Advances in Condensed Matter Physics

Advances in Condensed Matter Physics / 2016 / Article

Research Article | Open Access

Volume 2016 |Article ID 2360729 |

K. S. Al Mugren, El Sayed Yousef, A. El-Taher, H. Shoukry, "Dosimetric UV Exposure Effect on the Optical Properties of Ag2O Doped P2O5-ZnO-CuO Glass", Advances in Condensed Matter Physics, vol. 2016, Article ID 2360729, 7 pages, 2016.

Dosimetric UV Exposure Effect on the Optical Properties of Ag2O Doped P2O5-ZnO-CuO Glass

Academic Editor: Rosa Lukaszew
Received30 Apr 2016
Revised17 Jul 2016
Accepted26 Jul 2016
Published24 Aug 2016


Silver phosphate glass types within composition 60P2O5-30ZnO-10CuO-100000 ppm Ag2O were prepared by melt-quenching technique. The optical properties of these glass types were studied under UV exposure at different times, 0, 20, 80, 105, and 115 minutes. The optical absorbance spectra were measured in the range of wavelength from 190 to 3200 nm. The absorbance bandwidth decreases with increasing the time of UV exposure. The optical energy gap, , linear refractive index, , ratio between molar refraction, , and molar volume, , and metallization criterion () were estimated. The value of decreases from 2.132 to 1.91 eV with increasing the time of UV exposure from 0 to 115 min. Otherwise value and metallization increase with increase in the time of UV exposure. The results indicated that these glass types are promising for using an ultraviolet radiation dosimeter.

1. Introduction

Phosphate glass types are attractive hosts and also considered to be promising for optical amplifier, fibres, laser, and dosimetery [1]. Otherwise, the disadvantage of phosphate glass is the poor chemical durability, so adding modifier like transition metals oxides leads to increasing the benefits of the glass types with decreasing their chemical durability [2, 3]. The advantage of phosphate glass types is having low melting temperature, small viscosity, and high solubility of rare earth ions [4]. Many studies on the characterization of phosphate glass types proved that, by adding cation with high value of electrostatic field strength like Zn2+ and Pb2+, the covalence of P-O-M bonds increases [5, 6]. The doping by transition metal ions like Ag leads to capturing the electron and causing positive hole and it can undergo photochemical reaction which can modify their valences [7]. What is more important is that phosphate glass types contain Ag+ and Cu+ ions which can be used as potential antimicrobial properties [8, 9]. Moreover Ag+ was found to have the highest potent antimicrobial effect against different microorganisms compared to Cu+ ions [10]. Some oxide of glass types irradiated by ionizing radiation and excited by UV light obtained emission of visible photons; this phenomenon is called the radio photoluminescence (RPL). It is a phenomenon observed in phosphate glass types doped with silver. When UV with ionized X-ray or gamma irradiation incident on the glass types contains CuO as transition metal with binary glass types, P2O5-ZnO affected in and induced defects were showed through the positive holes or generated electrons during the irradiation process [11, 12]. Hence we add Ag2O and CuO to phosphate glass types with composition 60P2O5-30ZnO-10CuO that can be used as a dosimeter. The present work is to investigate the characterization and the effect of UV irradiated exposure on the optical properties of glass types with composition 60P2O5-30ZnO-10CuO-100000 ppm Ag2O with different times of exposure to UV light at 20, 80, and 105 to 115 minutes.

2. Experimental Work

Herein the phosphate glass types within composition 60P2O5-30ZnO-10CuO doped with 100000 ppm Ag2O were melted by quenching technique in alumina crucibles at temperature of 1200°C. The prepared sample was transferred to an annealing furnace and kept at 400°C for 2 h. Herein the prepared glass types contained Cu2+ ions which leads to bluish colors. The optical absorption spectra of the glass types were measured in the wavelength range 190–3200 nm using UV-VIS-NIR spectrophotometer (Schimadzu, UV-3600). Irradiation was performed at room temperature with a UV light which is emitted mainly in the spectra at 254 nm wavelength radiation and provides evaluated light beam irradiance of 7.2 mW/cm2 at a distance of 30 cm from the sample. No external filter was used during irradiation (this setup is shown in Figure 1). The optical properties of prepared glass types were investigated under UV irradiation exposure at different times, 0, 20, 80, 105, and 115 min.

