar and Bhattacharjee [5] found that the diameter of capillary pores ranges from 10 nm to hundreds of microns. Capillary flow is defined by the following:where Q: volume flow (m3·s−1), π: Ludolph’s number (3.1415…), pt: air pressure in the capillary (Pa), t: time (s), η: dynamic viscosity (Pa·s), r: radius of the capillary (m), and l: capillary length (m).

From equation (1), it is evident that the radius of the capillary in the fourth power is the critical flow factor, and it is therefore appropriate to reduce the capillary diameter to slow down the rate of degradation. The affection of cement sealant by aggressive gases generated by industrial processes, combustion engines, living organisms, etc., is conditioned by humidity along with the most common aggressive gases such as CO2, SO2, NO2, HCl, H2S, HF, NH3, and Cl2.

Diluting acidic gaseous exhalants in water creates diluted solutions of inorganic acids, which react with components of cement sealant, especially Ca(OH)2 [6]. The products of cement paste corrosion occupy a larger volume, thus breaking the cohesion of hardened cement paste leading to decrease in pH and cracking. These cracks consequently allow for an accelerated corrosion of steel reinforcement due to a quicker decrease of pH [7, 8].

The main factors that have the greatest impact on the assessment of aggressive gaseous environments include the following:(i)Gas concentration in the air(ii)Relative air humidity(iii)Temperature(iv)Activity of more aggressive agents at the same time

Aggressive waters contain dissolved acid gases and various salts in varying concentrations. Emmons and Emmons [9] stated that depending on the nature of the corrosion products, there are three types of degradation:Type I: degradation related to the action of water media with low salt content and predominantly neutral reactionType II: degradation under the influence of very aggressive media, such as acids, alkali, some salts, such as sodium or magnesium chlorideType III: degradation due to the penetration of liquid media into the pores, which form an insoluble crystalline compound of larger volume with the pore fluid or cement sealant

Broomfield [10] mentions that one of the options for protection against corrosion media is a concrete finish that can reduce or prevent water and aggressive substances from entering its structure. Such a finish is usually used in order to protect concrete from the harmful effects of these aggressive substances. One such commonly used method is called secondary protection. For the design of secondary protection itself, the degree of aggressiveness of the environment, the type of the substrate, and the correct choice of the material for the protection must be considered. One of the subgroups of waterproofing and surface treatments are polymer cement waterproofing coatings and screeds. They represent a proven, affordable, and environmentally acceptable alternative to traditional asphalt- or polymer-based waterproofing. Flexible polymer cementitious sealants exist as two-component systems with a liquid polymeric component, mostly based on styrene-acrylate dispersion, cement binder and suitable dry filler. Alternatively, these systems are formulated on the basis of polymeric redispersible powders that allow the formation of single-component systems which are only mixed with water prior to processing [11].

Screeding and smoothing compounds, often based on ethylene-vinyl acetate, are used to level and smooth out conventional concrete beddings (monoliths and prefabricates), cement screed, or reprofilable mortars for the rehabilitation of reinforced concrete. These cement-based repair mortars present a very suitable and cost-effective solution for concrete protection as they have very similar properties as concrete, thus ensuring their mutual compatibility; moreover, such materials are partially permeable for water vapour, which allows for drying concrete out. Impermeable polymer coatings entrap the moisture in the porous cementitious substrate causing additional damage to concrete in freezing and thawing cycles. The aim is achieving a sufficiently smooth and level surface with a waterproofing function serving as a final treatment or as a suitable basis under the coating system. Current technologies allow for the use of levelling and smoothing screeds that can be applied in layers from less than 1 mm to 5 mm. At the same time, it is possible to produce a material with waterproofing function, even with very low thickness of the applied layer, by means of suitable formulations and using sealing materials.

The cementitious and polymeric components of these materials increase their cost, and for that reason, there are attempts to find methods of reducing the cementitious content. One of these attempts is the partial replacement of cement with waste or secondary raw materials, such as powder fly ash or slag. The inclusion of such secondary raw materials has the added benefit of reducing the environmental impact associated with the issues of depositing waste materials and CO2 production during clinker burning. Using the fly ash as a partial replacement for cement also contributes to the increase in durability of cement composites as the fly ash is capable of pozzolanic reaction with calcium hydroxide, which produces additional calcium-silicate hydrates (C-S-H) and calcium-aluminium-silicate hydrates (C-A-S-H). They additionally cause refinement and reduction of permeability of pore structure of cement matrix as the pozzolanic reaction is slower than hydration of cement as presented in the studies of Moffatt et al. [12] and Feng et al. [13].

