Table of Contents Author Guidelines Submit a Manuscript
Advances in Condensed Matter Physics
Volume 2010, Article ID 627452, 6 pages
http://dx.doi.org/10.1155/2010/627452
Research Article

Phonons in A 3 C 6 0 Lattice and Structural Dynamics

Department of Chemistry, Chalmers University of Technology, 412 96 Göteborg, Sweden

Received 2 June 2009; Accepted 14 September 2009

Academic Editor: Dragan Mihailovic

Copyright © 2010 Sven Larsson. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. A. F. Hebard, M. J. Rosseinsky, R. C. Haddon et al., “Superconductivity at 18 K in potassium-doped C60,” Nature, vol. 350, no. 6319, pp. 600–601, 1991. View at Google Scholar · View at Scopus
  2. M. J. Rosseinsky, A. P. Ramirez, S. H. Glarum et al., “Superconductivity at 28 K in RbxC60,” Physical Review Letters, vol. 66, no. 21, pp. 2830–2832, 1991. View at Publisher · View at Google Scholar
  3. R. M. Fleming, A. P. Ramirez, M. J. Rosseinsky et al., “Relation of structure and superconducting transition temperatures in A3C60,” Nature, vol. 352, no. 6338, pp. 787–788, 1991. View at Publisher · View at Google Scholar · View at Scopus
  4. L. S. Cox and R. A. Laskey, “DNA replication occurs at discrete sites in pseudonuclei assembled from purified DNA in vitro,” Cell, vol. 66, no. 2, pp. 271–275, 1991. View at Publisher · View at Google Scholar · View at Scopus
  5. R. C. Haddon, A. F. Hebard, M. J. Rosseinsky et al., “Conducting films of C60 and C70 by alkali-metal doping,” Nature, vol. 350, no. 6316, pp. 320–322, 1991. View at Publisher · View at Google Scholar · View at Scopus
  6. T. Yildirim, O. Zhou, J. E. Fischer et al., “Intercalation of sodium heteroclusters into the C60 lattice,” Nature, vol. 360, no. 6404, pp. 568–571, 1992. View at Publisher · View at Google Scholar · View at Scopus
  7. K. Prassides, C. Christides, I. M. Thomas et al., “Crystal structure, bonding, and phase transition of the superconducting Na2CsC60 fulleride,” Science, vol. 263, no. 5149, pp. 950–954, 1994. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  8. Y. Maniwa, T. Saito, A. Ohi et al., “Electronic states and superconductivity in alkali-intercalated fullerides: C13-NMR study in Na2RbC60, Na2CsC60, K3C60, K2RbC60, K2CsC60, KRbCsC60, Rb2CsC60 and RbCs2C60,” Journal of the Physical Society of Japan, vol. 52, pp. 1139–1148, 1994. View at Google Scholar
  9. T. T. M. Palstra, O. Zhou, Y. Iwasa, P. E. Sulewski, R. M. Fleming, and B. R. Zegarski, “Superconductivity at 40 K in cesium doped C60,” Solid State Communications, vol. 93, no. 4, pp. 327–330, 1995. View at Publisher · View at Google Scholar · View at Scopus
  10. A. Y. Ganin, Y. Takabayashi, Y. Z. Khimyak et al., “Bulk superconductivity at 38 K in a molecular system,” Nature Materials, vol. 7, no. 5, pp. 367–371, 2008. View at Publisher · View at Google Scholar · View at PubMed
  11. Y. Takabayashi, A. Y. Ganin, P. Jeglič et al., “The disorder-free non-BCS superconductor Cs3C60 emerges from an antiferromagnetic insulator parent state,” Science, vol. 323, no. 5921, pp. 1585–1590, 2009. View at Publisher · View at Google Scholar · View at PubMed
  12. O. Gunnarsson, “Superconductivity in fullerides,” Reviews of Modern Physics, vol. 69, no. 2, pp. 575–606, 1997. View at Publisher · View at Google Scholar · View at Scopus
  13. M. J. Rosseinsky, “Recent developments in the chemistry and physics of metal fullerides,” Chemistry of Materials, vol. 10, no. 10, pp. 2665–2685, 1998. View at Publisher · View at Google Scholar · View at Scopus
  14. S. Margadonna and K. Prassides, “Recent advances in fullerene superconductivity,” Journal of Solid State Chemistry, vol. 168, no. 2, pp. 639–652, 2002. View at Publisher · View at Google Scholar
  15. Y. Iwasa and T. Takenobu, “Superconductivity, Mott-Hubbard states, and molecular orbital order in intercalated fullerides,” Journal of Physics: Condensed Matter, vol. 15, no. 13, pp. R495–R519, 2003. View at Publisher · View at Google Scholar
  16. M. J. Rosseinsky, D. W. Murphy, R. M. Fleming, and O. Zhou, “Intercalation of ammonia into K3C60,” Nature, vol. 364, no. 6436, pp. 425–427, 1993. View at Publisher · View at Google Scholar · View at Scopus
  17. O. Zhou, R. M. Fleming, D. W. Murphy et al., “Increased transition temperature in superconducting Na2CsC60 by intercalation of ammonia,” Nature, vol. 362, no. 6419, pp. 433–435, 1993. View at Publisher · View at Google Scholar · View at Scopus
