Synthesis and Characterization of New Catalysts Grains Based on Iron(Oxy)Hydroxides supported on Zirconium for the Degradation of 4-Nitrophenol in Aqueous Solution

<table class="table-group" id="tab4"><tr><td><table class="table"><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr class="thead"><td class="align_left" rowspan="3">Sample</td><td class="align_center" colspan="2">PZC</td></tr><tr class="thead"><td class="align_center" rowspan="2">Powder</td><td class="align_center">Grain</td></tr><tr class="thead"><td class="align_center"><span style="width: 106.052ptpx;"><svg height="9.92533pt" id="M25" style="vertical-align:-0.6370001pt" version="1.1" viewbox="-0.0498162 -9.28833 106.052 9.92533" width="106.052pt" xmlns="http://www.w3.org/2000/svg" xmlns:xlink="http://www.w3.org/1999/xlink"><g transform="matrix(.013,0,0,-0.013,0,0)"><path d="M241 635C89 635 35 457 35 312C35 153 89 -12 240 -12C390 -12 443 166 443 312C443 466 390 635 241 635ZM238 602C329 602 354 454 354 312C354 172 330 22 240 22C152 22 124 173 124 313S148 602 238 602Z"></path></g><g transform="matrix(.013,0,0,-0.013,6.24,0)"><path d="M113 -12C146 -12 170 11 170 46C170 78 146 103 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423C504 407 475 389 446 366C425 418 382 449 334 449C303 449 279 437 253 421C222 403 201 385 180 371V452C135 432 85 419 41 411V388C99 379 102 374 102 310V103C102 38 93 32 27 26V0H238V26C189 32 180 38 180 103V338C210 363 250 390 289 390C351 390 377 348 377 275V103C377 37 368 32 306 26V0H520V26C465 32 456 38 456 101V296C456 314 455 326 453 338C491 369 529 390 565 390C628 390 653 345 653 274V107C653 36 642 32 583 26V0H797Z"></path></g><g transform="matrix(.013,0,0,-0.013,42.625,0)"><path d="M512 -3V55L134 254V256L512 456V514L75 281V230L512 -3Z"></path></g><g transform="matrix(.013,0,0,-0.013,53.888,0)"><path d="M530 686C535 705 530 712 521 712C504 712 448 684 359 674L358 648H393C437 648 439 646 429 593L400 435C372 447 345 448 332 448C286 448 194 414 144 373C68 311 23 203 23 111C23 26 57 -12 91 -12C120 -12 147 3 188 29C227 54 290 102 341 170H343L322 71C308 6 320 -12 341 -12C373 -12 442 27 501 96L485 120C455 91 422 67 408 67C401 67 401 76 404 91C440 294 479 473 530 686ZM387 375L355 241C326 187 200 53 142 53C126 53 109 73 109 130C109 217 154 337 218 381C240 396 265 404 297 404S372 390 387 375Z"></path></g><g transform="matrix(.013,0,0,-0.013,64.735,0)"><path d="M512 -3V55L134 254V256L512 456V514L75 281V230L512 -3Z"></path></g><g transform="matrix(.013,0,0,-0.013,75.998,0)"><path d="M384 0V27C293 34 287 42 287 114V635C232 613 172 594 109 583V559L157 557C201 555 205 550 205 499V114C205 42 199 34 109 27V0H384Z"></path></g><g transform="matrix(.013,0,0,-0.013,84.413,0)"><path d="M797 0V26C739 32 732 36 732 103V296C732 394 682 449 605 449C576 449 550 437 529 423C504 407 475 389 446 366C425 418 382 449 334 449C303 449 279 437 253 421C222 403 201 385 180 371V452C135 432 85 419 41 411V388C99 379 102 374 102 310V103C102 38 93 32 27 26V0H238V26C189 32 180 38 180 103V338C210 363 250 390 289 390C351 390 377 348 377 275V103C377 37 368 32 306 26V0H520V26C465 32 456 38 456 101V296C456 314 455 326 453 338C491 369 529 390 565 390C628 390 653 345 653 274V107C653 36 642 32 583 26V0H797Z"></path></g><g transform="matrix(.013,0,0,-0.013,95.06,0)"><path d="M797 0V26C739 32 732 36 732 103V296C732 394 682 449 605 449C576 449 550 437 529 423C504 407 475 389 446 366C425 418 382 449 334 449C303 449 279 437 253 421C222 403 201 385 180 371V452C135 432 85 419 41 411V388C99 379 102 374 102 310V103C102 38 93 32 27 26V0H238V26C189 32 180 38 180 103V338C210 363 250 390 289 390C351 390 377 348 377 275V103C377 37 368 32 306 26V0H520V26C465 32 456 38 456 101V296C456 314 455 326 453 338C491 369 529 390 565 390C628 390 653 345 653 274V107C653 36 642 32 583 26V0H797Z"></path></g></svg></span></td></tr><tr><td class="thead-hr" colspan="3"><hr/></td></tr><tr><td class="align_left">25GFe75Zr</td><td class="align_center">7.13</td><td class="align_center">9.17</td></tr><tr><td class="align_left">75GFe25Zr</td><td class="align_center">7.18</td><td class="align_center">11.12</td></tr><tr><td class="align_left">50GFe50Zr</td><td class="align_center">7.01</td><td class="align_center">9.40</td></tr><tr><td class="align_left">Goethite</td><td class="align_center">6.1</td><td class="align_center">9.07</td></tr><tr><td class="align_left">25HFe75Zr</td><td class="align_center">4.11</td><td class="align_center">6.07</td></tr><tr><td class="align_left">75HFe25Zr</td><td class="align_center">8.14</td><td class="align_center">11.20</td></tr><tr><td class="align_left">50HFe50Zr</td><td class="align_center">8.19</td><td class="align_center">8.67</td></tr><tr><td class="align_left">HFO</td><td class="align_center">10.42</td><td class="align_center">8.31</td></tr><tr class="table-tr"><td colspan="3"><hr class="tbody-hr"/></td></tr></table></td></tr></table>

<div>pH of point of zero charge (PZC) of catalysts used in the degradation of 4-nitrophenol.</div>

Adsorption Science & Technology

tab4

Table 4

Table 4: Synthesis and Characterization of New Catalysts Grains Based on Iron(Oxy)Hydroxides supported on Zirconium for the Degradation of 4-Nitrophenol in Aqueous Solution 

Table 4 | Synthesis and Characterization of New Catalysts Grains Based on Iron(Oxy)Hydroxides supported on Zirconium for the Degradation of 4-Nitrophenol in Aqueous Solution 