Another effective means of protecting and improving the durability of cement composites are surface coatings [14]. Pan et al. [15] described many advantages and disadvantages of various types of concrete surface treatments. The development of new waterproofing materials also leads to the use of special crystallization admixtures to enhance the protective function. Mostly, they are powdered substances based on finely ground cement, treated fine silica sand, and an active chemical. Conventional coatings and screeds fulfil only the surface protection function, while crystallization admixtures penetrate the pore system into the concrete structure, where it is sealed. The principle action is a catalytic chemical reaction, conditioned by sufficient relative humidity. This leads to an additional crystallization process of the still unhydrated clinker minerals in the pore system of concrete, resulting in filling practically all the capillary active pores of the concrete with needle-like crystals. The introduced active chemical, therefore, is not a source of crystals but merely a catalyst that allows for the growth of crystals within the pores of concrete from the untreated clinker minerals present in the cement sealant. During the hydration process, Ca(OH)2 is temporarily produced, followed by the catalytic crystallization process and the growth of the resulting crystals directly into the concrete pore structure. This is probably the accumulated process accompanied by the formation of 3CaO·2SiO2·3H2O together with the formation of 3CaO·Al2O3·Ca(OH)2·12H2O. In this chemical reaction, branched needle-like crystals are formed. The active substances penetrate into the pores, with moisture, to a distance of up to ten centimetres from their source and catalyze the reactions in which crystals form in the pore system of the cement sealant [16, 17]. According to X-ray fluorescence spectroscopy (XRF), the needle-like crystals (Figure 1) probably contain calcium or silicon [18].

The speed and depth of crystal growth through the cracks and pore system of the concrete depend on many factors, such as the extent of the concrete’s treatment, the presence of sufficient volume of pore water, type of cement, concrete proportioning, pore structure, and temperature of the concrete [1924]. The general process of action has been described by Roig-Flores et al. [25], where the crystallization agent, MxRx, reacts with the tricalcium silicate and the water to form clots blocking the pores. This is represented by the following equation:

Research on secondary crystallization in cement composites has previously been dealing with the sealing of pore structures and sealing cracks. The benefits of utilisation of crystalline admixtures are well demonstrated in previously published studies [2530]: however, improving the properties of concrete remains an important task even today [19]. Improving the durability of cementitious composites helps extend their longevity, thereby reducing repair costs associated with moisture damage of concrete structures [31]. This study pays attention to the use of the crystallization admixture in the cement-polymer waterproofing materials applied to the surface of concrete, such as coating and screed, capable of breathability, crack healing ability, good compatibility with concrete, and chemical resistance. In order to reduce the overall costs for crystalline admixtures and polymer compounds, fly ash is considered to be an environmentally friendly partial replacement for cement with a positive impact on durability due to pozzolanic reaction.

2. Materials and Methods

2.1. Materials

In order to decrease the permeability of the concrete surface against water, gaseous, and liquid aggressive environments, two insulating materials were developed and applied to the surface of the concrete. The insulating materials were applied as a coating (CT) and a screed (SC). Both materials utilized a crystallization admixture (Xypex Admix) and fly ashas a secondary raw material.

The thin coating layer copying the concrete surface is applied to the concrete with the use of a brush or roller, whereas the screed that compensates for the unevenness of the concrete is applied using a steel trowel. The concrete specimens (150 mm cubes) of C 45/55 reference concrete were used. The reference concrete was tested according to EN 1542 [32] and EN 12390-3 [33] and yielded a compressive strength of 52 MPa and tensile strength of 3.2 MPa. The composition of the reference concrete (REF) is given in Table 1. Specimens were matured for 28 days at an ambient temperature of 21 ± 3°C and a relative humidity of 60 ± 10%, followed by epoxy coating on the sides and immersed in water for 48 hours. Subsequently, the surface without epoxy was wiped with a rug and an insulating screed or a coating was applied to the damp surface of the concrete specimens (Figure 2) using a brush (coating) and a steel trowel (screed). After application, the specimens were covered with a plastic foil. After 72 hours, the plastic foil was removed and the specimens were cured for another 28 days in an environment with a relative humidity of 60 ± 10% and a temperature of 21 ± 3°C, which lead to the start of the test or to the exposure to the aggressive environments. This storage enabled the active substances to penetrate into the pore structure of the underlying concrete and thus allowed for the formation of secondary crystallization products, reducing the pore diameter in concrete.


