Table of Contents Author Guidelines Submit a Manuscript
Bioinorganic Chemistry and Applications
Volume 2007 (2007), Article ID 28508, 6 pages
Research Article

A Mononuclear and a Mixed-Valence Chain Polymer Arising from Copper(II) Halide Chemistry and the Use of 2,2'-Pyridil

1School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ, UK
2Institute of Materials Science, National Centre of Scientific Research “Demokritos”, Aghia Paraskevi Attikis 153 10, Greece
3Department of Chemistry, University of Patras, Patras 265 04, Greece
4Laboratory of Inorganic Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis, Zografou 157 71, Greece

Received 14 February 2007; Accepted 14 April 2007

Academic Editor: Jean Pierre Tuchagues

Copyright © 2007 Constantinos J. Milios et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Linked References

  1. G. S. Papaefstathiou and S. P. Perlepes, “Families of polynuclear manganese, cobalt, nickel and copper complexes stabilized by various forms of di-2-pyridyl ketone,” Comments on Inorganic Chemistry, vol. 23, no. 4, pp. 249–274, 2002. View at Publisher · View at Google Scholar
  2. C. J. Milios, T. C. Stamatatos, and S. P. Perlepes, “The coordination chemistry of pyridyl oximes,” Polyhedron, vol. 25, no. 1, pp. 134–194, 2006, (Polyhedron Report). View at Publisher · View at Google Scholar
  3. G. S. Papaefstathiou, C. P. Raptopoulou, A. Tsohos, A. Terzis, E. G. Bakalbassis, and S. P. Perlepes, “Alcoholysis of 2,2-pyridil, (2-C5H4N)C(O)C(O)(2-C5H4N), in the presence of copper(II): a family of planar pentanuclear copper(II) complexes stabilized by [(2-C5H4N)C(O)(OR)C(O)(OR)(2-C5H4N)]2- and carboxylate ligands,” Inorganic Chemistry, vol. 39, no. 20, pp. 4658–4662, 2000. View at Publisher · View at Google Scholar
  4. R. D. Willett, G. Pon, and C. Nagy, “Crystal chemistry of the 4,4-dimethyl-2,2bipyridine/copper bromide system,” Inorganic Chemistry, vol. 40, no. 17, pp. 4342–4352, 2001. View at Publisher · View at Google Scholar
  5. R. D. Willett, “Bromination of the 3-chloroanilinium cation: structure of a novel two-dimensional copper(I) bromide lattice prepared via in-situ redox processes,” Inorganic Chemistry, vol. 40, no. 5, pp. 966–971, 2001. View at Publisher · View at Google Scholar
  6. R. D. Willett and K. Halvorson, “Structures of catalytically related species involving copper(II) halides. VI. Tetrakis(3-aminopyridinium) decabromodicuprate(I)dicuprate(II),” Acta Crystallographica, vol. C44, pp. 2068–2071, 1988. View at Publisher · View at Google Scholar
  7. J. P. Fackler Jr., “Mixed valence compounds,” in Encyclopedia of Inorganic Chemistry, R. B. King, Ed., vol. 5, pp. 2270–2281, John Wiley & Sons, Chichester, UK, 1994. View at Google Scholar
  8. E. W. Constable, Metals and Ligand Reactivity, VCH, Weinheim, Germany, 2nd edition, 1996.
  9. M. G. Barandika, Z. E. Serna, M. K. Urtiaga, J. I. R. De Larramendi, M. I. Arriortua, and R. Cortés, “Crystal structure and magnetic properties of two metal-picolinate systems obtained from degradation of bis(2-pyridylketone) through reaction with Mn(II) and Cu(II),” Polyhedron, vol. 18, no. 8-9, pp. 1311–1316, 1999. View at Publisher · View at Google Scholar
  10. M. Du, X.-H. Bu, M. Shionoya, and M. Shiro, “Metal assisted rearrangement of 2,2-pyridil with M(CIO4)26H2O(M=CoII,NiII and CuII): syntheses, characterization and crystal structures,” Journal of Molecular Structure, vol. 607, no. 2-3, pp. 155–161, 2002. View at Publisher · View at Google Scholar
  11. B. F. Abrahams, T. A. Hudson, and R. Robson, “In situ synthesis of trisubstituted methanol ligands and their potential as one-pot generators of cubane-like metal complexes,” Chemistry, vol. 12, no. 27, pp. 7095–7102, 2006. View at Publisher · View at Google Scholar
  12. R. W. Hay and C. R. Clark, “Transition metal complexes of 2-carbethoxypyridine (ethyl picolinate),” Transition Metal Chemistry, vol. 4, pp. 28–31, 1979. View at Publisher · View at Google Scholar
  13. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, New York, NY, USA, 4th edition, 1986.
  14. A. Álvarez-Larena, W. Clegg, L. Cucurull-Sánchez et al., “Mercury(II) halide adducts of esters of 2-pyridinecarboxylic acid. Crystal structures and structural variations within the series [HgCl2(C5H4NCOOR)], R=Me, Et, Prn, Pri,” Inorganica Chimica Acta, vol. 266, no. 1, pp. 81–90, 1997. View at Google Scholar