Statistical Physics Modeling of Sorption Isotherms of Aluminum, Iron, and Indium on Tetraphenylporphyrin (H₂TPP) and Tetrakis(4-tolylphenyl)porphyrin (H₂TTPP): Phenomenological Investigation of Metalloporphyrins at the Molecular Level

Table 3

Values of the physicochemical parameters (, , , , , , , and ) affecting the adsorption of AlCl₃, FeCl₃, and InCl₃ on 5,10,15,20-tetrakis(4-methylphenyl) porphyrin H₂TTPP (systems (a), (b), and (c)) at five temperatures.

System	Parameters	290 K	300 K	310 K	320 K	330 K
System (a): AlCl3-H2TTPP		0.80 (±0.02)	0.81 (±0.015)	0.89 (±0.019)	0.99 (±0.024)	1.01 (±0.019)
		281.7 (±8.2)	320.6 (±9.4)	366.1 (±8.9)	401.9 (±10.9)	450.7 (±11.7)
		0.015 (±0.005)	0.015 (±0.006)	0.016 (±0.005)	0.016 (±0.005)	0.017 (±0.006)
System (b): FeCl3-H2TTPP		0.71 (±0.025)	0.73 (±0.015)	0.79 (±0.022)	0.84 (±0.019)	0.89 (±0.02)
		228.4 (±12.1)	262.6 (±10.9)	298.7 (±9.99)	333.6 (±8.79)	389.8 (±9.78)
		0.011 (±0.004)	0.011 (±0.005)	0.012 (±0.006)	0.011 (±0.006)	0.012 (±0.007)
	()	8.3 (±0.2)	7.2 (±0.3)	6.1 (±0.4)	5.8 (±0.3)	5.1 (±0.5)
	()	2.6 (±0.1)	3.2 (±0.2)	3.9 (±0.2)	4.8 (±0.4)	5.7 (±0.4)
System (c): InCl3-H2TTPP		0.63 (±0.018)	0.66 (±0.023)	0.69 (±0.016)	0.74 (±0.022)	0.82 (±0.016)
		142.3 (±9.52)	189.4 (±10.7)	233.8 (±12.8)	289.4 (±11.2)	320.5 (±10.9)
		0.0033 (±0.0007)	0.003 (±0.008)	0.0035 (±0.0003)	0.0032 (±0.0009)	0.0036 (±0.0004)
		0.026 (±0.007)	0.025 (±0.009)	0.026 (±0.008)	0.025 (±0.004)	0.027 (±0.007)