Open Access

Satoko Hayashi, Waro Nakanishi, "Proposal for Sets of
^{77}Se NMR Chemical Shifts in Planar and Perpendicular Orientations of Aryl Group and the Applications", *Bioinorganic Chemistry and Applications*, vol. 2006, Article ID 079327, 13 pages, 2006. https://doi.org/10.1155/BCA/2006/79327

# Proposal for Sets of
^{77}Se NMR Chemical Shifts in Planar and Perpendicular Orientations of Aryl Group and the Applications

#### Abstract

The orientational effect of **pl** and **pd** employing 9-(arylselanyl)anthracenes (**1**) and 1-(arylselanyl)anthraquinones (**2**), respectively,
where Se–**pl** and perpendicular to the plane in **pd**. Absolute magnetic shielding tensors of Se (**pl** and **pd**, with the DFT-GIAO method. Observed characters are well reproduced by the total shielding tensors (**pl** and **pd**. Sets of **1**) and **2**) act
as the standards for **pl** and **pd**, respectively, when

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#### Copyright

Copyright © 2006 Satoko Hayashi and Waro Nakanishi. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.