Scanning electron microscopy (SEM) was performed using JEOL Model JSM-T330 operating at 25 kV. To determine the elements in a crystalline phase by using EDx (Energy Dispersive Spectrum) X-ray detector can measure the intensity of the X-rays versus the energy.

3. Result and Discussion

Studying the optical absorption edge in UV-region is a very useful method for characterizations of both the optical transitions and electronic band structure of the amorphous material [1315]. Two mechanisms are possible to determine direct and indirect transition that can be occurring in band gap by UV absorption spectra at the fundamental absorption edge of the amorphous material. Figures 2(a)2(e) show UV, VIS, and NIR absorbance spectra of prepared glass types 60P2O5-30ZnO-10CuO-100000 ppm Ag2O irradiated by UV with time of 0, 20, 80, 105, and 115 min, respectively. The absorbance value of prepared glass types decreased by increasing the time of UV light exposure. The broad absorbance band from λ1 = 1390 to λ2 = 3190 nm (where δλ = λ2λ1 = 1800 nm) in prepared glass types with no irradiation by UV was obtained (see Figure 2(a)). When the prepared glass is exposed to UV light at different times from 20 to 80 to 105 to 115 min, this leads to the absorbance band pass decreasing from 1590 to 1465 to 1455 to 1385 nm; consequently, this is shown in Figures 2(a)2(e). This means that the time of UV exposure increase leads to the absorbance band pass being decreased. In two cases, the electromagnetic waves interact with the electrons in the valence band and hence were excited to the conduction band. In glassy materials, the absorption coefficient [α(ω)] increases with the photon energy nearest to the energy gap. Davis and Mott [16] gave a formula for [α(ω)] as a function of photon energy () for two different cases: firstly direct and secondly indirect transitions through the following expression: , where = 4.14·10−15 (eV·s), = 1/2 for direct transition but = 2 for indirect transition, is a constant related to the extent of the band tailing, and is optical band gap energy. Moreover the absorption edge of glassy materials increases exponentially with photon energy. The energy of the incident light is less than the band gap due to the increase in absorption coefficient and leads to exponential decay of density of the localized state into the gap [13, 14] in which the absorption edge denotes Urbach edge, where value is in the range from 10 to 103 cm−1. Urbach energy strongly depends on many factors as follows: (1) temperature; (2) thermal vibrations in the glass types lattice; (3) induced disorder; (4) static disorder; (5) strong ionic bonds; and (6) average photon energies. Figures 3(a)3(e) showed the plot ()1/2 versus () of the studied prepared glass types, where the energy, , has been estimated from the linear regions of the curves by extrapolating them to meet the -axis at ()1/2 = 0 [1719] and the values are listed in Table 1 for both samples. The optical energy gap values decrease from 2.131 to 1.91 eV with increasing the UV irradiate exposure time from 0 to 115 min; this is shown in Figure 4. When incorporating CuO and Ag2O, largest chance for Ag and Cu ions leads to changing their valences by photochemical reactions from holes (h+) and electron generated during the irradiation exposure. Hence the following reactions happened: Cu+ + e → Cu0, Cu+ + h+ → Cu++, Ag+ + e → Ag0, and Ag+ + h+ → Ag++ [20]. The electron is generated faster than h+ in the glass types matrix and hence the accumulation velocity of Ag0 and Cu0 is higher than that of Ag++ and Cu++. We can explain the observed decreasing values of from 2.131 to 1.91 eV with increasing the UV irradiate exposure time from 0 to 115 min due to increasing the number of the unpaired electrons per unit volume with increasing the spin density in unfilled bands. In addition to irradiation of UV, the defects centers formed from charge trapping of the electrons or holes which often have electronic states in the gap between the valence and the conduction bands. Hence optical photons can induce transition from the valence band to the defects level or from the defect level to the conduction band.