MaterialDosage (kg)

Cement EN 197-1 CEM II/A-S 42.5 R340
Sand 0/41280
Gravel 4/8 mined200
Gravel 4/8 crushed221
Silica fume (5% aqueous dispersion)120
Water150

As a waterproofing material with a crystallization admixture, a polymer cement coating (CT) with 10% cement replacement by fly ash and addition of 2% of crystallization admixture by weight of cement was developed. The second tested material was a screed (SC) with 10% cement replacement by fly ash and addition of 2% of crystallization admixture by weight of cement. The composition of both materials is shown in Tables 2 and 3. The mix design of both waterproofing materials was based on the general knowledge of the behaviour of individual components and industrially used products. The average thickness of the coating is designed to be 1.5 mm–2 mm with respect to the maximum grain size of sand. The screed was applied in designed thickness of 3 mm–5 mm.


MaterialDosage (kg)

Cement EN 197-1 CEM II/A-S 42.5 R270
Silica sand700
Silica fume (5% aqueous dispersion)8
Silica filler20
Fly ash (10%)30
Xypex Admix (2%)6
Water300
Carboxymethyl cellulose10
Styrene-acrylate dispersion700
Defoaming agent on synthetic copolymer base5

Percentual substitute for cement was based on the initial dose 300 kg/m3 of cement.

MaterialDosage (kg)

Cement EN 197-1 CEM II/A-S 42.5 R248
Silica sand450
Ground limestone250
Silica filler120
Polymeric dispersion powder on vinyl acetate and ethylene base3.5
Polypropylene fibres0.5
Water220
Superplasticizer on polycarboxylates base1
Carboxymethyl cellulose1
Fly ash (10%)27.5
Xypex Admix (2%)5.4

The physical and chemical compositions of the raw materials used are given in Table 4 and in Figure 3. Phase composition of crystalline admixture in Figure 4.


ComponentContent (%)
CEMFly ashSilica fillerSilica sandSilica fumeCrystalline admixture

SiO218.2856.8299.19991.9711.5
Al2O34.9628.930.270.30.12.34
Fe2O33.676.180.0980.030.671.74
TiO22.020.380.050.020.129
CaO64.91.790.1945.7
MgO2.001.311.240.734
MnO0.030.102
K2O1.021.793.320.387
Na2O0.200.320.56.61
SO33.710.360.672.05
S0.2
Specific surface (m2/kg)37825017.5150 000386

2.2. Testing Methods

3 batches of concrete specimens were prepared (REF, REF treated with CT, and REF treated with SC) for 7 selected environments (Table 5). For 6, 12, and 18 months, they were exposed to the environment and after each interval a complex testing programme was carried out, allowing to assess the state of the secondary crystal development, their possible degradation, their impact on the durability of the concrete, and its resistance to the selected environment, compared to untreated reference concrete. The testing programme included the following:(1)The water absorption was determined on 3 specimens (150 mm concrete cubes) of each batch according to EN 14617-1 [34].(2)Depth of penetration of water under pressure was determined on 3 specimens (150 mm concrete cubes) at different ages according to EN 12390-8 with water pressure of 500 ± 50 kPa for 72 ± 2 h [35].(3)Scanning electron microscopy (SEM) was carried out after the exposure of the specimens to an aggressive environment for 18 months. The presence of crystals and their evolution with respect to the age and effects of degradation were observed on test specimens, cut out of the remains of 150 mm concrete cubes after determination of depth of penetration of water under pressure using a circular saw with a diamond blade. The fragments of concrete were taken from the depth of 15 mm below the interface of treatment and the sound concrete, dried out, and sized down to the size approximately 5 mm × 5 mm × 5 mm. A thin layer of gold 300–400 Å was applied to the samples using the Quorum Q150r. Gold-plated, now conductive, samples were inserted into the body of the FEI Nova 200, and the shots were taken at a suitable resolution (magnification of 4,000x to 25,000x).(4)For the determination of pH values of concrete with treated and untreated surfaces, respectively, the samples were extracted from 3 specimens (150 mm concrete cubes) at a depth of approximately 15 mm. First, the samples were taken before placing the specimens in an aggressive environment. After 18 months of exposure, the pH test was performed again. The samples were extracted from the cubes using 40 mm diamond core drill. Consequently, the holes were filed up with epoxy resin in order to prevent aggressive environment from penetrating the specimens. This allowed reuse of the specimens for the pH test after 18 months. For the pH test, 10 mm thick section of the core sample was cut out at a distance of 10 mm from the interface of treatment and sound concrete or from the untreated surface of REF concrete, respectively. Oven-dried (60°C for 24 h) sections were then milled and sieved through the mesh (0.063 mm). After that, 10 g of material was separated and dispersed in 100 g of distilled water. After mixing in electromagnetic mixer for 30 minutes, the solution was filtered and the pH value determined in solution using pH meter.


