Research Article

Determination of Tetracycline and Fluoroquinolone Antibiotics at Trace Levels in Sludge and Soil

Table 2

Precursor and product ions, collision energy (CE), and declustering potential (DP).

CompoundsPrecursor ion → product ion (CE (eV))DP (V)

Tetracycline445 → 410 (25) and 445 → 154 (35)36
Oxytetracycline461 → 426 (25) and 461 → 443 (19)36
Chlortetracycline479 → 444 (27) and 479 → 462 (23)36
Minocycline479 → 441 (27) and 479 → 352 (23)36
Doxycycline445 → 428 (23) and 445 → 154 (41)41
Ciprofloxacin332 → 288 (23) and 332 → 231 (49)51
Enrofloxacin360 → 316 (25) and 360 → 245 (35)51
Ofloxacin362 → 261 (35) and 362 → 318 (23)51
Norfloxacin320 → 276 (27) and 320 → 231 (51)61
Danofloxacin358 → 340 (27) and 358 → 82 (67)26
Marbofloxacin363 → 72 (37) and 363 → 320 (23)21
Orbifloxacin396 → 295 (33) and 396 → 352 (23)31
Difloxacin400 → 356 (25) and 400 → 299 (35)41