  18. O. Zhou, T. T. M. Palstra, Y. Iwasa et al., “Structural and electronic properties of (NH3)xK3C60,” Physical Review B, vol. 52, no. 1, pp. 483–489, 1995. View at Publisher · View at Google Scholar
  19. S. Larsson, “Localization of electrons and excitations,” Chemical Physics, vol. 326, no. 1, pp. 115–122, 2006. View at Publisher · View at Google Scholar · View at Scopus
  20. K. Prassides, P. N. Schatz, K. Y. Wong, and P. Day, “Vibronic coupling model for mixed-valence compounds. Extension to two-site two-electron systems,” Journal of Physical Chemistry, vol. 90, no. 22, pp. 5588–5597, 1986. View at Google Scholar · View at Scopus
  21. K. Prassides and P. N. Schatz, “Vibronic coupling model for mixed-valence compounds. Extension to the multimode case,” Journal of Physical Chemistry, vol. 93, no. 1, pp. 83–89, 1989. View at Publisher · View at Google Scholar · View at Scopus
  22. S. Larsson, “Electronic structure of planar superconducting systems: from finite to extended model,” Chemical Physics, vol. 236, no. 1–3, pp. 133–150, 1998. View at Publisher · View at Google Scholar · View at Scopus
  23. G. Sparn, J. D. Thompson, S.-M. Huang et al., “Pressure dependence of superconductivity in single-phase K3C60,” Science, vol. 252, no. 5014, pp. 1829–1831, 1991. View at Publisher · View at Google Scholar · View at PubMed · View at Scopus
  24. J. E. Schirber, L. Hansen, B. Morosin, J. E. Fischer, J. D. Jorgensen, and G. H. Kwei, “Effect of pressure on the superconducting primitive cubic and “polymeric” phases of Na2CsC60,” Physica C, vol. 260, no. 3-4, pp. 173–176, 1996. View at Google Scholar · View at Scopus
  25. J. Diederichs, J. S. Schilling, K. W. Herwig, and W. B. Yelon, “Dependence of the superconducting transition temperature and lattice parameter on hydrostatic pressure for Rb3C60,” Journal of Physics and Chemistry of Solids, vol. 58, no. 1, pp. 123–132, 1997. View at Publisher · View at Google Scholar · View at Scopus
  26. P. Bhyrappa, P. Paul, J. Stinchcombe, P. D. W. Boyd, and C. A. Reed, “Synthesis and electronic characterization of discrete buckminsterfulleride salts: C602 and C603,” Journal of the American Chemical Society, vol. 115, no. 23, pp. 11004–11005, 1993. View at Publisher · View at Google Scholar · View at Scopus
  27. P. C. Trulove, R. T. Carlin, G. R. Eaton, and S. S. Eaton, “Determination of the singlet-triplet energy separation for C602 in DMSO by electron paramagnetic resonance,” Journal of the American Chemical Society, vol. 117, no. 23, pp. 6265–6272, 1995. View at Publisher · View at Google Scholar · View at Scopus
  28. S. Nakazawa, K. Sato, D. Shiomi et al., “Electronic and molecular structures of C60-based polyanionic high-spin molecular clusters: direct spin identification and electron spin transient nutation spectroscopy for high-spin chemistry,” Inorganica Chimica Acta, vol. 361, no. 14-15, pp. 4031–4037, 2008. View at Publisher · View at Google Scholar
  29. S. Larsson, “Electron pair transfer in A3C60,” in Chemical Physics of Intercalation II, P. Bernier, J. E. Fischer, S. Roth, and S. A. Solin, Eds., vol. 305 of NATO Science Series, pp. 227–231, Plenum Press, New York, NY, USA, 1993. View at Google Scholar
  30. S. Larsson and L. Rodríguez Monge, “Correlation and pairing in C[stack602n] ions. Superconductivity of alkali and alkaline earth compounds of C60,” International Journal of Quantum Chemistry, vol. 27, pp. 655–665, 1993. View at Publisher · View at Google Scholar
  31. F. Negri, G. Orlandi, and F. Zerbetto, “Low-lying electronic excited states of buckminsterfullerene anions,” Journal of the American Chemical Society, vol. 114, no. 8, pp. 2909–2913, 1992. View at Publisher · View at Google Scholar · View at Scopus
  32. G. Duškesas and S. Larsson, “Bond lengths and reorganization energies in fullerenes and their ions,” Theoretical Chemistry Accounts, vol. 97, no. 1–4, pp. 110–118, 1997. View at Google Scholar · View at Scopus
  33. D. Reznik, L. Pintschovius, M. Ito et al., “Electron-phonon coupling reflecting dynamic charge inhomogeneity in copper oxide superconductors,” Nature, vol. 440, no. 7088, pp. 1170–1173, 2006. View at Publisher · View at Google Scholar · View at PubMed