EnvironmentConcentrationRelative humidityTemperature

GaseousCO2Low: 1-2%60 ± 10%21 ± 2°C
CO2High: 5–10%
SO2High: 5–10%

LiquidSO42−Na2SO4·10 g/l21 ± 2°C
SO42−Na2SO4·34.6 g/l
ClNaCl·100 g/l

Real outdoor environment

The real environment shows the effects of climatic influence on samples stored outdoors where during the exposure, the temperatures alternate ranging from −15.9°C to + 34.8°C. Samples were also exposed to irregular precipitation, direct sunlight, air pollution, and biological agents.
2.3. Exposure Environment

The resistance of the proposed waterproofing materials was verified by placing the specimens in the aggressive media defined in Table 5 for 6–18 months.

The gaseous environments were created in the Köhler Automobiltechnik GmbH salt spray chambers HK 400-800/M/WTG (Figure 5) which can accommodate 32 specimens in 4 layers separated vertically with polymer grids. Specimens were placed in chamber with the treated side against the door in order to prevent the aggressive condensates from remaining on the treated side of the specimen.

3. Results and Discussion

3.1. Water Absorption

Based on the evaluation of the results of the water absorption test of concrete samples treated with the coating and the screed, it is suggested that these materials significantly reduce the water absorption. Changes in the water absorption after the exposures in liquid aggressive environments can be clearly seen in Figures 6 and 7 in the case of exposure to gaseous media. In all environments, untreated concrete (REF) showed a higher total water absorption than concrete with a waterproofing coating or screed. Especially after 18 months in the liquid environment, the greatest differences in absorbency between the treated concrete and the reference concrete are observed. This indicated the effectiveness of the use of the screed and especially the coating, which has in all cases the lowest absorption, even after exposure in a highly concentrated sulphate environment. In an environment with NaCl, however, the coating appears to be less resistant than in the environment with a high concentration of sulphates.

Gaseous environments with a high SO2 concentration and, in particular, CO2 have significantly influenced the water absorption of the samples. This suggests that a coating may be a more effective protective material against gaseous aggressive environments than a screed.

The real environment, compared to a highly concentrated long-term liquid and gas environment (18 months), shows much less aggressiveness and less damage to treated and untreated concrete.

Absorbance values generally fluctuated at low values due to the possibility of penetration of the liquid through only one nonepoxy surface; therefore, it was also necessary to verify this test with the depth of penetration of water under pressure.

3.2. Depth of Penetration of Water under Pressure

The test for the determination of penetration of water under pressure according to EN 12390-8, due to the effect of increased water pressure on the tested sample, provides a sharper and more conclusive possibility of comparing the ability of treated concrete to resist water and aggressive substances, as opposed to untreated concrete. The screed and coating increased the resistance of concrete structures against penetration of water under pressure as opposed to untreated concrete (REF).

Figures 8 and 9 compare the absorption values of both treated and untreated concrete samples in the corrosive environment, after six, twelve, and eighteen months in the aggressive environment.

Untreated concrete always exhibited a higher depth of penetration of water under pressure than concrete treated with a coating and with the screed, which was also confirmed by the water absorption tests. The samples were also assessed according to the design limit values for the composition and properties of the concrete according to EN 206 + A1. All concrete samples with an applied treatment, after 18 months of storage, had a depth of penetration of water under pressure lower than 50 mm, a value corresponding to the resistance to XA1, XS4, XF1, XF2, and XD2 environments. Samples treated with a coating specifically for XD3 environment, corrosion caused by chlorides other than the sea, and chemically aggressive XA3 environments had withstood the test with the exception of environments with high concentrations of CO2 and SO2 ions because the limit values of the depth of penetration are 20 mm [36]. Based on these results, it can be stated that, in terms of water permeability, the tested crystallization materials are suitable for structures exposed to water under pressure. Regarding the resistance of the tested materials against the penetration of aggressive gases, leakage results indicate that the resistance is comparable to the influence of the liquid medium.