Time of UV irradiated exposure in minutes Optical energy gap, , in eVBand width, , in nmRefractive index/ in mol−1Metallization, ,


The refractive index () at different wavelength can be determined by , where molar refraction is in cm3·mol−1 and is the molar volume in cm−3. Duffy and Ingram [21] have obtained an empirical formula that relates the energy gap, , to the molar refraction as follows: ; the metallization criterion, , can be determined by expression . If this means that the linear refractive index becomes infinite; moreover, when () and ) this indicated the nonmetallic and metallic character of material, respectively. Herein the refractive index increases from 2.681 to 2.776 when the time of UV exposure of prepared sample increases from 0 to 115 min; this is shown in Figure 5. Also the ratio of value increases from 0.674 to 0.691 in mol−1 when the time of UV exposure increases from 0 to 115 min. Otherwise the metallization value of prepared glass types decreases from 0.326 to 0.309 when the time of UV exposure increases from 0 to 115 min. Tošić et al. [22] estimated that the phosphate glass types containing ZnO have shorter phosphate anions length as bond of nonbridge oxygen replaces bond of bridging oxygen on the P-tetrahedra change in the polarizability of surrounding the copper ions due to increasing the distortion which strongly depends on the field strengths of network modifier former ion. So the increasing of polarizability with time of UV exposure increasing from 0 to 115 min leads to increase in refractive index. Measurement of a dosimeter character is the process of finding at least one physical property that can be used for designing radiation dosimeter which can be possible calibration. Here we found that the relation between optical energy gap and UV irradiated exposure time is good linear fitting with regression value ( = 0.9948) (see Figure 4); this indicates the increase in the nonbridge oxygen due to increase in the number of free electrons. Also the relation between the value of refractive index and the time of UV irradiated exposure is in good agreement with high regression ( = 0.994) (see Figure 5). Hence we can estimate that the prepared glass types with composition 60P2O5-30ZnO-10CuO-100000 ppm Ag2O may be used in the instrument of UV dosimeter. Finally we investigated the prepared glass types by using SEM at room temperature; this is shown in Figure 6(a); no crystalline was obtained in this figure. After the prepared glass types annealed at 600°C, the crystalline silver as shape sheets appeared, and it was analyzed by using EDX (see Figures 6(b) and 6(c)).

4. Conclusion

The incorporation of Ag2O into the ternary glass in the system 60P2O5-30ZnO-10CuO leads to preparing activated phosphate glass types under UV irradiation. The band width decreases with increasing the time of UV irradiated exposure of prepared glass types. The value of optical energy gap decreases linearly with increasing the time of UV exposure. Otherwise the refractive index increases with increasing the time of UV exposure and polarizability of nonbridging oxygen.

Competing Interests

The authors declare that they have no competing interests.


The authors are thankful to the Deanship of Scientific Research at Princess Nourah Bint Abdualrahman University (PNU) for funding this research project (no. 36-S-101).


