Review Article

Carbon-Based Nanoadsorbents for the Removal of Emerging Pollutants

Table 1

Removal of emerging contaminants by CNT-based adsorbents.

AdsorbentPollutantAdsorption capacityReferenceSignificant findings

SnO2-CNTAs (III)106.95 mg/g[29](i) 86% removal efficiency after 5 regeneration cycles
(ii) Multifunctionality: catalytic effectiveness against 4-nitrophenol, alizarin red S dye, and metronidazole pollutants. Antimicrobial activity against bacterial and fungal strains
Oxidized multiwalled carbon nanotubes with different oxygen contentsTetracyclineAdsorption capacity of CNTs-.[44]
Ciprofloxacin (CPX)[46]qm/SSA continued to increase with increasing oxygen content
SWCNT, acidified ammonium persulfate treated SWCNT (t-SWCNT)Bisphenol A (BPA), 17β-estradiol (E2)BPA: 19.4 mg/g and 8 mg/g, respectively, for SWCNT and t-SWCNT; E2: 27.2 mg/g[48]
MWCNTs with 15nm, 30nm, 50nm and SWCNTs (hydroxyl functionalized, carboxy functionalized, and pure)Ofloxacin (OFL) and norfloxacin (NOR)[47]The structural and hydrophobic characteristics of OFL and NOR influenced their adsorption
SWCNTs and MWCNTsIbuprofen (IBU) and triclosan (TCS)For SWCNT, IBU at pH 7: 232 mg/g; TCS at pH 7: 558 mg/g[49]SWCNT adsorbed more IBU and TCS than MWCNT; IBU adsorption was higher at pH 4, but TCS adsorption was higher at pH 7; CNT surface oxidation decreased adsorption
MWCNTsCiprofloxacin (CPX)150 mg/g[50]CNT absorbed more CPX than activated carbon and carbon xerogel; however, oxidation and heat treatment had little effect on CNT adsorption
SWCNTs and MWCNTsPerchlorate (ClO4)3.55 mg/g[51]DWCNTs adsorbed better than SWCNTs and MWCNTs; the presence of additional ClO4 oxygen-containing functional groups increased adsorption
SWCNTs in the presence of natural organic matter (NOM)Bisphenol A (BPA) and 17β-estradiol (E2)[52]The adsorption of BPA and E2 varied from 7.3 to 95% depending on the solution pH and the presence or absence of NOM and SWCNTs
MWCNT carboxyl functionalizationMixture of four linear alkyl benzene sulfonates168 mg/g[53]The adsorption was made possible through hydrophobic contact and the creation of hydrogen bonds