3.3. SEM Analysis of Crystal Growth

SEM was performed in order to detect secondary crystallization products and to monitor the impact of aggressive media on the concrete microstructure. Images for the two most aggressive liquid and two gaseous environments were selected.

In the liquid NaCl and Na2SO4 medium shown in Figures 10 and 11, a more pronounced developed elongated flattened crystals of about 20 μm can be observed filling the pores. These crystals are incompletely shaped, but their amount and size indicate that the initial absorption and the liquid environment have provided sufficient moisture to fill the pores with secondary crystallization. There are no clearly identifiable crystals in the images that would indicate significant signs of carbonation, sulphation, or degradation due to aggressive environments. On the contrary, a sufficiently dense cement matrix is evident. Larger pores can also be expected to be filled.

Figures 12 and 13 from the CO2 and SO2 gaseous media again show rod-like crystals penetrating the pores. Crystals filling the pores differ in shape and size, their amount and size are substantially smaller, and their clusters are of a smaller and finer structure than the samples stored in the liquid environment. The humidity inside the pores probably was not sufficient enough for crystal growth to a larger extent. It can be concluded that most of the pores filled had a diameter of less than 20 μm.

3.4. Changes in the pH of Concrete

Figure 14 shows pH values before storage and after 18 months in aggressive environments. The graph is sorted downwards according to the change of pH during the exposure to the aggressive environment.

The most obvious decrease in pH can be clearly seen in the untreated concrete (REF). Mostly in NaCl and real environments, the pH values of concrete with coating showed a significant decrease. This may be due to coat breakage during application, manipulation, and exposure and also due to the formation of Friedel’s salt within the pores. In general, it can be observed that the tested coatings and screeds successfully helped to slow down the rate of pH reduction during the exposure of concrete to an aggressive environment.

It turned out that at a depth of 15 mm from the surface of concrete, even after 18 months, there was no significant pH decrease (below 9.6) in concrete and, as such, it would not cease to perform the steel reinforcement protection function.

4. Conclusions

(i)It has been demonstrated that the polymer cement waterproofing materials with crystallization admixture can be successfully modified with fly ash additive in order to reduce the content of cement in the formulations by 10%.(ii)The functionality of the crystallization admixture in polymer cement systems has been proved.(iii)The modification of the waterproofing materials and therefore the reduction of Ca(OH)2 content necessary for crystallization and crystal formation in the proposed formulations did not cause a drop in the pH value to the critical limit of the monitored concrete samples where the reinforcement would no longer be protected.(iv)It was confirmed that the type of environment had a significant influence on the properties of the tested concrete sample treated with the proposed waterproofing materials.(v)Throughout the whole 18-month exposure, the coating and screed modified by fly ash and crystallization admixture Xypex Admix have shown increased resistance to aggressive environments with a much higher concentration than is common.(vi)The functionality of sealing technology of concrete pores with crystalline neoplasm after 18 months in an aggressive environment was verified at a depth of 15 mm below the interface of sound concrete, especially if liquid water was available. In concrete, where no liquid water was present in aggressive environment, the formation of crystals occurred to a much lesser extent.(vii)The needle-shaped crystals with the maximum length of 15 μm of single crystals mostly filled out pores with sizes of about 20 μm.(viii)Designed formulations of crystallization coatings and screeds with the admixture of fly ash have shown very good complex properties in increasing the protection of concrete even with long-term exposure to aggressive agents (CO2, SO2, SO42−, Cl, and real outdoor conditions).

Data Availability

The data used to support the findings of this study are included within the article.

Conflicts of Interest

The authors declare that there are no conflicts of interest regarding the publication of this paper.

Acknowledgments

This paper was created with the financial support of the Grant Agency of the Czech Republic (No. 16-25472S) “Dynamics of degradation of cement composites modified by secondary crystallization” and the project (No. LO1408) “AdMaS UP-Advanced Materials, Structures and Technologies,” supported by the Ministry for Education, Youth and Sports of the Czech Republic under “National Sustainability Programme I.”

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Copyright © 2019 Rostislav Drochytka et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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