Research Article

Highly Sensitive Detection of Trace Tetracycline in Water Using a Metal-Organic Framework-Enabled Sensor

Table 1

Summary of the tetracycline detecting performance between different sensors.

Sensor typesDetection techniquesSignal transducer or active electrode materialsLinear range (μM)Detection limit (μM)References

Optical sensor typeColorimetricAuNPs0.95-29.250.38[33]
TMB0.01-10.045[34]
FluorescenceMIP-APS-QDs0.12-0.370.54[35]
MIP-MAA-QDs0.10-0.370.50[36]
SPRAgNPs112.5-1125029.25[37]
Electrochemical sensor typeDPVFe/Zn-MMT/GCE0.30–520.10[1]
MIOPPy-AuNP/SPCE1-200.65[37]
MWCNTs/GCE0.01-100.005[38]
CVPtNPs/C/GCE9.99–44.014.28[39]
UV-DNA/GCE0.3-900.27[40]
MIP/MWCNTs-AuNPs/GCE0.225-900.09[41]
DPVMIL-53(Fe)/GCE0.0643-1.530.026This work

SPR: surface plasmon resonance; DPV: differential pulse voltammetry; CV: cyclic voltammetry; AuNPs: Au nanoparticles; TMB: 3,3,5,5-tetramethylbenzidine; MIP-APS-QDs: molecularly imprinting polymer-3-mercapto-propyltriethoxysilane-CdTe quantum dots; MIP-MAA-QDs: molecmolecularly imprinting polymer-methacrylic acid-CdTe quantum dots; AgNPs: Ag nanoparticles; Fe/Zn-MMT/GCE: iron/zinc cation–exchanged montmorillonite catalyst on glassy carbon electrode; MIOPPy-AuNP/SPCE: screen-printed carbon electrodes modified with molecularly imprinted overoxidized polypyrrole and gold nanoparticles; MWCNTs/GCE: multiwalled carbon nanotubes, modified glass carbon electrode; PtNPs/C/GCE: platinum nanoparticles supported on carbon-coated glassy carbon electrode; UV-DNA/GCE: UV irradiated DNA film modified glassy carbon electrode; MIP/MWCNTs-AuNPs/GCE: molecularly imprinting polymer and gold nanoparticles modified multiwalled carbon nanotubes, modified glass carbon electrode.