  1. R. V. S. S. N. Ravikumar, A. V. Chandrasekhar, L. Ramamoorthy et al., “Spectroscopic studies of transition metal doped sodium phosphate glasses,” Journal of Alloys and Compounds, vol. 364, no. 1-2, pp. 176–179, 2004. View at: Google Scholar
  2. R. K. Brow, “Review: the structure of simple phosphate glasses,” Journal of Non-Crystalline Solids, vol. 263-264, pp. 1–28, 2000. View at: Publisher Site | Google Scholar
  3. M. Catauro, G. Laudisio, and J. Therm, “The non-isothermal devitrification of glasses in the SrO·4GeO2–BaO·4GeO2composition range,” Journal of Thermal Analysis and Calorimetry, vol. 58, no. 3, pp. 617–623, 1999. View at: Publisher Site | Google Scholar
  4. I. W. Donald, “Preparation, properties and chemistry of glass- and glass-ceramic-to-metal seals and coatings,” Journal of Materials Science, vol. 28, no. 11, pp. 2841–2886, 1993. View at: Publisher Site | Google Scholar
  5. R. K. Brow and D. R. Tallant, “Structural design of sealing glasses,” Journal of Non-Crystalline Solids, vol. 222, pp. 396–406, 1997. View at: Publisher Site | Google Scholar
  6. N. H. Ray, C. J. Lewis, J. N. C. Laycock, and W. D. Robinson, “Oxide glasses of very low softening point. Part 1, 2: preparation and properties of some lead phosphate glasses,” Glass Technology, vol. 14, pp. 50–59, 1973. View at: Google Scholar
  7. F. H. ElBatal, S. Y. Marzouk, N. Nada, and S. M. Desouky, “Gamma-ray interaction with copper-doped bismuth–borate glasses,” Physica B: Condensed Matter, vol. 391, no. 1, pp. 88–97, 2007. View at: Publisher Site | Google Scholar
  8. I. Ahmed, D. Ready, M. Wilson, and J. C. Knowles, “Antimicrobial effect of silver-doped phosphate-based glasses,” Journal of Biomedical Materials Research Part A, vol. 79, no. 3, pp. 618–626, 2006. View at: Publisher Site | Google Scholar
  9. E. A. Abou Neel, I. Ahmed, J. Pratten, S. N. Nazhat, and J. C. Knowles, “Characterisation of antibacterial copper releasing degradable phosphate glass fibres,” Biomaterials, vol. 26, no. 15, pp. 2247–2254, 2005. View at: Publisher Site | Google Scholar
  10. S. I. S. Shaharuddin, I. Ahmed, D. Furniss, A. J. Parsons, and C. D. Rudd, “Thermal properties, viscosities and densities of (50-x)Na 2O-xCaO-50P2O5 glasses,” Glass Technology: European Journal of Glass Science and Technology Part A, vol. 53, no. 6, pp. 245–251, 2012. View at: Google Scholar
  11. N. Aboulfotoh, Y. Elbashar, and M. Ibrahem, “Characterization of copper doped phosphate glasses for optical applications,” Ceramics International, vol. 40, no. 7, pp. 10395–10399, 2014. View at: Publisher Site | Google Scholar
  12. E. J. Friebele, Optical Properties of Glass, American Ceramic Society, Westerville, Ohio, USA, 1991.
  13. F. Abeles, Ed., The Optical Properties of Solids, North Holland, Amsterdam, The Netherlands, 1970.
  14. E. S. Yousef and B. Al-Qaisi, “UV spectroscopy, refractive indices and elastic properties of the 76-x TeO29P2O515ZnO·xLiNbO3 glass,” Solid State Sciences, vol. 19, pp. 6–11, 2013. View at: Publisher Site | Google Scholar
  15. E. S. Yousef, “Er3+ ions doped tellurite glasses with high thermal stability, elasticity, absorption intensity, emission cross section and their optical application,” Journal of Alloys and Compounds, vol. 561, pp. 234–240, 2013. View at: Publisher Site | Google Scholar
  16. E. A. Davis and N. F. Mott, “Conduction in non-crystalline systems V. Conductivity, optical absorption and photoconductivity in amorphous semiconductors,” Philosophical Magazine, vol. 22, no. 179, pp. 903–922, 1970. View at: Publisher Site | Google Scholar
  17. F. Urbach, “The long-wavelength edge of photographic sensitivity and of the electronic absorption of solids,” Journal of Physical Review, vol. 92, no. 5, p. 1324, 1953. View at: Publisher Site | Google Scholar
  18. M. I. Ojovan and W. E. Lee, “Alkali ion exchange in γ-irradiated glasses,” Journal of Nuclear Materials, vol. 335, no. 3, pp. 425–432, 2004. View at: Publisher Site | Google Scholar
  19. A. S. Monem, H. A. ElBatal, E. M. A. Khalil, M. A. Azooz, and Y. M. Hamdy, “In vivo behavior of bioactive phosphate glass-ceramics from the system P2O5-Na2O-CaO containing TiO2,” Journal of Materials Science: Materials in Medicine, vol. 19, no. 3, pp. 1097–1108, 2008. View at: Publisher Site | Google Scholar
  20. Y. Miyamoto, T. Yamamoto, K. Kinoshita et al., “Emission mechanism of radiophotoluminescence in Ag-doped phosphate glass,” Radiation Measurements, vol. 45, no. 3–6, pp. 546–549, 2010. View at: Publisher Site | Google Scholar
  21. J. A. Duffy and M. D. Ingram, “An interpretation of glass chemistry in terms of the optical basicity concept,” Journal of Non-Crystalline Solids, vol. 21, no. 3, pp. 373–410, 1976. View at: Publisher Site | Google Scholar
  22. M. B. Tošić, J. D. Nikolić, S. R. Grujić et al., “Dissolution behavior of a polyphosphate glass into an aqueous solution under static leaching conditions,” Journal of Non-Crystalline Solids, vol. 362, pp. 185–194, 2013. View at: Publisher Site | Google Scholar

Copyright © 2016 K. S. Al Mugren et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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