  34. T. Holstein, “Studies of polaron motion—part I: the molecular-crystal model,” Annals of Physics, vol. 8, no. 3, pp. 325–342, 1959, reprinted: Annals of Physics, vol. 281, pp. 706–724, 2000. View at Publisher · View at Google Scholar
  35. T. Holstein, “Studies of polaron motion—part II: the “small” polaron,” Annals of Physics, vol. 8, no. 3, pp. 343–389, 1959. View at Publisher · View at Google Scholar
  36. K. Prassides, S. Margadonna, D. Arcon, A. Lappas, H. Shimoda, and Y. Iwasa, “Magnetic ordering in the ammoniated fulleride (ND3)K3C60,” Journal of the American Chemical Society, vol. 121, no. 48, pp. 11227–11228, 1999. View at Publisher · View at Google Scholar
  37. J. Arvanitidis, K. Papagelis, T. Takenobu et al., “Antiferromagnetic ordering in the expanded (NH3)Rb3C60 fulleride,” Physica B, vol. 326, no. 1–4, pp. 572–576, 2003. View at Publisher · View at Google Scholar · View at Scopus
  38. R. L. Martin and J. P. Ritchie, “Coulomb and exchange interactions in C60n,” Physical Review B, vol. 48, no. 7, pp. 4845–4849, 1993. View at Publisher · View at Google Scholar
  39. R. W. Lof, M. A. van Veenendaal, B. Koopmans, H. T. Jonkman, and G. A. Sawatzky, “Band gap, excitons, and Coulomb interaction in solid C60,” Physical Review Letters, vol. 68, no. 26, pp. 3924–3927, 1992. View at Publisher · View at Google Scholar · View at Scopus
  40. P. A. Brühweiler, A. J. Maxwell, A. Nilsson, N. Mårtensson, and O. Gunnarsson, “Auger and photoelectron study of the Hubbard U in C60 , K3C60, and K6C60,” Physical Review B, vol. 48, no. 24, pp. 18296–18299, 1993. View at Publisher · View at Google Scholar
  41. O. Gunnarsson, E. Koch, and R. M. Martin, “Mott transition in degenerate Hubbard models: application to doped fullerenes,” Physical Review B, vol. 54, no. 16, pp. R11026–R11029, 1996. View at Google Scholar · View at Scopus
  42. M. R. Pederson and A. A. Quong, “Polarizabilities, charge states, and vibrational modes of isolated fullerene molecules,” Physical Review B, vol. 46, no. 20, pp. 13584–13591, 1992. View at Publisher · View at Google Scholar
  43. V. P. Antropov, O. Gunnarsson, and O. Jepsen, “Coulomb integrals and model Hamiltonians for C60,” Physical Review B, vol. 46, no. 20, pp. 13647–13650, 1992. View at Publisher · View at Google Scholar
  44. S. Larsson, A. Klimkāns, L. Rodríguez-Monge, and G. Duškesas, “Reorganization energies in organic π systems,” Journal of Molecular Structure: Theochem, vol. 425, no. 1-2, pp. 155–159, 1998. View at Publisher · View at Google Scholar · View at Scopus
  45. M. Knupfer and J. Fink, “Mott-Hubbard-like behavior of the energy gap of A4C60(A=Na,K,Rb,Cs) and Na10C60,” Physical Review Letters, vol. 79, no. 14, pp. 2714–2717, 1997. View at Publisher · View at Google Scholar · View at Scopus
  46. Y. Iwasa, K. Tanaka, T. Yasuda, T. Koda, and S. Koda, “Metallic reflection spectra of K3C60,” Physical Review Letters, vol. 69, no. 15, pp. 2284–2287, 1992. View at Publisher · View at Google Scholar
  47. E. Sohmen, J. Fink, and W. Krätchmer, “Electronic structure studies of undoped and n-type doped fullerene C60,” Europhysics Letters, vol. 17, pp. 51–55, 1992. View at Publisher · View at Google Scholar
  48. A. Wachowiak, R. Yamachika, K. H. Khoo et al., “Applied physics: visualization of the molecular Jahn-Teller effect in an insulating K4C60 monolayer,” Science, vol. 310, no. 5747, pp. 468–470, 2005. View at Publisher · View at Google Scholar · View at PubMed
  49. J. N. O'Shea, “Molecular orbitals tell the story,” Science, vol. 310, no. 5747, pp. 453–454, 2005. View at Publisher · View at Google Scholar · View at PubMed
  50. M. Capone, M. Fabrizio, C. Castellani, and E. Tosatti, “Colloquiumml: modeling the unconventional superconducting properties of expanded A3C60 fullerides,” Reviews of Modern Physics, vol. 81, no. 2, pp. 943–958, 2009. View at Publisher · View at Google Scholar
  51. G. R. Darling, A. Y. Ganin, M. J. Rosseinsky, Y. Takabayashi, and K. Prassides, “Intermolecular overlap geometry gives two classes of fulleride superconductor: electronic structure of 38 K TcCS3C60,” Physical Review Letters, vol. 101, no. 13, Article ID 136404, 2008. View at Publisher · View at Google Scholar · View at Scopus
  52. S. Larsson, accepted for publication, International Journal of Quantum Chemistry.